Mercury, diphenyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas98. ± 20.kcal/molAVGN/AAverage of 7 values; Individual data points

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus397.65KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δsub27.0 ± 0.2kcal/molCC-SBCarson, Stranks, et al., 1958MS
Δsub27.0 ± 0.2kcal/molMECarson, Stranks, et al., 1958, 2Based on data from 314. to 303. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.32PEFurlani, Piancastelli, et al., 1981LLK
9.4 ± 0.2EIGlockling, Irwin, et al., 1976LLK
8.30 ± 0.03PIRodionov, Potapov, et al., 1973LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C6H5Hg+11.5 ± 0.2C6H5EIGlockling, Irwin, et al., 1976LLK
Hg+10.0 ± 0.2?EIGlockling, Irwin, et al., 1976LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Carson, Stranks, et al., 1958
Carson, A.S.; Stranks, D.R.; Wilmshurst, B., Proc. Roy. Soc. (London), 1958, A244, 72. [all data]

Carson, Stranks, et al., 1958, 2
Carson, A.S.; Stranks, D.R.; Wilmshurst, B.R., The Measurement of Very Low Vapour Pressures Using Radioactive Isotopes: The Latent Heat of Sublimation of Mercury Diphenyl, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 1958, 244, 1236, 72-84, https://doi.org/10.1098/rspa.1958.0026 . [all data]

Furlani, Piancastelli, et al., 1981
Furlani, C.; Piancastelli, M.N.; Cauletti, C.; Faticanti, F.; Ortaggi, G., He(I) and He(II) photoelectron spectra of some organomercury compounds with carbon π-systems, J. Electron Spectrosc. Relat. Phenom., 1981, 22, 309. [all data]

Glockling, Irwin, et al., 1976
Glockling, F.; Irwin, J.G.; Morrison, R.J.; Sweeney, J.J., A mass spectroscopic study of organomercurials and mercuric halides, Inorg. Chim. Acta, 1976, 19, 267. [all data]

Rodionov, Potapov, et al., 1973
Rodionov, A.N.; Potapov, V.K.; Rogozhin, K.L., Photoionization of certain aromatic heteroorganic compounds, High Energy Chem., 1973, 7, 249, In original 278. [all data]


Notes

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