Osmocene

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Phase change data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Tboil571.KN/ABaev, Barkatin, et al., 1979Uncertainty assigned by TRC = 0.00001 K; TRC
Quantity Value Units Method Reference Comment
Tfus506.8KN/ABaev, Barkatin, et al., 1979Crystal phase 1 phase; Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Δsub19.2 ± 0.41kcal/molN/ABaev and Barkatin, 1984AC
Δsub19.2 ± 0.41kcal/molCC-SBBaev and Barkatin, 1984Another value for the enthalpy of vaporization has been reported: 18.0 kcal/mol Fischer and Grubert, 1959; MS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
13.5 ± 0.31535.Baev and Barkatin, 1984Based on data from 506. to 563. K.; AC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Reference Comment
17.4 ± 0.33393. to 506.Baev and Barkatin, 1984AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
~7.0EQRyan, Eyler, et al., 1992LL
7.6 ± 0.1EIMuller and D'Or, 1967RDSH

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baev, Barkatin, et al., 1979
Baev, A.K.; Barkatin, A.A.; Gubin, S.P.; Dyagileva, S.P., Thermodynamics of phase transitions and vapor state of some compounds of elements with incomplete d-shells in Vses. Konf. po Kalorimetrii i Khim. Termodinamike, 8th, Ivanovo, p 386-389, 1979. [all data]

Baev and Barkatin, 1984
Baev, A.K.; Barkatin, A.A., Russ. J. Phys. Chem., 1984, 58, 195. [all data]

Fischer and Grubert, 1959
Fischer, E.O.; Grubert, H., Chem. Ber., 1959, 92, 2302. [all data]

Ryan, Eyler, et al., 1992
Ryan, M.F.; Eyler, J.R.; Richardson, D.E., Adiabatic ionization energies, bond disruption enthalpies, and solvation free energies for gas-phase metallocenes and metallocenium ions, J. Am. Chem. Soc., 1992, 114, 8611. [all data]

Muller and D'Or, 1967
Muller, J.; D'Or, L., Massenspektrometrische Untersuchungen an Dicyclopentadienylkomplexen von Ubergangsmetallen, J.Organometal. Chem., 1967, 10, 313. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, References