Methyl Alcohol

Formula: CH₄O
Molecular weight: 32.0419
IUPAC Standard InChI: InChI=1S/CH4O/c1-2/h2H,1H3
IUPAC Standard InChIKey: OKKJLVBELUTLKV-UHFFFAOYSA-N
CAS Registry Number: 67-56-1
Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript.
Isotopologues:
Other names: Methanol; Carbinol; Methyl hydroxide; Methylol; Monohydroxymethane; Wood alcohol; CH3OH; Colonial spirit; Columbian spirit; Hydroxymethane; Wood naphtha; Alcool methylique; Alcool metilico; Columbian spirits; Metanolo; Methylalkohol; Metylowy alkohol; Pyroxylic spirit; Wood spirit; Rcra waste number U154; UN 1230; Pyro alcohol; Spirit of wood; Bieleski's solution; NSC 85232
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Information on this page:
Other data available:
- Reaction thermochemistry data: reactions 51 to 100, reactions 101 to 150, reactions 151 to 200, reactions 201 to 250, reactions 251 to 300
- Henry's Law data
- Ion clustering data
- Vibrational and/or electronic energy levels
- Fluid Properties
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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity	Value	Units	Method	Reference	Comment
Δ_fH°_gas	-205. ± 10.	kJ/mol	AVG	N/A	Average of 9 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
Δ_cH°_gas	-763.68 ± 0.20	kJ/mol	Cm	Rossini, 1932	Flame Calorimetry; Corresponding Δ_fHº_gas = -201.49 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of gas

C_p,gas (J/mol*K)	Temperature (K)	Reference	Comment
34.00	50.	Thermodynamics Research Center, 1997	p=1 bar. Recommended entropies and heat capacities are in good agreement with other statistically calculated values [ Ivash E.V., 1955, Zhuravlev E.Z., 1959, Chen S.S., 1977, Chao J., 1986, Gurvich, Veyts, et al., 1989]. Please also see Chao J., 1986, 2.; GT
36.95	100.
38.64	150.
39.71	200.
42.59	273.15
44.06 ± 0.03	298.15
44.17	300.
51.63	400.
59.70	500.
67.19	600.
73.86	700.
79.76	800.
84.95	900.
89.54	1000.
93.57	1100.
97.12	1200.
100.24	1300.
102.98	1400.
105.40	1500.
110.2	1750.
113.8	2000.
116.5	2250.
118.6	2500.
120.	2750.
121.	3000.

Constant pressure heat capacity of gas

C_p,gas (J/mol*K)	Temperature (K)	Reference	Comment
42.4 ± 1.3	279.	Stromsoe E., 1970	Heat capacity at 279 K was obtained by thermal conductivity [ Halford J.O., 1957]. Vapor heat capacities from calorimetric measurements [ De Vries T., 1941] were converted to the ideal gas heat capacities by corrections for the gas imperfection effects [ Chen S.S., 1977, Chao J., 1986, 2]. Ideal gas heat capacities are given by [ Stromsoe E., 1970] as a linear function Cp=f1(a+bT). This expression approximates the experimental values with the average deviation of 1.17 J/molK. The accuracy of the experimental heat capacities [ Stromsoe E., 1970] is estimated as less than 0.3%. Please also see De Vries T., 1941, Weltner W., 1951, Halford J.O., 1957.; GT
48.0 ± 1.3	345.6
46.8 ± 1.2	347.35
46.1 ± 1.3	349.65
47.6 ± 1.2	356.55
46.7 ± 1.3	358.15
48.2 ± 1.3	358.85
48.8 ± 1.3	359.85
50.3 ± 1.3	368.15
49.0 ± 1.2	373.35
51.3 ± 1.3	382.15
51.1 ± 1.2	398.95
52.3 ± 1.3	401.15
51.3 ± 1.2	401.35
52.01 ± 0.42	403.2
53.2 ± 1.3	420.15
53.9 ± 1.2	431.45
54.8 ± 1.2	442.15
55.9 ± 1.3	442.65
56.0 ± 1.2	457.35
57.20 ± 0.42	464.0
57.8 ± 1.2	477.75
58.4 ± 1.2	485.05
59.5 ± 1.2	498.95
60.4 ± 1.3	521.2
61.4 ± 1.2	521.35
64.3 ± 1.2	555.95
66.4 ± 1.2	581.35
66.8 ± 1.2	585.35

Condensed phase thermochemistry data

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Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity	Value	Units	Method	Reference	Comment
Δ_fH°_liquid	-238.4	kJ/mol	Ccr	Baroody and Carpenter, 1972	ALS
Δ_fH°_liquid	-239.5 ± 0.2	kJ/mol	Ccb	Chao and Rossini, 1965	see Rossini, 1934; ALS
Δ_fH°_liquid	-238.9 ± 3.6	kJ/mol	Ccb	Green, 1960	Reanalyzed by Cox and Pilcher, 1970, Original value = -238.5 ± 0.2 kJ/mol; ALS
Δ_fH°_liquid	-250.6	kJ/mol	Ccb	Parks, 1925	ALS
Δ_fH°_liquid	-251.3 ± 5.0	kJ/mol	Ccb	Richards and Davis, 1920	DRB
Quantity	Value	Units	Method	Reference	Comment
Δ_cH°_liquid	-725.7 ± 0.1	kJ/mol	Ccb	Chao and Rossini, 1965	see Rossini, 1934; Corresponding Δ_fHº_liquid = -239.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δ_cH°_liquid	-726.5 ± 0.2	kJ/mol	Ccb	Green, 1960	Corresponding Δ_fHº_liquid = -238.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δ_cH°_liquid	-726.34 ± 0.20	kJ/mol	Ccb	Rossini, 1931	Corresponding Δ_fHº_liquid = -238.83 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δ_cH°_liquid	-715.05	kJ/mol	Ccb	Parks, 1925	Corresponding Δ_fHº_liquid = -250.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δ_cH°_liquid	-713.83	kJ/mol	Ccb	Richards and Davis, 1920	At 291 K; Corresponding Δ_fHº_liquid = -251.34 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity	Value	Units	Method	Reference	Comment
S°_liquid	127.19	J/mol*K	N/A	Carlson and Westrum, 1971	DH
S°_liquid	126.8	J/mol*K	N/A	Kelley, 1929	DH
S°_liquid	129.7	J/mol*K	N/A	Parks, Kelley, et al., 1929	Extrapolation below 90 K, 34.3 J/mol*K. Revision of previous data.; DH
S°_liquid	136.4	J/mol*K	N/A	Parks, 1925	Extrapolation below 90 K, 40.75 J/mol*K.; DH
Quantity	Value	Units	Method	Reference	Comment
S°_{solid,1 bar}	1.117	J/mol*K	N/A	Ahlberg, Blanchard, et al., 1937	DH

Constant pressure heat capacity of liquid

C_p,liquid (J/mol*K)	Temperature (K)	Reference	Comment
79.5	298.15	Filatov and Afanas'ev, 1992	DH
81.11	298.15	Khasanshin and Zykova, 1989	T = 175 to 338 K. Unsmoothed experimental datum.; DH
80.24	298.15	Andreoli-Ball, Patterson, et al., 1988	DH
80.35	298.15	Okano, Ogawa, et al., 1988	DH
81.0	298.15	Lankford and Criss, 1987	DH
81.32	298.	Korolev, Kukharenko, et al., 1986	DH
80.28	298.15	Ogawa and Murakami, 1986	DH
81.56	298.15	Tanaka, Toyama, et al., 1986	DH
80.22	298.15	Costas and Patterson, 1985	T = 298.15, 313.15 K.; DH
81.47	298.15	Zegers and Somsen, 1984	DH
78.90	288.15	Benson and D'Arcy, 1982	DH
81.92	298.15	Villamanan, Casanova, et al., 1982	DH
80.8	293.15	Atalla, El-Sharkawy, et al., 1981	DH
81.13	298.15	Carlson and Westrum, 1971	T = 5 to 332 K.; DH
83.7	298.	Deshpande and Bhatagadde, 1971	T = 298 to 318 K.; DH
85.8	313.2	Paz Andrade, Paz, et al., 1970	DH
85.8	298.2	Katayama, 1962	T = 10 to 60°C.; DH
80.8	311.	Swietoslawski and Zielenkiewicz, 1960	Mean value 21 to 56°C.; DH
86.2	323.	Hough, Mason, et al., 1950	T = 323 to 353 K.; DH
75.77	270.	Staveley and Gupta, 1949	T = 90 to 270 K.; DH
86.6	300.8	Phillip, 1939	DH
83.56	313.15	Fiock, Ginnings, et al., 1931	T = 40 to 110°C.; DH
79.9	292.0	Kelley, 1929	T = 16 to 293 K. Value is unsmoothed experimental datum.; DH
78.2	270.	Mitsukuri and Hara, 1929	T = 190 to 270 K.; DH
79.9	290.1	Parks, 1925	T = 89 to 290 K. Value is unsmoothed experimental datum.; DH
83.3	298.	von Reis, 1881	T = 288 to 335 K.; DH

