copper chloride


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas21.77kcal/molReviewChase, 1998Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
gas,1 bar56.692cal/mol*KReviewChase, 1998Data last reviewed in March, 1966

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 3000. to 6000.
A 8.897881
B 0.149851
C -0.010285
D 0.000877
E -0.046379
F 18.95500
G 67.15490
H 21.77010
ReferenceChase, 1998
Comment Data last reviewed in March, 1966

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-31.353kcal/molReviewChase, 1998Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
liquid,1 bar22.41cal/mol*KReviewChase, 1998Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
Δfsolid-33.000kcal/molReviewChase, 1998Data last reviewed in March, 1966
Quantity Value Units Method Reference Comment
solid20.80cal/mol*KReviewChase, 1998Data last reviewed in March, 1966

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 703. to 3000.
A 16.00000
B -8.842321×10-11
C 5.178650×10-11
D -9.322321×10-12
E -2.345410×10-12
F -36.12271
G 41.76991
H -31.35229
ReferenceChase, 1998
Comment Data last reviewed in March, 1966

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 298. to 703.
A 17.99020
B -6.413031
C 6.140431
D -1.758600
E -0.441622
F -39.61040
G 41.74579
H -33.00000
ReferenceChase, 1998
Comment Data last reviewed in March, 1966

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to ClCu+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
10.7EIBloom and Williams, 1981LLK
10.7 ± 0.3EIGuido, Gigli, et al., 1972LLK
10.7 ± 0.3EIHildenbrand, 1970RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Bloom and Williams, 1981
Bloom, H.; Williams, D.J., A mass spectrometric study of the vapors above the molten salt systems LiCl-CuCl, LiBr-CuBr, and NaI-CuI, J. Chem. Phys., 1981, 75, 4636. [all data]

Guido, Gigli, et al., 1972
Guido, M.; Gigli, G.; Balducci, G., Dissociation energy of CuCl and Cu2Cl2 gaseous molecules, J. Chem. Phys., 1972, 57, 3731. [all data]

Hildenbrand, 1970
Hildenbrand, D.L., Dissociation energies and chemical bonding in the alkaline-earth chlorides from mass spectrometric studies, J. Chem. Phys., 1970, 52, 5751. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References