zirconium tetrafluoride

• Formula: F₄Zr
• Molecular weight: 167.218
• IUPAC Standard InChI: InChI=1S/4FH.Zr/h4*1H;/p-1 Copy

  
• IUPAC Standard InChIKey: NLGFRLRLBUOAEJ-UHFFFAOYSA-M Copy
• CAS Registry Number: 7783-64-4
• Chemical structure:
  This structure is also available as a 2d Mol file
• Information on this page:
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Appearance energy determinations

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = ( • )

By formula: F^- + F₄Zr = (F^- • F₄Zr)

F₅Zr^- +  = F₉Zr₂^-

By formula: F₅Zr^- + F₄Zr = F₉Zr₂^-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Murad and Hildenbrand, 1966
Murad, E.; Hildenbrand, D.L., Mass-spectrometric study of the thermodynamic properties of Zr-F species, J. Chem. Phys., 1966, 45, 4751. [all data]

Skokan, Sorokin, et al., 1982
Skokan, E.V.; Sorokin, I.D.; Sidorov, L.N.; Nikitin, M.I., Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VI. Enthalpy of Formation of ZrF₅^-, Int. J. Mass Spectrom. Ion Phys., 1982, 43, 4, 209, https://doi.org/10.1016/0020-7381(82)80017-X . [all data]

Skokan, Nikitin, et al., 1981
Skokan, E.V.; Nikitin, M.I.; Sorokin, I.D.; Gusarov, A.V.; Sidirov, L.N., Determination of the heat of formation of the tetrafluoroscandate and pentfluorozirconate ions by the effusion nethod, Russ. J. Phys. Chem., 1981, 55, 1062. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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