Trimethylphosphine sulfide


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Reference Comment
16.8380.Burg, 1966Based on data from 366. to 394. K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.48PEStarzewski and Dieck, 1979Vertical value
8.48 ± 0.035PEElbel and Dieck, 1976Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Burg, 1966
Burg, Anton B., A Thiopolyphosphine Heterocycle 1, J. Am. Chem. Soc., 1966, 88, 18, 4298-4299, https://doi.org/10.1021/ja00970a059 . [all data]

Starzewski and Dieck, 1979
Starzewski, K.A.O.; Dieck, H.t., Electronic structure and reactivity. 8. Iminophosphoranes- simple ylide analogues? An investigation of quantitative and sphenomenological differences, Inorg. Chem., 1979, 18, 3307. [all data]

Elbel and Dieck, 1976
Elbel, S.; Dieck, H.t., Photoelectron spectra of group 5 compounds. Part IV. A study of the E-X bond in R3EX compounds (R = Me or F; E = N or P; X = O or S), J. Chem. Soc. Dalton Trans., 1976, 1757. [all data]


Notes

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