Tetraethyllead

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas109.6 ± 5.1kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid53.0 ± 5.0kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Δcliquid-6383.5 ± 2.5kJ/molCC-RBGood, Scott, et al., 1956Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
liquid464.6J/mol*KN/ARabinovich, Nistratov, et al., 1989DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
307.4298.15Rabinovich, Nistratov, et al., 1989T = 5 to 315 K.; DH
310.0298.15Scott, Good, et al., 1956DH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
11.1EIdeRidder and Dijkstra, 1967

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H5Pb+12.2?EIdeRidder and Dijkstra, 1967 
C4H10Pb+12.2?EIdeRidder and Dijkstra, 1967 
C6H15Pb+10.8C2H5EIdeRidder and Dijkstra, 1967 
PbH+14.4?EIdeRidder and Dijkstra, 1967 
Pb+11.6?EIdeRidder and Dijkstra, 1967 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Good, Scott, et al., 1956
Good, W.D.; Scott, D.W.; Waddington, G., J. Phys. Chem., 1956, 60, 1090. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Rabinovich, Nistratov, et al., 1989
Rabinovich, I.B.; Nistratov, V.P.; Sheiman, M.S.; Karataev, E.N.; Kamelova, G.P.; Feshchenko, I.A., Heat capacity, phase transitions, and thermodynamic function of tetraethyllead, Zhur. Fiz. Khim., 1989, 63, 2520-2524. [all data]

Scott, Good, et al., 1956
Scott, D.W.; Good, W.D.; Waddington, G., Tetraethyllead: heat of formation by rotating-bomb calorimetry, J. Phys. Chem., 1956, 60, 1090-1095. [all data]

deRidder and Dijkstra, 1967
deRidder, J.J.; Dijkstra, G., Mass spectra of the tetramethyl and tetraethyl compounds of carbon, silicon, germanium, tin and lead, Rec. Trav. Chim., 1967, 86, 737. [all data]


Notes

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