Silane, bromo-

• Formula: BrH₃Si
• Molecular weight: 111.013
• IUPAC Standard InChI: InChI=1S/BrH3Si/c1-2/h2H3 Copy

  
• IUPAC Standard InChIKey: VQPFDLRNOCQMSN-UHFFFAOYSA-N Copy
• CAS Registry Number: 13465-73-1
• Chemical structure:
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• Information on this page:
  • Gas phase thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Vibrational and/or electronic energy levels
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Causley, Clark, et al., 1976
Causley, G.C.; Clark, J.B.; Russell, B.R., The vacuum ultraviolet spectrum of bromosilane, Chem. Phys. Lett., 1976, 38, 602. [all data]

Frost, Herring, et al., 1971
Frost, D.C.; Herring, F.G.; Katrib, A.; McLean, R.A.N.; Drake, J.E.; Westwood, N.P.C., Photoelectron spectra and bonding in some halosilanes, Can. J. Chem., 1971, 49, 4033. [all data]

Cradock and Whiteford, 1971
Cradock, S.; Whiteford, R.A., Photo-electron spectra of the mono and dihalo silanes and germanes, J. Chem. Soc. Faraday Trans., 1971, 67, 3425. [all data]

Cradock and Ebsworth, 1971
Cradock, S.; Ebsworth, E.A.V., Photo-electron spectra of silyl and germyl halides (p→d)π-bonding, Chem. Commun., 1971, 57. [all data]

Notes

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• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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