Constant pressure heat capacity of solid

C_p,solid (J/mol*K)	Temperature (K)	Reference	Comment
68.39	120.	Sugisaki, Suga, et al., 1968	glass phase; T = 20 to 120 K.; DH
5.40	20.5	Ahlberg, Blanchard, et al., 1937	T = 5 to 28 K.; DH
105.	173.	Maass and Walbauer, 1925	T = 93 to 173 K.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity	Value	Units	Method	Reference	Comment
T_boil	337.8 ± 0.3	K	AVG	N/A	Average of 154 out of 171 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
T_fus	176. ± 1.	K	AVG	N/A	Average of 13 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
T_triple	175.5 ± 0.5	K	AVG	N/A	Average of 8 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
T_c	513. ± 1.	K	AVG	N/A	Average of 27 out of 31 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
P_c	81. ± 1.	bar	AVG	N/A	Average of 17 out of 20 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
V_c	0.117	l/mol	N/A	Gude and Teja, 1995
V_c	0.113024	l/mol	N/A	Craven and de Reuck, 1986	TRC
V_c	0.118	l/mol	N/A	Francesconi, Lentz, et al., 1981	Uncertainty assigned by TRC = 0.004 l/mol; TRC
V_c	0.11663	l/mol	N/A	Zubarev and Bagdonas, 1969	Uncertainty assigned by TRC = 0.0035 l/mol; TRC
Quantity	Value	Units	Method	Reference	Comment
ρ_c	8.51 ± 0.07	mol/l	AVG	N/A	Average of 7 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
Δ_vapH°	37.6 ± 0.5	kJ/mol	AVG	N/A	Average of 11 out of 12 values; Individual data points

Enthalpy of vaporization

Δ_vapH (kJ/mol)	Temperature (K)	Method	Reference	Comment
35.21	337.7	N/A	Majer and Svoboda, 1985
39.2	258.	A	Stephenson and Malanowski, 1987	Based on data from 175. to 273. K.; AC
36.9	353.	A	Stephenson and Malanowski, 1987	Based on data from 338. to 487. K.; AC
43.7	213.	A	Stephenson and Malanowski, 1987	Based on data from 188. to 228. K.; AC
38.9	275.	A	Stephenson and Malanowski, 1987	Based on data from 224. to 290. K.; AC
38.3	300.	A	Stephenson and Malanowski, 1987	Based on data from 285. to 345. K.; AC
37.0	350.	A	Stephenson and Malanowski, 1987	Based on data from 335. to 376. K.; AC
36.1	388.	A	Stephenson and Malanowski, 1987	Based on data from 373. to 458. K.; AC
35.1	468.	A	Stephenson and Malanowski, 1987	Based on data from 453. to 513. K.; AC
32.7	373.	C	Yerlett and Wormald, 1986	AC
28.1	423.	C	Yerlett and Wormald, 1986	AC
20.6	473.	C	Yerlett and Wormald, 1986	AC
7.4	510.	C	Yerlett and Wormald, 1986	AC
37.5	331.	EB	Cervenkova and Boublik, 1984	Based on data from 316. to 336. K.; AC
38.3	303.	N/A	Gibbard and Creek, 1974	Based on data from 288. to 337. K. See also Boublik, Fried, et al., 1984.; AC
35.2 ± 0.1	338.	C	Counsell and Lee, 1973	AC
35.6 ± 0.1	331.	C	Counsell and Lee, 1973	AC
36.2 ± 0.1	321.	C	Counsell and Lee, 1973	AC
37.0 ± 0.1	306.	C	Counsell and Lee, 1973	AC
36.7 ± 0.1	313.	C	Svoboda, Veselý, et al., 1973	AC
36.2 ± 0.1	323.	C	Svoboda, Veselý, et al., 1973	AC
35.6 ± 0.1	333.	C	Svoboda, Veselý, et al., 1973	AC
35.3 ± 0.1	338.	C	Svoboda, Veselý, et al., 1973	AC
34.7 ± 0.1	343.	C	Svoboda, Veselý, et al., 1973	AC
37.0	352.	N/A	Wilhoit and Zwolinski, 1973	Based on data from 337. to 383. K.; AC
38.7	290.	EB	Boublík and Aim, 1972	Based on data from 275. to 336. K. See also Stephenson and Malanowski, 1987.; AC
38.3	303.	EB	Ambrose and Sprake, 1970	Based on data from 288. to 357. K.; AC
36.3	368.	N/A	Hirata, Suda, et al., 1967	Based on data from 353. to 483. K.; AC
38.4	293.	N/A	Klyueva, Mischenko, et al., 1960	Based on data from 278. to 323. K.; AC

Enthalpy of vaporization

Δ_vapH = A exp(-αT_r) (1 − T_r)^β
Δ_vapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
T_r = reduced temperature (T / T_c)

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Temperature (K)	298. to 477.
A (kJ/mol)	45.3
α	-0.31
β	0.4241
T_c (K)	512.6
Reference	Majer and Svoboda, 1985

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)

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Temperature (K)	A	B	C	Reference	Comment
353.5 to 512.63	5.15853	1569.613	-34.846	Ambrose, Sprake, et al., 1975	Coefficents calculated by NIST from author's data.
288.1 to 356.83	5.20409	1581.341	-33.50	Ambrose and Sprake, 1970	Coefficents calculated by NIST from author's data.
353. to 483.	5.31301	1676.569	-21.728	Hirata and Suda, 1967	Coefficents calculated by NIST from author's data.

Enthalpy of fusion

Δ_fusH (kJ/mol)	Temperature (K)	Reference	Comment
3.18	175.3	Domalski and Hearing, 1996	AC
2.196	176.	Maass and Walbauer, 1925	DH

Entropy of fusion

Δ_fusS (J/mol*K)	Temperature (K)	Reference	Comment
12.5	176.	Maass and Walbauer, 1925	DH

Entropy of fusion

Δ_fusS (J/mol*K)	Temperature (K)	Reference	Comment
3.7	161.1	Domalski and Hearing, 1996	CAL
18.1	175.3
4.0	157.3
18.3	175.6

Enthalpy of phase transition

ΔH_trs (kJ/mol)	Temperature (K)	Initial Phase	Final Phase	Reference	Comment
0.6360	157.34	crystaline, II	crystaline, I	Carlson and Westrum, 1971	DH
3.2154	175.59	crystaline, I	liquid	Carlson and Westrum, 1971	DH
1.540	103.	crystaline	glass	Sugisaki, Suga, et al., 1968	Glass transition.; DH
0.711	157.8	crystaline, II	crystaline, I	Staveley and Gupta, 1949	DH
3.159	175.4	crystaline, I	liquid	Staveley and Gupta, 1949	DH
0.6456	157.4	crystaline, II	crystaline, I	Kelley, 1929	DH
3.167	175.2	crystaline, I	liquid	Kelley, 1929	DH
0.590	161.1	crystaline, II	crystaline, I	Parks, 1925	DH
3.176	175.3	crystaline, I	liquid	Parks, 1925	DH

Entropy of phase transition

ΔS_trs (J/mol*K)	Temperature (K)	Initial Phase	Final Phase	Reference	Comment
4.04	157.34	crystaline, II	crystaline, I	Carlson and Westrum, 1971	DH
18.31	175.59	crystaline, I	liquid	Carlson and Westrum, 1971	DH
14.95	103.	crystaline	glass	Sugisaki, Suga, et al., 1968	Glass; DH
4.51	157.8	crystaline, II	crystaline, I	Staveley and Gupta, 1949	DH
18.01	175.4	crystaline, I	liquid	Staveley and Gupta, 1949	DH
4.10	157.4	crystaline, II	crystaline, I	Kelley, 1929	DH
18.08	175.2	crystaline, I	liquid	Kelley, 1929	DH
3.66	161.1	crystaline, II	crystaline, I	Parks, 1925	DH
18.12	175.3	crystaline, I	liquid	Parks, 1925	DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

+ Methyl Alcohol = ( • )

