cyclohexyl isocyanide


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
0.951277.7DSCSingh and Murthy, 2008AC
1.01279.6N/ADomalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
7.665192.6Domalski and Hearing, 1996CAL
3.614279.6

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.476192.6crystaline, IIcrystaline, IKishimoto, Pinvidic, et al., 1991DH
1.010279.6crystaline, IliquidKishimoto, Pinvidic, et al., 1991DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
7.665192.6crystaline, IIcrystaline, IKishimoto, Pinvidic, et al., 1991DH
3.614279.6crystaline, IliquidKishimoto, Pinvidic, et al., 1991DH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.72 ± 0.05EIDistefano, Innorta, et al., 1968RDSH
11.0PEYoung and Cheng, 1976Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Singh and Murthy, 2008
Singh, L.P.; Murthy, S.S.N., Study of secondary relaxation in disordered plastic crystals of isocyanocyclohexane, cyanocyclohexane, and 1-cyanoadamantane, J. Chem. Phys., 2008, 129, 9, 094501, https://doi.org/10.1063/1.2961036 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Kishimoto, Pinvidic, et al., 1991
Kishimoto, I.; Pinvidic, J.J.; Matsuo, T.; Suga, H., Phase transition and glass transitions in isocyanocyclohexane studied by a polaro-calorimeter, Proc. Jpn. Acad., Ser, 1991, B 67(4), 66-71. [all data]

Distefano, Innorta, et al., 1968
Distefano, G.; Innorta, G.; Pignataro, S.; Foffani, A., Correlation between the ionization potentials of transition metal complexes and of the corresponding ligands, J. Organometal. Chem., 1968, 14, 165. [all data]

Young and Cheng, 1976
Young, V.Y.; Cheng, K.L., The ultraviolet photoelectron spectra of aliphatic aromatic isonitriles, J. Electron Spectrosc. Relat. Phenom., 1976, 9, 317. [all data]


Notes

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