Diethylzinc

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas57. ± 6.kJ/molAVGN/AAverage of 6 values; Individual data points

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid18. ± 6.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δcliquid-3372.3 ± 2.1kJ/molCC-SBLautsch, Tröber, et al., 1963Please also see Lautsch, Erzberger, et al., 1958 and Cox and Pilcher, 1970.; MS
Δcliquid-3369. ± 13.kJ/molCC-SBLong and Norrish, 1949Please also see Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
liquid290.2J/mol*KN/ARabinovich, Nistratov, et al., 1988DH
liquid276.6J/mol*KN/AGibin, Grishnova, et al., 1987DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
194.4298.15Rabinovich, Nistratov, et al., 1988T = 5 to 300 K.; DH
188.9298.15Gibin, Grishnova, et al., 1987T = 18 to 273 K.; DH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.6PECreber and Bancroft, 1980Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Lautsch, Erzberger, et al., 1958
Lautsch, W.F.; Erzberger, P.; Tröber, A., Wiss. Z. Tech. Hochsch. Chem. Leuna-Merseburg, 1958, 1, 31. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Long and Norrish, 1949
Long, L.H.; Norrish, R.G.W., Phil. Trans. Roy. Soc. (London), 1949, A241, 587. [all data]

Rabinovich, Nistratov, et al., 1988
Rabinovich, I.B.; Nistratov, V.P.; Fedoseev, V.B.; Sheiman, M.S.; Kamelova, G.P.; Karataev, E.N.; Feshchenko, I.A., Low-temperature specific heat and thermodynamic functions of diethylzinc, Zhur.Fiz. Khim., 1988, 62, 1349-1352. [all data]

Gibin, Grishnova, et al., 1987
Gibin, A.M.; Grishnova, N.D.; Gusev, A.V.; Moiseev, A.N.; Remeshkova, I.I.; Salganskii, Yu.M., Study of the heat capacity of high-purity diethyl zinc at 18-273 K, Vysokochist. Veshchestva, 1987, (6), 28-32. [all data]

Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M., Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy, Inorg. Chem., 1980, 19, 643. [all data]


Notes

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