Aluminum monoxide

• Formula: AlO
• Molecular weight: 42.9809
• IUPAC Standard InChI: InChI=1S/Al.O Copy

  
• IUPAC Standard InChIKey: AIRCTMFFNKZQPN-UHFFFAOYSA-N Copy
• CAS Registry Number: 14457-64-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
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• Information on this page:
  • Gas phase thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Constants of diatomic molecules
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to AlO⁺ (ion structure unspecified)

Ionization energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Armentrout, Halle, et al., 1982
Armentrout, P.B.; Halle, L.F.; Beauchamp, J.L., Reaction of Cr⁺, Mn⁺, Fe⁺, Co⁺, and Ni⁺ with O₂ and N₂O. Examination of the translational energy dependence of the cross sections of endothermic reactions, J. Chem. Phys., 1982, 76, 2449. [all data]

Murad and Hildenbrand, 1980
Murad, E.; Hildenbrand, D.L., Dissociation energies of GdO, HoO, ErO, TmO, and LuO. Correlation of results for the lanthanide monoxide series, J. Chem. Phys., 1980, 73, 4005. [all data]

Ho and Burns, 1980
Ho, P.; Burns, R.P., A mass spectrometric study of the AlO₂ molecule, High Temp. Sci., 1980, 12, 31. [all data]

Hildenbrand, 1977
Hildenbrand, D.L., Dissociation energy of samarium monoxide and its relation to that of europium monoxide, Chem. Phys. Lett., 1977, 48, 340. [all data]

Smoes, Drowart, et al., 1976
Smoes, S.; Drowart, J.; Myers, C.E., Determination of the atomization energies of the molecules TaO(g) TaO₂(g) by the mass-spectrometric Knudsen-cell method, J. Chem. Thermodyn., 1976, 8, 225. [all data]

Paule, 1976
Paule, R.C., Mass spectrometric studies of Al₂O₃ vaporization processes, High Temp. Sci., 1976, 8, 257. [all data]

Hildenbrand, 1973
Hildenbrand, D.L., Dissociation energies of the molecules AlO and Al₂O, Chem. Phys. Lett., 1973, 20, 127. [all data]

Farber, Uy, et al., 1972
Farber, M.; Uy, O.M.; Srivastava, R.D., Effusion-mass spectrometric determination of the heats of formation of the gaseous molecules V₄O₁₀, V₄O₈, VO₂, and VO, J. Chem. Phys., 1972, 56, 5312. [all data]

Farber, Srivastava, et al., 1972
Farber, M.; Srivastava, R.D.; Uy, O.M., Mass spectrometric determination of the thermodynamic properties of the vapour species from alumina, J. Chem. Soc. Faraday Trans. 1, 1972, 68, 249. [all data]

Farber, Srivastava, et al., 1971
Farber, M.; Srivastava, R.D.; Uy, O.M., Mass spectrometric determination of the heat of formation of the AlO₂ molecule, J. Chem. Phys., 1971, 55, 4142. [all data]

Drowart, DeMaria, et al., 1960
Drowart, J.; DeMaria, G.; Burns, R.P.; Inghram, M.G., Thermodynamic study of Al₂O₃ using a mass spectrometer, J. Chem. Phys., 1960, 32, 1366. [all data]

Notes

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• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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