Methyldichlorophosphine


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
35.5282.AStephenson and Malanowski, 1987Based on data from 229. to 297. K. See also Holmes and Wagner, 1963.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.5PELappert, Pedley, et al., 1975LLK
9.85PELappert, Pedley, et al., 1975Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Holmes and Wagner, 1963
Holmes, Robert R.; Wagner, Raymond P., The Systems Phosphorus Trifluoride-Trimethylamine, Phosphorus Trifluoride-Triethylamine, and Methyldichlorophosphine-Trimethylamine, Inorg. Chem., 1963, 2, 2, 384-388, https://doi.org/10.1021/ic50006a035 . [all data]

Lappert, Pedley, et al., 1975
Lappert, M.F.; Pedley, J.B.; Wilkins, B.T.; Stelzer, O.; Unger, E., Bonding studies of compounds of boron and the group 3-5 elements. Part XIII. He(I) photoelectron spectra of phosphines RnPX3-n (R=Me or Bu'; X=H, Cl, or F; n=1-3), (Me2N)nPCl3-n(n=1-3), and (R2N)PF2(R=Me or Et), J. Chem. Soc. Dalton Trans., 1975, 1207. [all data]


Notes

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