By formula: Cl^- + CH₄O = (Cl^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	69. ± 10.	kJ/mol	AVG	N/A	Average of 8 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	94.6	J/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M
Δ_rS°	101.	J/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	92.0	J/mol*K	PHPMS	Sieck, 1985	gas phase; M
Δ_rS°	95.8	J/mol*K	N/A	Larson and McMahon, 1984	gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δ_rS°	61.9	J/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; Entropy change is questionable; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	42. ± 3.	kJ/mol	AVG	N/A	Average of 10 values; Individual data points

CH₃O^- + = Methyl Alcohol

By formula: CH₃O^- + H⁺ = CH₄O

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	1597. ± 8.	kJ/mol	AVG	N/A	Average of 6 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1573.3 ± 2.6	kJ/mol	H-TS	Nee, Osterwalder, et al., 2006	gas phase; B
Δ_rG°	1573.4 ± 2.3	kJ/mol	H-TS	Osborn, Leahy, et al., 1998	gas phase; B
Δ_rG°	1565. ± 8.4	kJ/mol	IMRE	Bartmess, Scott, et al., 1979	gas phase; The acidity is 1.2 kcal/mol stronger than that from the D-EA cycle, due to the multi-compound fit for the acidity scale.; value altered from reference due to change in acidity scale; B
Δ_rG°	1567. ± 8.8	kJ/mol	H-TS	Haas and Harrison, 1993	gas phase; Both metastable and 50 eV collision energy.; B
Δ_rG°	1569.4 ± 2.5	kJ/mol	TDEq	Meot-ner and Sieck, 1986	gas phase; Experimental entropy: 21.5 eu, 0.6 less than H2O; B

CH₅O⁺ + Methyl Alcohol = (CH₅O⁺ • )

By formula: CH₅O⁺ + CH₄O = (CH₅O⁺ • CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	136.	kJ/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	135.	kJ/mol	PHPMS	Szulejko and McMahon, 1992	gas phase; M
Δ_rH°	134.	kJ/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; M
Δ_rH°	138.	kJ/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Δ_rH°	141.	kJ/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	121.	J/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	122.	J/mol*K	PHPMS	Szulejko and McMahon, 1992	gas phase; M
Δ_rS°	111.	J/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; M
Δ_rS°	128.	J/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Δ_rS°	119.	J/mol*K	N/A	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	105.	kJ/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

CH₃O^- + Methyl Alcohol = (CH₃O^- • )

By formula: CH₃O^- + CH₄O = (CH₃O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	123. ± 4.2	kJ/mol	TDAs	Paul and Kebarle, 1990	gas phase; B,M
Δ_rH°	120.5 ± 1.3	kJ/mol	TDAs	Meot-ner and Sieck, 1986	gas phase; B,M
Δ_rH°	123. ± 10.	kJ/mol	TDAs	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Δ_rH°	79.5 ± 8.4	kJ/mol	N/A	Moylan, Dodd, et al., 1985	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	133.	J/mol*K	PHPMS	Paul and Kebarle, 1990	gas phase; M
Δ_rS°	112.	J/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	84.94	kJ/mol	IMRE	Mustanir, Matsuoka, et al., 2006	gas phase; B
Δ_rG°	82.8 ± 4.2	kJ/mol	TDAs	Paul and Kebarle, 1990	gas phase; B
Δ_rG°	87.0 ± 2.1	kJ/mol	TDAs	Meot-ner and Sieck, 1986	gas phase; B
Δ_rG°	84.9 ± 6.7	kJ/mol	TDAs	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
79.9	296.	FA	MacKay and Bohme, 1978	gas phase; From thermochemical cycle,switching reaction(CH3O-)H2O; Meot-Ner(Mautner), 1986; M

C₄H₉O^- + Methyl Alcohol = (C₄H₉O^- • )

By formula: C₄H₉O^- + CH₄O = (C₄H₉O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	107. ± 4.2	kJ/mol	TDEq	Meot-Ner and Sieck, 1986	gas phase; B,M
Δ_rH°	97.9 ± 9.2	kJ/mol	CIDT	DeTuri and Ervin, 1999	gas phase; B
Δ_rH°	109. ± 10.	kJ/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	117.	J/mol*K	N/A	Meot-Ner and Sieck, 1986	gas phase; Entropy change calculated or estimated; M
Δ_rS°	123.	J/mol*K	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	42.68	kJ/mol	IMRE	Mustanir, Matsuoka, et al., 2006	gas phase; B
Δ_rG°	71.5 ± 6.7	kJ/mol	TDEq	Meot-Ner and Sieck, 1986	gas phase; B
Δ_rG°	72.4 ± 6.7	kJ/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M

C₂H₅O^- + Methyl Alcohol = (C₂H₅O^- • )

By formula: C₂H₅O^- + CH₄O = (C₂H₅O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	114. ± 12.	kJ/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Δ_rH°	107. ± 7.9	kJ/mol	CIDT	DeTuri and Ervin, 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	123.	J/mol*K	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	77.8 ± 8.4	kJ/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
56.1	296.	FA	Mackay, Rakshit, et al., 1982	gas phase; From thermochemical cycle,switching reaction(CH3O-)CH3OH; Caldwell and Kebarle, 1986, Taft, 1983; M

( • Methyl Alcohol ) + = ( • 2)

By formula: (Cl^- • CH₄O) + CH₄O = (Cl^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	59.0 ± 1.7	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	57.32 ± 0.84	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; B,M
Δ_rH°	59.0 ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Δ_rH°	54.4 ± 2.9	kJ/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	101.	J/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	92.0	J/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M
Δ_rS°	81.2	J/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	30.5	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	29.7	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rG°	28. ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B
Δ_rG°	30.1 ± 1.7	kJ/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (Cl^- • 2CH₄O) + CH₄O = (Cl^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	48.12 ± 0.84	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	45.2 ± 1.3	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; B,M
Δ_rH°	49.4 ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Δ_rH°	51.5 ± 2.5	kJ/mol	N/A	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	95.8	J/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	95.0	J/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M
Δ_rS°	98.7	J/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	21.2	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	16.7	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rG°	21. ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B
Δ_rG°	21.8 ± 1.3	kJ/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

C₈H₅^- + Methyl Alcohol = (C₈H₅^- • )

By formula: C₈H₅^- + CH₄O = (C₈H₅^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	90.0 ± 8.4	kJ/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; B
Δ_rH°	90. ± 12.	kJ/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	123.	J/mol*K	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	46.0 ± 8.4	kJ/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; B
Δ_rG°	53.1 ± 8.4	kJ/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

CN^- + Methyl Alcohol = (CN^- • )

By formula: CN^- + CH₄O = (CN^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	65.7 ± 3.3	kJ/mol	TDAs	Larson, Szulejko, et al., 1988	gas phase; B,M
Δ_rH°	69.5 ± 4.2	kJ/mol	TDAs	Meot-ner, 1988	gas phase; B
Δ_rH°	69. ± 15.	kJ/mol	IMRE	Larson and McMahon, 1987	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	96.	J/mol*K	PHPMS	Larson, Szulejko, et al., 1988	gas phase; M
Δ_rS°	102.	J/mol*K	N/A	Larson and McMahon, 1987	gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	36.8 ± 0.84	kJ/mol	TDAs	Larson, Szulejko, et al., 1988	gas phase; B
Δ_rG°	43.5 ± 4.2	kJ/mol	TDAs	Meot-ner, 1988	gas phase; B
Δ_rG°	38. ± 9.6	kJ/mol	IMRE	Larson and McMahon, 1987	gas phase; B,M

+ Methyl Alcohol = ( • )

By formula: Li⁺ + CH₄O = (Li⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	154. ± 7.9	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD
Δ_rH°	159.	kJ/mol	ICR	Woodin and Beauchamp, 1978	gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Δ_rH°	160.	kJ/mol	ICR	Staley and Beauchamp, 1975	gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	110.	J/mol*K	N/A	Woodin and Beauchamp, 1978	gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	127.	kJ/mol	ICR	Woodin and Beauchamp, 1978	gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

+ Methyl Alcohol = ( • )

By formula: I^- + CH₄O = (I^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	49.79 ± 0.84	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	47.3 ± 4.2	kJ/mol	TDAs	Caldwell and Kebarle, 1984	gas phase; B,M
Δ_rH°	46.9	kJ/mol	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Δ_rH°	46.	kJ/mol	PHPMS	Caldwell, Masucci, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	71.5	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Δ_rS°	74.5	J/mol*K	PHPMS	Caldwell and Kebarle, 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	24.1	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	25. ± 4.2	kJ/mol	TDAs	Caldwell and Kebarle, 1984	gas phase; B
Δ_rG°	24. ± 8.4	kJ/mol	IMRE	Tanabe, Morgon, et al., 1996	gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

