Plumbane, tetraphenyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas161.1 ± 3.7kcal/molReviewMartinho SimõesSelected data

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub46.5 ± 1.5kcal/molEPilcher and Skinner, 1983See also Carson, Laye, et al., 1972.; AC
Δsub38.0 ± 0.2kcal/molCC-RBKana'an and Morrison, 1977MS
Δsub38.0 ± 0.2kcal/molME,TEKana'an and Morrison, 1977, 2Based on data from 412. to 474. K.; AC
Δsub19.8kcal/molN/ANewkirk, 1972AC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Reference Comment
36.1446.Stephenson and Malanowski, 1987Based on data from 412. to 480. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
8.0PENovak and Potts, 1984LBLHLM
8.95PENovak and Potts, 1984Vertical value; LBLHLM

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY
NIST MS number 62154

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References

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Carson, Laye, et al., 1972
Carson, A.S.; Laye, P.G.; Spencer, J.A.; Steele, W.V., The enthalpy of combustion of organo-metallic compounds measured with a vacuum-jacketed rotating aneroid calorimeter. The enthalpy of formation of lead tetraphenyl, The Journal of Chemical Thermodynamics, 1972, 4, 5, 783-787, https://doi.org/10.1016/0021-9614(72)90052-3 . [all data]

Kana'an and Morrison, 1977
Kana'an, A.S.; Morrison, T.I., J. Chem. Thermodyn., 1977, 9, 423. [all data]

Kana'an and Morrison, 1977, 2
Kana'an, Adli S.; Morrison, T.I., Enthalpy and entropy of sublimation of tetraphenyl plumbane the bond dissociation energy of Pb«58872»C, The Journal of Chemical Thermodynamics, 1977, 9, 5, 423-429, https://doi.org/10.1016/0021-9614(77)90142-2 . [all data]

Newkirk, 1972
Newkirk, Herbert W., Piezoelectric organometallic crystal: Growth and properties of tetraphenylsilicon, -germanium, -ti and -lead, Journal of Organometallic Chemistry, 1972, 44, 2, 263-271, https://doi.org/10.1016/S0022-328X(00)82914-9 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Novak and Potts, 1984
Novak, I.; Potts, A.W., The UV gas-phase photoelectron spectra of Group IVB tetraphenyl derivatives, J. Organomet. Chem., 1984, 262, 17. [all data]


Notes

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