Dimolybdenum hexakis(dimethylamide)


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas128. ± 12.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid16.9 ± 9.4kJ/molReviewMartinho Simões 

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub111. ± 8.kJ/molCAdedeji, Cavell, et al., 1979See also Cavell, Connor, et al., 1981.; AC
Δsub111.0 ± 8.0kJ/molRSCAdedeji, Cavell, et al., 1979MS

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C12H36Mo2N6+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
6.74PEBursten, Cotton, et al., 1980Vertical value; LLK

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Adedeji, Cavell, et al., 1979
Adedeji, F.A.; Cavell, K.J.; Cavell, S.; Connor, J.A.; Skinner, H.A.; Zafarani-Moattar, M.T., J. Chem. Soc. Faraday Trans. 1, 1979, 75, 603. [all data]

Cavell, Connor, et al., 1981
Cavell, K.J.; Connor, J.A.; Pilcher, G.; Ribeiro da Silva, M.A.V.; Ribiero da Silva, D.M.C.; Vipmani, Y.; Zafarani-Moattar, M.T., J. Chem. Soc. Faraday Trans. 1, 1981, 77, 1585. [all data]

Bursten, Cotton, et al., 1980
Bursten, B.E.; Cotton, F.A.; Green, J.C.; Seddon, E.A.; Stanley, G.G., Molecular orbital and spectroscopic studies of triple bonds between transition-metal atoms. 1. The d3-d3 Mo2L6 compounds (L = OR, NR2, CH2R), J. Am. Chem. Soc., 1980, 102, 4579. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References