C₂H₅O⁺ + Methyl Alcohol = (C₂H₅O⁺ • )

By formula: C₂H₅O⁺ + CH₄O = (C₂H₅O⁺ • CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	127.	kJ/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	113.	J/mol*K	N/A	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	93.3	kJ/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C₂H₇O⁺ + Methyl Alcohol = (C₂H₇O⁺ • )

By formula: C₂H₇O⁺ + CH₄O = (C₂H₇O⁺ • CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	124.	kJ/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	111.	J/mol*K	N/A	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	90.8	kJ/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C₃H₇O^- + Methyl Alcohol = (C₃H₇O^- • )

By formula: C₃H₇O^- + CH₄O = (C₃H₇O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	113. ± 12.	kJ/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	123.	J/mol*K	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	76.1 ± 8.4	kJ/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

+ Methyl Alcohol = ( • )

By formula: F^- + CH₄O = (F^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	124. ± 8.4	kJ/mol	IMRE	Larson and McMahon, 1983	gas phase; B,M
Δ_rH°	123. ± 9.2	kJ/mol	CIDT	DeTuri and Ervin, 1999	gas phase; B
Δ_rH°	97.5 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	105.	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Δ_rS°	94.6	J/mol*K	N/A	Larson and McMahon, 1983	gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	95.4 ± 8.4	kJ/mol	IMRE	Larson and McMahon, 1983	gas phase; B,M
Δ_rG°	66.1 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 3 Methyl Alcohol ) + = ( • 4)

By formula: (Cl^- • 3CH₄O) + CH₄O = (Cl^- • 4CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	43.9 ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Δ_rH°	43.93	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rH°	46.9 ± 2.5	kJ/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	95.8	J/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	110.	J/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	15. ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B
Δ_rG°	15.5	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rG°	13.8 ± 0.84	kJ/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

+ Methyl Alcohol = ( • )

By formula: Br^- + CH₄O = (Br^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	60.67 ± 0.42	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	58.2 ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	73.6	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	33.5 ± 0.42	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	36. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B
Δ_rG°	35. ± 8.4	kJ/mol	IMRE	Tanabe, Morgon, et al., 1996	gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

C₃H₉Si⁺ + Methyl Alcohol = (C₃H₉Si⁺ • )

By formula: C₃H₉Si⁺ + CH₄O = (C₃H₉Si⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	164.	kJ/mol	PHPMS	Wojtyniak and Stone, 1986	gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	124.	J/mol*K	N/A	Wojtyniak and Stone, 1986	gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
106.	468.	PHPMS	Wojtyniak and Stone, 1986	gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

+ Methyl Alcohol = ( • )

By formula: Na⁺ + CH₄O = (Na⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	97.1 ± 5.4	kJ/mol	CIDC	Amicangelo and Armentrout, 2001	Anchor NH3=24.41; RCD
Δ_rH°	91.6 ± 5.9	kJ/mol	CIDT	Armentrout and Rodgers, 2000	RCD
Δ_rH°	100. ± 0.8	kJ/mol	HPMS	Hoyau, Norrman, et al., 1999	RCD
Δ_rH°	111. ± 0.8	kJ/mol	HPMS	Guo, Conklin, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	85800.	J/mol*K	HPMS	Hoyau, Norrman, et al., 1999	RCD
Δ_rS°	102.	J/mol*K	HPMS	Guo, Conklin, et al., 1989	gas phase; M

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
72.4	298.	IMRE	McMahon and Ohanessian, 2000	Anchor alanine=39.89; RCD

( • 4 Methyl Alcohol ) + = ( • 5)

By formula: (Cl^- • 4CH₄O) + CH₄O = (Cl^- • 5CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	38. ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Δ_rH°	43.9 ± 2.1	kJ/mol	N/A	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	90.8	J/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	107.	J/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	11. ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B
Δ_rG°	12.1 ± 0.42	kJ/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

+ = 2 Methyl Alcohol +

By formula: H₂O + C₅H₁₂O₂ = 2CH₄O + C₃H₆O

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	20.3 ± 0.04	kJ/mol	Cm	Wiberg, Morgan, et al., 1994	liquid phase; ALS
Δ_rH°	20.43 ± 0.04	kJ/mol	Cm	Wiberg and Squires, 1979	liquid phase; Heat of hydrolysis; ALS
Δ_rH°	20.433 ± 0.028	kJ/mol	Cm	Wiberg and Squires, 1979, 2	liquid phase; solvent: Water; Hydrolysis; ALS
Δ_rH°	-16.5 ± 0.2	kJ/mol	Cm	Stern and Dorer, 1962	liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 15.4 ± 0.2 kJ/mol; Heat of hydrolysis; ALS

(CH₅O⁺ • Methyl Alcohol ) + = (CH₅O⁺ • 2)

By formula: (CH₅O⁺ • CH₄O) + CH₄O = (CH₅O⁺ • 2CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	88.7	kJ/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	87.9	kJ/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; M
Δ_rH°	89.1	kJ/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	113.	J/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	108.	J/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; M
Δ_rS°	118.	J/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

C₅H₁₁O^- + Methyl Alcohol = (C₅H₁₁O^- • )

By formula: C₅H₁₁O^- + CH₄O = (C₅H₁₁O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	108. ± 12.	kJ/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	71.1 ± 8.4	kJ/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

C₆H₁₁S₂^- + Methyl Alcohol = (C₆H₁₁S₂^- • )

By formula: C₆H₁₁S₂^- + CH₄O = (C₆H₁₁S₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	92. ± 10.	kJ/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	55.2 ± 6.7	kJ/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

( • Methyl Alcohol ) + = ( • 2)

By formula: (Cu⁺ • CH₄O) + CH₄O = (Cu⁺ • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	57.7	kJ/mol	HPMS	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	100.	J/mol*K	N/A	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	26.	kJ/mol	HPMS	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

(CH₅O⁺ • 2 • 3 Methyl Alcohol ) + = (CH₅O⁺ • 3 • 3)

By formula: (CH₅O⁺ • 2H₂O • 3CH₄O) + H₂O = (CH₅O⁺ • 3H₂O • 3CH₄O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	38.	kJ/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	92.	J/mol*K	N/A	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
13.	272.	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

(CH₅O⁺ • 3 • 2 Methyl Alcohol ) + = (CH₅O⁺ • 4 • 2)

By formula: (CH₅O⁺ • 3H₂O • 2CH₄O) + H₂O = (CH₅O⁺ • 4H₂O • 2CH₄O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	39.	kJ/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	92.	J/mol*K	N/A	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
13.	272.	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

(CH₅O⁺ • 4 • Methyl Alcohol ) + = (CH₅O⁺ • 5 • )

By formula: (CH₅O⁺ • 4H₂O • CH₄O) + H₂O = (CH₅O⁺ • 5H₂O • CH₄O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	39.	kJ/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	92.	J/mol*K	N/A	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
15.	269.	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

(CH₅O⁺ • ) + Methyl Alcohol = (CH₅O⁺ • • )

By formula: (CH₅O⁺ • H₂O) + CH₄O = (CH₅O⁺ • CH₄O • H₂O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	103.	kJ/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	120.	J/mol*K	N/A	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
48.5	452.	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

C₆H₅NO₂^- + Methyl Alcohol = (C₆H₅NO₂^- • )

By formula: C₆H₅NO₂^- + CH₄O = (C₆H₅NO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	63.18 ± 0.84	kJ/mol	TDAs	Sieck, 1985	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	109.	J/mol*K	PHPMS	Sieck, 1985	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	30.5 ± 1.7	kJ/mol	TDAs	Sieck, 1985	gas phase; B
Δ_rG°	26. ± 6.7	kJ/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
26.	343.	PHPMS	Chowdhury, 1987	gas phase; M

+ Methyl Alcohol = ( • )

By formula: Cu⁺ + CH₄O = (Cu⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	56.1	kJ/mol	HPMS	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	100.	J/mol*K	N/A	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	25.	kJ/mol	HPMS	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

( • Methyl Alcohol ) + = ( • 2)

By formula: (F^- • CH₄O) + CH₄O = (F^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	84.9 ± 1.3	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	80.8 ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	97.1	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	54.27	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	51.9 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (F^- • 2CH₄O) + CH₄O = (F^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	63.2 ± 2.5	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	60.7 ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	88.7	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	33.7	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	34. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (Br^- • 2CH₄O) + CH₄O = (Br^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	39.7 ± 2.1	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	44.4 ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	90.4	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	17.8	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	18. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • Methyl Alcohol ) + = ( • 2)

