Pentafluoroethyliodide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil285.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil285. to 286.KN/AFarchan Laboratories, 1990BS
Tboil285. to 286.KN/APCR Inc., 1990BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
20.8268.AStephenson and Malanowski, 1987Based on data from 248. to 283. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.7 ± 0.1EIHsieh and Hanrahan, 1977LLK
10.44PEGolovin, Akopyan, et al., 1989Vertical value; LL

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CF2I+13.8 ± 0.1?PIPECOGolovin, Akopyan, et al., 1989LL
CF3+13.7 ± 0.05CF2+IPIPECOGolovin, Akopyan, et al., 1989LL
CF3+13.7 ± 0.1CF2,IEIHsieh and Hanrahan, 1977LLK
C2F4I+15.0 ± 0.1FPIPECOGolovin, Akopyan, et al., 1989LL
C2F5+11.0 ± 0.1IEIGolovin, Akopyan, et al., 1989LL
C2F5+11.2 ± 0.1IPIPECOGolovin, Akopyan, et al., 1989LL
C2F5+11.7 ± 0.1IEIHsieh and Hanrahan, 1977LLK
I+13.8 ± 0.1?PIPECOGolovin, Akopyan, et al., 1989LL

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Farchan Laboratories, 1990
Farchan Laboratories, Research Chemicals Catalog, Farchan Laboratories, Gainesville, FL, 1990, 91. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Hsieh and Hanrahan, 1977
Hsieh, T.; Hanrahan, R.J., An electron impact investigation of pentafluoroethyl iodide, Int. J. Mass Spectrom. Ion Phys., 1977, 23, 201. [all data]

Golovin, Akopyan, et al., 1989
Golovin, A.V.; Akopyan, M.E.; Reingand, L.M.; Chistyakov, A.B., Energetics and mechanism of C2F5I photoionization processes, High Energy Chem., 1989, 23, 301, In original 387. [all data]


Notes

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