xenon difluoride

• Formula: F₂Xe
• Molecular weight: 169.290
• CAS Registry Number: 13709-36-9
• Information on this page:
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Phase change data
  • Reaction thermochemistry data
  • Vibrational and/or electronic energy levels
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to F₂Xe⁺ (ion structure unspecified)

Ionization energy determinations

Appearance energy determinations

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 + F₂Xe = F₃Xe^-

By formula: F^- + F₂Xe = F₃Xe^-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Guyon, P.M.; Holloway, J.; Spohr, R., Photo-ionization studies of F₂, HF, DF, and the xenon fluorides, Advan. Mass Spectrom., 1971, 5, 112. [all data]

Brundle, Robin, et al., 1970
Brundle, C.R.; Robin, M.B.; Jones, G.R., High resolution He I and He II photoelectron spectra of xenon difluoride, J. Chem. Phys., 1970, 52, 3383. [all data]

Brehm, Menzinger, et al., 1970
Brehm, B.; Menzinger, M.; Zorn, C., The photoelectron spectrum of XeF₂, Can. J. Chem., 1970, 48, 3193. [all data]

Morrison, Nicholson, et al., 1968
Morrison, J.D.; Nicholson, A.J.C.; O'Donnell, T.A., Ionization and dissociation of xenon difluoride induced by photon impact, J. Chem. Phys., 1968, 49, 959. [all data]

Nielsen and Schwarz, 1976
Nielsen, U.; Schwarz, W.H.E., VUV spectra of the xenon fluorides, Chem. Phys., 1976, 13, 195. [all data]

Berkowitz, Chupka, et al., 1971, 2
Berkowitz, J.; Chupka, W.A.; Guyon, P.M.; Holloway, J.H.; Spohr, R., Photoionization mass spectrometric study of XeF₂, XeF₄, and XeF₆, J. Phys. Chem., 1971, 75, 1461. [all data]

Svec and Flesch, 1963
Svec, H.J.; Flesch, G.D., Thermochemical properties of xenon difluoride and xenon tetrafluoride from massspectra, Science, 1963, 142, 954. [all data]

Krouse, Hao, et al., 2007
Krouse, I.H.; Hao, C.T.; Check, C.E.; Lobring, K.C.; Sunderlin, L.S.; Wenthold, P.G., Bonding and electronic structure of XeF3-, J. Am. Chem. Soc., 2007, 129, 4, 846-852, https://doi.org/10.1021/ja065038b . [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  IE (evaluated)	Recommended ionization energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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