By formula: (Br^- • CH₄O) + CH₄O = (Br^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	50.21 ± 0.84	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	52.3 ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	86.6	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	23.5	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	26. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (I^- • 2CH₄O) + CH₄O = (I^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	32.2 ± 2.5	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	41. ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	93.7	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	14.3	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	13. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • Methyl Alcohol ) + = ( • 2)

By formula: (I^- • CH₄O) + CH₄O = (I^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	39.7 ± 0.84	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	46.4 ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	94.6	J/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	17.8	kJ/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	18. ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 10 Methyl Alcohol ) + = ( • 11)

By formula: (Cl^- • 10CH₄O) + CH₄O = (Cl^- • 11CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	31. ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; Estimated entropy; single temperature measurement; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	84.	J/mol*K	N/A	Hiraoka and Mizuse, 1987	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.4 ± 4.2	kJ/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; Estimated entropy; single temperature measurement; B

( • Methyl Alcohol ) + = ( • 2)

By formula: (Na⁺ • CH₄O) + CH₄O = (Na⁺ • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	85.8 ± 5.9	kJ/mol	CIDC	Amicangelo and Armentrout, 2001	Anchor NH3=24.41; RCD
Δ_rH°	89.5 ± 6.7	kJ/mol	CIDC	Amicangelo and Armentrout, 2001	Anchor NH3=24.41; RCD
Δ_rH°	85.8 ± 6.7	kJ/mol	CIDC	Amicangelo and Armentrout, 2001	Anchor NH3=24.41; RCD
Δ_rH°	84.5 ± 0.8	kJ/mol	HPMS	Guo, Conklin, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	90.8	J/mol*K	HPMS	Guo, Conklin, et al., 1989	gas phase; M

H₄ClO₂^- + Methyl Alcohol + 2 = CH₈ClO₃^-

By formula: H₄ClO₂^- + CH₄O + 2H₂O = CH₈ClO₃^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	43.51 ± 0.84	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rH°	47.7 ± 1.3	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; For solvation by MeOH of core ion; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	24.3	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rG°	25.1	kJ/mol	TDAs	Evans and Keesee, 1991	gas phase; For solvation by MeOH of core ion; B

(CH₅O⁺ • 2 Methyl Alcohol ) + = (CH₅O⁺ • • 2)

By formula: (CH₅O⁺ • 2CH₄O) + C₂H₆O = (CH₅O⁺ • C₂H₆O • 2CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	72.0	kJ/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	120.	J/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH₅O⁺ • 3 Methyl Alcohol ) + = (CH₅O⁺ • • 3)

By formula: (CH₅O⁺ • 3CH₄O) + C₂H₆O = (CH₅O⁺ • C₂H₆O • 3CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	57.3	kJ/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	129.	J/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH₅O⁺ • 2 Methyl Alcohol ) + = (CH₅O⁺ • 3)

By formula: (CH₅O⁺ • 2CH₄O) + CH₄O = (CH₅O⁺ • 3CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	58.6	kJ/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	67.4	kJ/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	100.	J/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	121.	J/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • 3 Methyl Alcohol ) + = (CH₅O⁺ • 4)

By formula: (CH₅O⁺ • 3CH₄O) + CH₄O = (CH₅O⁺ • 4CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	47.3	kJ/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	56.5	kJ/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	93.3	J/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	120.	J/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • 4 Methyl Alcohol ) + = (CH₅O⁺ • 5)

By formula: (CH₅O⁺ • 4CH₄O) + CH₄O = (CH₅O⁺ • 5CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	42.7	kJ/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	52.3	kJ/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	98.3	J/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	130.	J/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • Methyl Alcohol ) + = (CH₅O⁺ • • )

By formula: (CH₅O⁺ • CH₄O) + C₂H₆O = (CH₅O⁺ • C₂H₆O • CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	91.6	kJ/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	105.	J/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH₅O⁺ • 5 Methyl Alcohol ) + = (CH₅O⁺ • 6)

By formula: (CH₅O⁺ • 5CH₄O) + CH₄O = (CH₅O⁺ • 6CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	39.	kJ/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	49.8	kJ/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	98.3	J/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	138.	J/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • 6 Methyl Alcohol ) + = (CH₅O⁺ • 7)

By formula: (CH₅O⁺ • 6CH₄O) + CH₄O = (CH₅O⁺ • 7CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	38.	kJ/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	50.2	kJ/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	108.	J/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	149.	J/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

( • 11 Methyl Alcohol ) + = ( • 12)

By formula: (F^- • 11CH₄O) + CH₄O = (F^- • 12CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	36. ± 4.2	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	100.	J/mol*K	N/A	Hiraoka and Yamabe, 1991	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.6 ± 8.4	kJ/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to CH₄O⁺ (ion structure unspecified)

Quantity	Value	Units	Method	Reference	Comment
IE (evaluated)	10.84 ± 0.01	eV	N/A	N/A	L
Quantity	Value	Units	Method	Reference	Comment
Proton affinity (review)	754.3	kJ/mol	N/A	Hunter and Lias, 1998	HL
Quantity	Value	Units	Method	Reference	Comment
Gas basicity	724.5	kJ/mol	N/A	Hunter and Lias, 1998	HL

Ionization energy determinations

IE (eV)	Method	Reference	Comment
10.85 ± 0.03	PI	Tao, Klemm, et al., 1992	LL
10.82 ± 0.05	EI	Holmes and Lossing, 1991	LL
10.84 ± 0.07	EI	Bowen and Maccoll, 1984	LBLHLM
10.9	EI	Mishchanchuk, Pokrovskii, et al., 1982	LBLHLM
10.84 ± 0.08	EI	Allam, Migahed, et al., 1982	LBLHLM
10.90 ± 0.03	EI	Sahini, Constantin, et al., 1978	LLK
10.85 ± 0.01	PI	Berkowitz, 1978	LLK
10.846 ± 0.002	PE	MacNeil and Dixon, 1977	LLK
10.90 ± 0.12	EI	Finney and Harrison, 1972	LLK
10.83 ± 0.03	PI	Warneck, 1971	LLK
10.85 ± 0.02	PE	Cocksey, Eland, et al., 1971	LLK
10.85	PE	Baker, Betteridge, et al., 1971	LLK
10.85	PE	Baker, Betteridge, et al., 1971	LLK
10.829 ± 0.015	PI	Omura, Kaneko, et al., 1969	RDSH
10.85	EI	Lifshitz, Shapiro, et al., 1969	RDSH
10.83	PE	Dewar and Worley, 1969	RDSH
10.84 ± 0.02	PI	Refaey and Chupka, 1968	RDSH
10.85	CI	Cermak, 1968	RDSH
10.83	PE	Al-Joboury and Turner, 1964	RDSH
10.85 ± 0.02	PI	Watanabe, 1954	RDSH
10.96	EI	Vorob'ev, Furlei, et al., 1989	Vertical value; LL
11.0	PE	Von Niessen, Bieri, et al., 1980	Vertical value; LLK
10.95	PE	Utsunomiya, Kobayashi, et al., 1980	Vertical value; LLK
10.95	PE	Kobayashi, 1978	Vertical value; LLK
10.86	PE	Benoit and Harrison, 1977	Vertical value; LLK
10.97 ± 0.03	PE	Peel and Willett, 1975	Vertical value; LLK
10.96	PE	Robin and Kuebler, 1973	Vertical value; LLK
10.95	PE	Ogata, Onizuka, et al., 1973	Vertical value; LLK
10.94	PE	Katsumata, Iwai, et al., 1973	Vertical value; LLK
10.95	PE	Ogata, Onizuka, et al., 1972	Vertical value; LLK
10.96	PE	Baker, Betteridge, et al., 1971	Vertical value; LLK

