Ammonium Chloride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub177.kJ/molN/ALuft, 1955 

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference
168.6550.ICallanan and Smith, 1971
176.6 ± 0.4308. to 363.TEWagner and Neumann, 1961

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C9H27NSn3 (cr) + (Hydrogen chloride • 55Water) (solution) + 3Water (l) = (Ammonium Chloride • 55Water) (solution) + 3C3H10OSn (cr)

By formula: C9H27NSn3 (cr) + (HCl • 55H2O) (solution) + 3H2O (l) = (H4ClN • 55H2O) (solution) + 3C3H10OSn (cr)

Quantity Value Units Method Reference Comment
Δr-293.7 ± 1.3kJ/molRSCBaldwin, Lappert, et al., 1972 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
0.540 ± 0.050LPESEustis, Whiteside, et al., 2010B

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
H3N+10.10 ± 0.05HClPIEvlasheva, Potapov, et al., 1975LLK
H4N+10.10 ± 0.05ClPIEvlasheva, Potapov, et al., 1975LLK

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-9217
NIST MS number 228589

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References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Luft, 1955
Luft, N.W., Ind. Chemist, 1955, 31, 502. [all data]

Callanan and Smith, 1971
Callanan, Jane E.; Smith, Norman O., Sublimation pressures of solid solutions III. NH4Cl + NH4Br, The Journal of Chemical Thermodynamics, 1971, 3, 4, 531-538, https://doi.org/10.1016/S0021-9614(71)80036-8 . [all data]

Wagner and Neumann, 1961
Wagner, Horst; Neumann, Kurt, Der Dampfdruck des Ammoniumchlorids zwischen 35 und 90°C, Zeitschrift für Physikalische Chemie, 1961, 28, 12, 51-70, https://doi.org/10.1524/zpch.1961.28.12.051 . [all data]

Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S., J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]

Eustis, Whiteside, et al., 2010
Eustis, S.N.; Whiteside, A.; Wang, D.; Gutowski, M.; Bowen, K.H., Ammonia-Hydrogen Bromide and Ammonia-Hydrogen Iodide Complexes: Anion Photoelectron and ab Initio Studies, J. Phys. Chem. A, 2010, 114, 3, 1357-1363, https://doi.org/10.1021/jp906238v . [all data]

Evlasheva, Potapov, et al., 1975
Evlasheva, T.I.; Potapov, V.K.; Tulupov, V.A., The structure of the ammonium chloride molecule, Russ. J. Phys. Chem., 1975, 49, 738. [all data]


Notes

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