Tetrakil(trimethylsilyl)silane


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub20.0 ± 5.0kcal/molN/APilcher and Skinner, 1983See also Pedley and Iseard, 1972.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.41 ± 0.01EIPitt, Bursey, et al., 1970RDSH
8.24PEBock and Ensslin, 1971Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Pedley and Iseard, 1972
Pedley, J.B.; Iseard, B.S., , CATCH Tables, Silicon Compounds, University of Sussex, Brighton, 1972. [all data]

Pitt, Bursey, et al., 1970
Pitt, C.G.; Bursey, M.M.; Rogerson, P.F., Catenates of the group IV elements. Correlation of σ electron energies, J. Am. Chem. Soc., 1970, 92, 519. [all data]

Bock and Ensslin, 1971
Bock, H.; Ensslin, W., Bond-bond interaction in polysilanes, Angew. Chem. Int. Ed. Engl., 1971, 10, 404. [all data]


Notes

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