Appearance energy determinations

Ion	AE (eV)	Other Products	Method	Reference	Comment
CH⁺	22.31 ± 0.09	?	EI	Reed and Snedden, 1956	RDSH
CHO⁺	13.06 ± 0.10	H₂+H	PI	Warneck, 1971	LLK
CHO⁺	14.0 ± 0.2	H₂+H	EI	Lifshitz, Shapiro, et al., 1969	RDSH
CH₂⁺	14.05 ± 0.05	H₂O	PI	Warneck, 1971	LLK
CH₂⁺	15.3	H₂O	EI	Haney and Franklin, 1968	RDSH
CH₂O⁺	10.9	H₂	EI	Mishchanchuk, Pokrovskii, et al., 1982	LBLHLM
CH₂O⁺	12.05 ± 0.12	H₂	PI	Warneck, 1971	LLK
CH₂O⁺	12.45	H₂	PI	Refaey and Chupka, 1968	RDSH
CH₃⁺	13.82 ± 0.04	OH	PI	Warneck, 1971	LLK
CH₃⁺	13.5	OH	EI	Friedman, Long, et al., 1957	RDSH
CH₃O⁺	11.67 ± 0.09	H	EI	Bowen and Maccoll, 1984	LBLHLM
CH₃O⁺	10.4	H	EI	Mishchanchuk, Pokrovskii, et al., 1982	LBLHLM
CH₃O⁺	11.85 ± 0.08	H	EI	Allam, Migahed, et al., 1982	LBLHLM
CH₃O⁺	11.88 ± 0.05	H	EI	Selim and Helal, 1981	LLK
CH₃O⁺	11.69	H	EI	Lossing, 1977	LLK
CH₃O⁺	11.76 ± 0.11	H	EI	Finney and Harrison, 1972	LLK
CH₃O⁺	11.55 ± 0.03	H	PI	Warneck, 1971	LLK
CH₃O⁺	11.66 ± 0.04	H	PI	Omura, Kaneko, et al., 1969	RDSH
CH₃O⁺	11.67	H	EI	Lifshitz, Shapiro, et al., 1969	RDSH
CH₃O⁺	11.67 ± 0.03	H	PI	Refaey and Chupka, 1968	RDSH
CH₃O⁺[CH₂OH⁺]	11.649 ± 0.003	H	PI	Berkowitz, Ellison, et al., 1994	Unpublished results of B. Ruscic and J. Berkowitz; LL
CO⁺	13.7	2H₂	EI	Friedman, Long, et al., 1957	RDSH
CO⁺	14.31 ± 0.05	2H₂	EI	Friedland and Strakna, 1956	RDSH

De-protonation reactions

CH₃O^- + = Methyl Alcohol

By formula: CH₃O^- + H⁺ = CH₄O

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	1597. ± 8.	kJ/mol	AVG	N/A	Average of 6 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1573.3 ± 2.6	kJ/mol	H-TS	Nee, Osterwalder, et al., 2006	gas phase; B
Δ_rG°	1573.4 ± 2.3	kJ/mol	H-TS	Osborn, Leahy, et al., 1998	gas phase; B
Δ_rG°	1565. ± 8.4	kJ/mol	IMRE	Bartmess, Scott, et al., 1979	gas phase; The acidity is 1.2 kcal/mol stronger than that from the D-EA cycle, due to the multi-compound fit for the acidity scale.; value altered from reference due to change in acidity scale; B
Δ_rG°	1567. ± 8.8	kJ/mol	H-TS	Haas and Harrison, 1993	gas phase; Both metastable and 50 eV collision energy.; B
Δ_rG°	1569.4 ± 2.5	kJ/mol	TDEq	Meot-ner and Sieck, 1986	gas phase; Experimental entropy: 21.5 eu, 0.6 less than H2O; B

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: Tanya L. Myers, Russell G. Tonkyn, Ashley M. Oeck, Tyler O. Danby, John S. Loring, Matthew S. Taubman, Stephen W. Sharpe, Jerome C. Birnbaum, and Timothy J. Johnson

liquid; Bruker Tensor 27 FTIR; 0.4821395 cm^-1 resolution

Data compiled by: Pamela M. Chu, Franklin R. Guenther, George C. Rhoderick, and Walter J. Lafferty

gas; IFS66V (Bruker); 3-Term B-H Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm^-1 resolution
gas; IFS66V (Bruker); Boxcar Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm^-1 resolution
gas; IFS66V (Bruker); Happ Genzel Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm^-1 resolution
gas; IFS66V (Bruker); NB Strong Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm^-1 resolution
gas; IFS66V (Bruker); Triangular Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm^-1 resolution

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Gas Chromatography, References, Notes

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Origin	Japan AIST/NIMC Database- Spectrum MS-NW- 72
NIST MS number	229809

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Gas Chromatography

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type	Active phase	Temperature (C)	I	Reference	Comment
Capillary	SE-30	140.	340.	Haken and Korhonen, 1985	Column length: 25. m; Column diameter: 0.33 mm
Packed	SE-30	100.	384.	Winskowski, 1983	Gaschrom Q; Column length: 2. m
Packed	SE-30	150.	356.	Haken, Nguyen, et al., 1979	Celatom AW silanized; Column length: 3.7 m
Packed	Apiezon L	120.	336.	Bogoslovsky, Anvaer, et al., 1978	Celite 545
Packed	SE-30	100.	373.	Pías and Gascó, 1975	Ar, Chromosorb W AW DMCS HP (80-100 mesh); Column length: 1. m
Packed	Apiezon L	100.	355.	Brown, Chapman, et al., 1968	N2, DCMS-treated Chromosorb W; Column length: 2.3 m
Packed	SE-30	80.	330.	Viani, Müggler-Chavan, et al., 1965	He, Chromosorb P; Column length: 6. m

Kovats' RI, non-polar column, custom temperature program

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	Petrocol DH-100	380.	Haagen-Smit Laboratory, 1997	He; Column length: 100. m; Column diameter: 0.2 mm; Program: 5C(10min) => 5C/min => 50C(48min) => 1.5C/min => 195C(91min)

Kovats' RI, polar column, isothermal

View large format table.

Column type	Active phase	Temperature (C)	I	Reference	Comment
Capillary	OV-351	100.	917.	Haken and Korhonen, 1985	N2; Column length: 25. m; Column diameter: 0.32 mm
Capillary	OV-351	80.	891.	Haken and Korhonen, 1985	N2; Column length: 25. m; Column diameter: 0.32 mm
Packed	PEG-2000	152.	860.	Anderson, Jurel, et al., 1973	He, Celite 545 (44-60 mesh); Column length: 3. m
Packed	PEG-2000	179.	881.	Anderson, Jurel, et al., 1973	He, Celite 545 (44-60 mesh); Column length: 3. m
Packed	Carbowax 20M	100.	892.	Zarazir, Chovin, et al., 1970	Chromosorb W; Column length: 2. m
Packed	Polyethylene Glycol 4000	100.	904.	Bonastre and Grenier, 1968	Chromosorb P; Column length: 6. m
Packed	Polyethylene Glycol 4000	120.	897.	Bonastre and Grenier, 1968	Chromosorb P; Column length: 6. m
Packed	Polyethylene Glycol 4000	140.	886.	Bonastre and Grenier, 1968	Chromosorb P; Column length: 6. m
Packed	Polyethylene Glycol 4000	80.	914.	Bonastre and Grenier, 1968	Chromosorb P; Column length: 6. m

Kovats' RI, polar column, temperature ramp

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	CBP-20	899.	Shimadzu, 2003	25. m/0.2 mm/0.25 μm, He, 50. C @ 5. min, 4. K/min; T_end: 200. C
Capillary	DB-Wax	888.	Shimoda and Shibamoto, 1990	He, 40. C @ 6. min, 3. K/min; Column length: 60. m; Column diameter: 0.25 mm; T_end: 190. C

Kovats' RI, polar column, custom temperature program

View large format table.

Column type	Active phase	I	Reference	Comment
Packed	Carbowax 20M	869.	Kevei and Kozma, 1976	Chromosorb; Program: not specified

Van Den Dool and Kratz RI, non-polar column, temperature ramp

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	Petrocol DH	372.7	Censullo, Jones, et al., 2003	50. m/0.25 mm/0.5 μm, He, 35. C @ 10. min, 3. K/min, 200. C @ 10. min
Capillary	Petrocol DH	378.2	Censullo, Jones, et al., 2003	50. m/0.25 mm/0.5 μm, He, 35. C @ 10. min, 3. K/min, 200. C @ 10. min
Capillary	SE-30	400.0	Golovnya, Kuz'menko, et al., 2000	25. m/0.32 mm/1. μm, He, 4. K/min; T_start: 60. C
Capillary	SE-30	400.0	Golovnya, Kuz'menko, et al., 2000, 2	25. m/0.32 mm/1. μm, He, 4. K/min; T_start: 60. C
Capillary	DB-1	361.	Bartelt, 1997	30. m/0.32 mm/5. μm, He, 35. C @ 1. min, 10. K/min; T_end: 270. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

View large format table.

