(2H3)ammonia

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tfus199.KN/ATaylor and Jungers, 1933Uncertainty assigned by TRC = 0.5 K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
10.083 ± 0.010PILocht, Leyh, et al., 1991LL
10.21PEPotts and Price, 1972LLK
14.94 ± 0.03PEWeiss and Lawrence, 1970RDSH
10.18 ± 0.01PEWeiss and Lawrence, 1970RDSH
10.17PEBranton, Frost, et al., 1969RDSH
15.15PEBranton, Frost, et al., 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
D2N+15.72 ± 0.04DEILocht, Servais, et al., 1988LL
D2N+15.90 ± 0.015DPIPECOPowis, 1982LBLHLM
D2N+15.89 ± 0.01DPIMcCulloh, 1976LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taylor and Jungers, 1933
Taylor, H.S.; Jungers, J.C., The Deuteroammonias, J. Am. Chem. Soc., 1933, 55, 5057-8. [all data]

Locht, Leyh, et al., 1991
Locht, R.; Leyh, B.; Denzer, W.; Hagenow, G.; Baumgartel, H., The photoionization of ammonia revisited. The vibrational autoionization of NH3 and its three isotopomers in the 10-12 eV photon energy range, Chem. Phys., 1991, 155, 407. [all data]

Potts and Price, 1972
Potts, A.W.; Price, W.C., Photoelectron spectra and valence shell orbital structures of groups V VI hydrides, Proc. R. Soc. London A:, 1972, 326, 181. [all data]

Weiss and Lawrence, 1970
Weiss, M.J.; Lawrence, G.M., Photoelectron spectroscopy of NH3 and ND3 using molecular beams, J. Chem. Phys., 1970, 53, 214. [all data]

Branton, Frost, et al., 1969
Branton, G.R.; Frost, D.C.; Herring, F.G.; McDowell, C.A.; Stenhouse, I.A., The ionization potentials of ammonia and ammonia-d3, measured by photoelectron spectroscopy, and an INDO calculation of these values, Chem. Phys. Lett., 1969, 3, 581. [all data]

Locht, Servais, et al., 1988
Locht, R.; Servais, C.; Ligot, M.; Derwa, F.; Momigny, J., The dissociative electroionization of ammonia and ammonia-d3. I. The NH+ and NH2+ dissociation channels, Chem. Phys., 1988, 123, 443. [all data]

Powis, 1982
Powis, I., Energy disposal in the rotational pre-dissociation of ND3, Chem. Phys., 1982, 68, 251. [all data]

McCulloh, 1976
McCulloh, K.E., Energetics and mechanisms of fragment ion formation in the photoionization of normal and deuterated water and ammonia, Int. J. Mass Spectrom. Ion Phys., 1976, 21, 333. [all data]


Notes

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