Selenium(IV) oxide

• Formula: O₂Se
• Molecular weight: 110.96
• IUPAC Standard InChI: InChI=1S/O2Se/c1-3-2 Copy

  
• IUPAC Standard InChIKey: JPJALAQPGMAKDF-UHFFFAOYSA-N Copy
• CAS Registry Number: 7446-08-4
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Selenium oxide; Selenium dioxide; SeO2; Selenious anhydride; Selenium oxide (SeO2); Selenium(iv) dioxide (1:2); Rcra waste number U204; Selenous acid anhydride
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Vibrational and/or electronic energy levels
• Data at other public NIST sites:
  • Microwave spectra (on physics lab web site)
  • X-ray Photoelectron Spectroscopy Database, version 5.0
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

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Phase change data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to O₂Se⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Snodgrass, Coe, et al., 1989
Snodgrass, J.T.; Coe, J.V.; McHugh, K.M.; Freidhoff, C.B.; Bowen, K.H., Photoelectron Spectroscopy of the Selenium and Tellurium Containing Negative Ions: SeO₂^-, Se₂^- and Te₂^-, J. Phys. Chem., 1989, 93, 4, 1249, https://doi.org/10.1021/j100341a016 . [all data]

Ficalora, Thompson, et al., 1969
Ficalora, P.J.; Thompson, J.C.; Margrave, J.L., Mass spectrometric studies at high temperatures-XXVI.The sublimation of SeO, and SeO₃, J. Inorg. Nucl. Chem., 1969, 31, 3771. [all data]

Potts, 1977
Potts, A.W., The valence electronic structure of SeO₂ studied by UPS its relation to that of other group VIB dioxides, J. Electron Spectrosc. Relat. Phenom., 1977, 11, 157. [all data]

Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  AE	Appearance energy
  EA	Electron affinity

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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