vanadium oxide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas127.61kJ/molReviewChase, 1998Data last reviewed in December, 1973
Quantity Value Units Method Reference Comment
gas,1 bar230.90J/mol*KReviewChase, 1998Data last reviewed in December, 1973

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 3500. to 6000.
A 44.16923
B -6.802305
C 2.368241
D -0.191252
E -3.325443
F 106.9112
G 275.8377
H 127.6120
ReferenceChase, 1998
Comment Data last reviewed in December, 1973

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to OV+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.2290 ± 0.0080LPESWu and Wang, 1998B

Ionization energy determinations

IE (eV) Method Reference Comment
7.2386 ± 0.0006TEHarrington and Weisshaar, 1992LL
7.5DERLias, Bartmess, et al., 1988LL
8.4EIBalducci, Gigli, et al., 1983LBLHLM
8. ± 1.EIFarber, Uy, et al., 1972LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Wu and Wang, 1998
Wu, H.; Wang, L.-S., A Photoelectron Spectroscopic Study of Monovanadium Oxide Anions (VOx-, x=1-4), J. Phys. Chem., 1998, 108, 13, 5310, https://doi.org/10.1063/1.475966 . [all data]

Harrington and Weisshaar, 1992
Harrington, J.; Weisshaar, J.C., State-to-state photoionization of VO: Propensity for large positive changes in rotational quantum number, J. Chem. Phys., 1992, 97, 2809. [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-phase ion and neutral thermochemistry, J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]

Balducci, Gigli, et al., 1983
Balducci, G.; Gigli, G.; Guido, M., Thermodynamic study of gaseous ternary oxide molecules. The europium-vanadium-oxygen system, J. Chem. Phys., 1983, 79, 5623. [all data]

Farber, Uy, et al., 1972
Farber, M.; Uy, O.M.; Srivastava, R.D., Effusion-mass spectrometric determination of the heats of formation of the gaseous molecules V4O10, V4O8, VO2, and VO, J. Chem. Phys., 1972, 56, 5312. [all data]


Notes

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