Dinitrogen tetroxide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas2.17kcal/molReviewChase, 1998Data last reviewed in September, 1964
Quantity Value Units Method Reference Comment
gas,1 bar72.749cal/mol*KReviewChase, 1998Data last reviewed in September, 1964

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 500. to 1000.1000. to 6000.
A 8.13880130.74140
B 45.885400.603333
C -36.10361-0.124494
D 10.610300.008755
E -0.037990-2.762199
F -2.125581-14.15540
G 70.2132999.67600
H 2.1699302.169930
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in September, 1964 Data last reviewed in September, 1964

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

0.76Nitrogen dioxide + 0.62Dinitrogen tetroxide + Methyl nitrate = Dinitrogen pentoxide + Methyl nitrite

By formula: 0.76NO2 + 0.62N2O4 + CH3NO3 = N2O5 + CH3NO2

Quantity Value Units Method Reference Comment
Δr8.662kcal/molCmRay and Ogg, 1959liquid phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.8 ± 0.2PEFrost, McDowell, et al., 1977LLK
11.4 ± 0.1PEChong, Frost, et al., 1982Vertical value; LBLHLM
11.5 ± 0.1PENomoto, Achiba, et al., 1979Vertical value; LLK
11.4 ± 0.1PENomoto, Achiba, et al., 1979, 2Vertical value; LLK
11.4 ± 0.1PEGan, Peel, et al., 1977Vertical value; LLK
11.PEYamazaki and Kimura, 1976Vertical value; LLK
11.6PEAmes and Turner, 1976Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Ray and Ogg, 1959
Ray, J.D.; Ogg, R.A., Jr., The heat of formation of methyl nitrate, J. Phys. Chem., 1959, 63, 1522-1523. [all data]

Frost, McDowell, et al., 1977
Frost, D.C.; McDowell, C.A.; Westwood, N.P.C., The photoelectron spectrum of dinitrogen tetroxide, J. Electron Spectrosc. Relat. Phenom., 1977, 10, 293. [all data]

Chong, Frost, et al., 1982
Chong, D.P.; Frost, D.C.; Lau, W.M.; McDowell, C.A., Shake-up satellites in HeI photoelectron spectra: N2O4 and CH3NO, Chem. Phys. Lett., 1982, 90, 332. [all data]

Nomoto, Achiba, et al., 1979
Nomoto, K.; Achiba, Y.; Kimura, K., HeII(304 Å) photoelectron spectrum of N2O4, Chem. Phys. Lett., 1979, 63, 277. [all data]

Nomoto, Achiba, et al., 1979, 2
Nomoto, K.; Achiba, Y.; Kimura, K., HeI and HeII photoelectron study of N2O4, Bull. Chem. Soc. Jpn., 1979, 52, 1614. [all data]

Gan, Peel, et al., 1977
Gan, T.H.; Peel, J.B.; Willett, G.D., Reinterpretation of the photoelectron spectrum of dinitrogen tetroxide, J. Chem. Soc. Faraday Trans. 2, 1977, 73, 1459. [all data]

Yamazaki and Kimura, 1976
Yamazaki, T.; Kimura, K., He I photoelectron spectrum of dinitrogen tetraoxide (N2O4), Chem. Phys. Lett., 1976, 43, 502. [all data]

Ames and Turner, 1976
Ames, D.L.; Turner, D.W., Photoelectron spectroscopic studies of dinitrogen tetroxide and dinitrogen pentoxide, Proc. R. Soc. London A:, 1976, 348, 175. [all data]


Notes

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