Column type	Active phase	I	Reference	Comment
Packed	SE-30	368.	Peng, Ding, et al., 1988	Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)

Van Den Dool and Kratz RI, polar column, temperature ramp

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	Carbowax	910.4	Censullo, Jones, et al., 2003	60. m/0.25 mm/0.5 μm, He, 50. C @ 10. min, 5. K/min, 250. C @ 10. min
Capillary	FFAP	916.	Ott, Fay, et al., 1997	30. m/0.25 mm/0.25 μm, He, 20. C @ 1. min, 4. K/min, 200. C @ 1. min
Packed	Carbowax 20M	866.	van den Dool and Kratz, 1963	Celite 545, 4.6 K/min; T_start: 75. C; T_end: 228. C

Normal alkane RI, non-polar column, isothermal

View large format table.

Column type	Active phase	Temperature (C)	I	Reference	Comment
Capillary	DB-1	60.	382.	Shimadzu, 2003, 2	60. m/0.32 mm/1. μm, He
Packed	Squalane	100.	338.	Vernon, 1971	N2
Packed	DC-400	150.	370.	Anderson, 1968	Helium, Gas-Pak (60-80 mesh); Column length: 3.0 m
Packed	Squalane	125.	348.	Cremer and Nonn, 1964	H2, Chromosorb W (80-100 mesh); Column length: 3. m

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	Polydimethyl siloxane: CP-Sil 5 CB	395.	Bramston-Cook, 2013	60. m/0.25 mm/1.0 μm, Helium, 45. C @ 1.45 min, 3.6 K/min, 210. C @ 2.72 min
Capillary	Petrocol DH	379.	Supelco, 2012	100. m/0.25 mm/0.50 μm, Helium, 20. C @ 15. min, 15. K/min, 220. C @ 30. min
Capillary	HP-5	367.5	Leffingwell and Alford, 2005	60. m/0.32 mm/0.25 μm, He, 30. C @ 2. min, 2. K/min, 260. C @ 28. min
Capillary	OV-101	381.	Zenkevich, 2005	25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; T_start: 50. C; T_end: 250. C
Capillary	BP-1	370.	Health Safety Executive, 2000	50. m/0.22 mm/0.75 μm, He, 5. K/min; T_start: 50. C; T_end: 200. C
Capillary	DB-5MS	353.5	Shoenmakers, Oomen, et al., 2000	30. m/0.25 mm/0.25 μm, He, 40. C @ 1. min, 3. K/min; T_end: 250. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	HP-5 MS	381.	Kotowska, Zalikowski, et al., 2012	30. m/0.25 mm/0.25 μm, Helium; Program: not specified
Capillary	Methyl Silicone	373.	Chen and Feng, 2007	Program: not specified
Capillary	Methyl Silicone	373.	Kou, Zhang, et al., 2006	Program: not specified
Capillary	Methyl Silicone	408.	Blunden, Aneja, et al., 2005	60. m/0.32 mm/1.0 μm, Helium; Program: -50 0C (2 min) 8 0C/min -> 200 0C (7.75 min) 25 0C -> 225 0C (8 min)
Capillary	Methyl Silicone	373.	Fu and Wang, 2004	Program: not specified
Capillary	Methyl Silicone	362.	N/A	Program: not specified
Capillary	Polydimethyl siloxanes	381.	Zenkevich, 2001	Program: not specified
Capillary	Polydimethyl siloxanes	381.	Zenkevich, 2001, 2	Program: not specified
Capillary	Methyl Silicone	381.	Zenkevich, 1999	Program: not specified
Capillary	SPB-1	353.	Flanagan, Streete, et al., 1997	60. m/0.53 mm/5. μm, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
Capillary	Polydimethyl siloxanes	381.	Zenkevich and Chupalov, 1996	Program: not specified
Capillary	Methyl Silicone	381.	Zenkevich, Korolenko, et al., 1995	Program: not specified
Capillary	DB-1	348.	Schuberth, 1994	30. m/0.25 mm/1. μm, He; Program: 40C (4min) => 10C/min => 200C => 50C/min => 250C
Capillary	SPB-1	353.	Strete, Ruprah, et al., 1992	60. m/0.53 mm/5.0 μm, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C
Capillary	SPB-1	391.	Strete, Ruprah, et al., 1992	60. m/0.53 mm/5.0 μm, Helium; Program: not specified
Capillary	CP Sil 8 CB	404.	Weller and Wolf, 1989	40. m/0.25 mm/0.25 μm, He; Program: 30 0C (1 min) 15 0C/min -> 45 0C 3 0C/min -> 120 0C
Capillary	OV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.	384.	Waggott and Davies, 1984	Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified

Normal alkane RI, polar column, isothermal

View large format table.

Column type	Active phase	Temperature (C)	I	Reference	Comment
Capillary	Carbowax 20M	100.	892.	Sun, Siepmann, et al., 2006	30. m/0.25 mm/0.25 μm, Helium
Capillary	Carbowax 20M	60.	899.	Sun, Siepmann, et al., 2006	30. m/0.25 mm/0.25 μm, Helium
Capillary	Carbowax 20M	80.	895.	Sun, Siepmann, et al., 2006	30. m/0.25 mm/0.25 μm, Helium
Capillary	DB-Wax	60.	921.	Shimadzu, 2003, 2	50. m/0.32 mm/1. μm, He

Normal alkane RI, polar column, temperature ramp

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	DB-Wax	911.	Shimadzu, 2012	30. m/0.32 mm/0.50 μm, Helium, 4. K/min; T_start: 40. C; T_end: 260. C
Capillary	DB-Wax	907.	Chida, Sone, et al., 2004	60. m/0.25 mm/0.5 μm, 35. C @ 5. min, 4. K/min, 240. C @ 10. min
Capillary	DB-Wax	911.	Shimadzu Corporation, 2003	30. m/0.32 mm/0.5 μm, He, 4. K/min; T_start: 40. C; T_end: 260. C
Capillary	DB-Wax	903.	Tanaka, Yamauchi, et al., 2003	30. m/0.25 mm/0.25 μm, 30. C @ 1. min, 4. K/min; T_end: 250. C
Capillary	DB-Wax	905.	Tanaka, Yamauchi, et al., 2003	30. m/0.25 mm/0.25 μm, 30. C @ 1. min, 4. K/min; T_end: 250. C
Capillary	TC-Wax	898.	Suhardi, Suzuki, et al., 2002	60. m/0.25 mm/0.25 μm, He, 40. C @ 10. min, 3. K/min, 230. C @ 10. min
Capillary	DB-Wax	905.	Duque, Bonilla, et al., 2001	30. m/0.25 mm/0.25 μm, Helium, 4. K/min, 220. C @ 30. min; T_start: 25. C

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	Carbowax 20M	920.	Vinogradov, 2004	Program: not specified
Capillary	Polyethylene Glycol	897.	Zenkevich, Korolenko, et al., 1995	Program: not specified
Capillary	DB-Wax	909.	Peng, Yang, et al., 1991	Program: not specified
Capillary	Carbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.	907.	Waggott and Davies, 1984	Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
Capillary	Carbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.	920.	Waggott and Davies, 1984	Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
Capillary	Carbowax 20M	883.	Ramsey and Flanagan, 1982	Program: not specified

References

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Rossini, F.D., The heats of combustion of methyl and ethyl alcohols, J. Res. NBS, 1932, 8, 119-139. [all data]

Thermodynamics Research Center, 1997
Thermodynamics Research Center, Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]

Ivash E.V., 1955
Ivash E.V., Thermodynamic properties of ideal gaseous methanol, J. Chem. Phys., 1955, 23, 1814-1818. [all data]

Zhuravlev E.Z., 1959
Zhuravlev E.Z., Isotopic effect on thermodynamic functions of some organic deuterocompounds in the ideal gas state, Tr. Khim. i Khim. Tekhnol., 1959, 2, 475-485. [all data]

Chen S.S., 1977
Chen S.S., Thermodynamic properties of normal and deuterated methanols, J. Phys. Chem. Ref. Data, 1977, 6, 105-112. [all data]

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Chao J., Thermodynamic properties of key organic oxygen compounds in the carbon range C1 to C4. Part 2. Ideal gas properties, J. Phys. Chem. Ref. Data, 1986, 15, 1369-1436. [all data]

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Stromsoe E., Heat capacity of alcohol vapors at atmospheric pressure, J. Chem. Eng. Data, 1970, 15, 286-290. [all data]

Halford J.O., 1957
Halford J.O., Standard heat capacities of gaseous methanol, ethanol, methane and ethane at 279 K by thermal conductivity, J. Phys. Chem., 1957, 61, 1536-1539. [all data]

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De Vries T., The heat capacity of organic vapors. I. Methyl alcohol, J. Am. Chem. Soc., 1941, 63, 1343-1346. [all data]

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Baroody, E.E.; Carpenter, G.A., Heats of formation of propellant compounds (U), Rpt. Naval Ordnance Systems Command Task No. 331-003/067-1/UR2402-001 for Naval Ordance Station, Indian Head, MD, 1972, 1-9. [all data]

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Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

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Parks, G.S., Thermal data on organic compounds I. The heat capacities and free energies of methyl, ethyl and normal-butyl alcohols, J. Am. Chem. Soc., 1925, 47, 338-345. [all data]

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Richards, T.W.; Davis, H.S., The heats of combustion of benzene, toluene, aliphatic alcohols, cyclohexanol, and other carbon compounds, J. Am. Chem. Soc., 1920, 42, 1599-1617. [all data]

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Rossini, F.D., The heat of combustion of methyl alcohol, Proc. Nat'l Acad. Sci., 1931, 17, 343-347. [all data]

Carlson and Westrum, 1971
Carlson, H.G.; Westrum, E.F., Jr., Methanol: heat capacity, enthalpies of transition and melting, and thermodynamic properties from 5-300K, J. Chem. Phys., 1971, 54, 1464-1471. [all data]

Kelley, 1929
Kelley, K.K., The heat capacity of methyl alcohol from 16K to 298K and the corresponding entropy and free energy, J. Am. Chem. Soc., 1929, 51, 180-187. [all data]

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Parks, G.S.; Kelley, K.K.; Huffman, H.M., Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds, J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]

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Ahlberg, J.E.; Blanchard, E.R.; Lundberg, W.O., The heat capacities of benzene, methyl alcohol and glycerol at very low temperatures, J. Chem. Phys., 1937, 5, 537-551. [all data]

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Khasanshin, T.S.; Zykova, T.B., Specific heat of saturated monatomic alcohols, Inzh. -Fiz. Zhur., 1989, 56(6), 991-994. [all data]

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Andreoli-Ball, L.; Patterson, D.; Costas, M.; Caceres-Alonso, M., Heat capacity and corresponding states in alkan-1-ol-n-alkane systems, J. Chem. Soc., Faraday Trans. 1, 1988, 84(11), 3991-4012. [all data]

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Okano, T.; Ogawa, H.; Murakami, S., Molar excess volumes, isentropic compressions, and isobaric heat capacities of methanol-isomeric butanol systems at 298.15 K, Can. J. Chem., 1988, 66, 713-717. [all data]

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Lankford, J.I.; Criss, C.M., Partial molar heat caqpacities of selected electrolytes and benzene in methanol and dimethyldulfoxide at 25, 40 and 80°C, J. Solution Chem., 1987, 16(11), 885-906. [all data]

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Korolev, V.P.; Kukharenko, V.A.; Krestov, G.A., Specific heat of binary mixtures of aliphatic alcohols with N,N-dimethylformamide and dimethylsulphoxide, Zhur. Fiz. Khim., 1986, 60, 1854-1857. [all data]

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Ogawa, H.; Murakami, S., Excess isobaric heat capacities for water + alkanol mixtures at 298.15 K, Thermochim. Acta, 1986, 109, 145-154. [all data]

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Tanaka, R.; Toyama, S.; Murakami, S., Heat capacities of {xCnH2n+1OH+(1-x)C7H16} for n = 1 to 6 at 298.15 K, J. Chem. Thermodynam., 1986, 18, 63-73. [all data]

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Costas, M.; Patterson, D., Self-association of alcohols in inert solvents, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 635-654. [all data]

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Zegers, H.C.; Somsen, G., Partial molar volumes and heat capacities in (dimethylformamide + an n-alkanol), J. Chem. Thermodynam., 1984, 16, 225-235. [all data]

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Benson, G.C.; D'Arcy, P.J., Excess isobaric heat capacities of water - n-alcohol mixtures, J. Chem. Eng. Data, 1982, 27, 439-442. [all data]

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Villamanan, M.A.; Casanova, C.; Roux-Desgranges, G.; Grolier, J.-P.E., Thermochemical behavior of mixtures of n-alcohol + aliphatic ether: heat capacities and volumes at 298.15 K, Thermochim. Acta, 1982, 52, 279-283. [all data]

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Atalla, S.R.; El-Sharkawy, A.A.; Gasser, F.A., Measurement of thermal properties of liquids with an AC heated-wire technique, Inter. J. Thermophys., 1981, 2(2), 155-162. [all data]

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Deshpande, D.D.; Bhatagadde, L.G., Heat capacities at constant volume, free volumes, and rotational freedom in some liquids, Aust. J. Chem., 1971, 24, 1817-1822. [all data]

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Paz Andrade, M.I.; Paz, J.M.; Recacho, E., Contribucion a la microcalorimetria de los calores especificos de solidos y liquidos, An. Quim., 1970, 66, 961-967. [all data]

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Katayama, T., Heats of mixing, liquid heat capacities and enthalpy, concentration charts for methanol-water and isopropanol-water systems, Kagaku Kogaku, 1962, 26, 361-372. [all data]

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Swietoslawski, W.; Zielenkiewicz, A., Mean specific heat in homologous series of binary and ternary positive azeotropes, Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1960, 8, 651-653. [all data]

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Hough, E.W.; Mason, D.M.; Sage, B.H., Heat capacities of several organic liquids, J. Am. Chem. Soc., 1950, 72, 5775-5777. [all data]

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Staveley, L.A.K.; Gupta, A.K., A semi-micro low-temperature calorimeter, and a comparison of some thermodynamic properties of methyl alcohol and methyl deuteroxide, Trans. Faraday Soc., 1949, 45, 50-61. [all data]

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Notes

Symbols used in this document:

AE	Appearance energy
C_p,gas	Constant pressure heat capacity of gas
C_p,liquid	Constant pressure heat capacity of liquid
C_p,solid	Constant pressure heat capacity of solid
IE (evaluated)	Recommended ionization energy
P_c	Critical pressure
S°_liquid	Entropy of liquid at standard conditions
S°_{solid,1 bar}	Entropy of solid at standard conditions (1 bar)
T	Temperature
T_boil	Boiling point
T_c	Critical temperature
T_fus	Fusion (melting) point
T_triple	Triple point temperature
V_c	Critical volume
ΔH_trs	Enthalpy of phase transition
ΔS_trs	Entropy of phase transition
Δ_cH°_gas	Enthalpy of combustion of gas at standard conditions
Δ_cH°_liquid	Enthalpy of combustion of liquid at standard conditions
Δ_fH°_gas	Enthalpy of formation of gas at standard conditions
Δ_fH°_liquid	Enthalpy of formation of liquid at standard conditions
Δ_fusH	Enthalpy of fusion
Δ_fusS	Entropy of fusion
Δ_rG°	Free energy of reaction at standard conditions
Δ_rH°	Enthalpy of reaction at standard conditions
Δ_rS°	Entropy of reaction at standard conditions
Δ_vapH	Enthalpy of vaporization
Δ_vapH°	Enthalpy of vaporization at standard conditions
ρ_c	Critical density

Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
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Methyl Alcohol

Data at NIST subscription sites:

Gas phase thermochemistry data

Constant pressure heat capacity of gas

Constant pressure heat capacity of gas

Condensed phase thermochemistry data

Constant pressure heat capacity of liquid

Constant pressure heat capacity of solid

Phase change data

Enthalpy of vaporization

Enthalpy of vaporization

Antoine Equation Parameters

Enthalpy of fusion

Entropy of fusion

Entropy of fusion

Enthalpy of phase transition

Entropy of phase transition

Reaction thermochemistry data

Reactions 1 to 50

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Gas phase ion energetics data

Ionization energy determinations

Appearance energy determinations

De-protonation reactions

IR Spectrum

Mass spectrum (electron ionization)

Spectrum

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Additional Data

Gas Chromatography

Kovats' RI, non-polar column, isothermal

Kovats' RI, non-polar column, custom temperature program

Kovats' RI, polar column, isothermal

Kovats' RI, polar column, temperature ramp

Kovats' RI, polar column, custom temperature program

Van Den Dool and Kratz RI, non-polar column, temperature ramp

Van Den Dool and Kratz RI, non-polar column, custom temperature program

Van Den Dool and Kratz RI, polar column, temperature ramp

Normal alkane RI, non-polar column, isothermal

Normal alkane RI, non-polar column, temperature ramp

Normal alkane RI, non-polar column, custom temperature program

Normal alkane RI, polar column, isothermal

Normal alkane RI, polar column, temperature ramp

Normal alkane RI, polar column, custom temperature program

References

Notes