HypoFluorous acid
- Formula: FHO
- Molecular weight: 36.0057
- IUPAC Standard InChIKey: AQYSYJUIMQTRMV-UHFFFAOYSA-N
- CAS Registry Number: 14034-79-8
- Chemical structure:
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 156. | K | N/A | Studier and Appleman, 1971 | Uncertainty assigned by TRC = 2. K |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 12.71 ± 0.01 | eV | N/A | N/A | L |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
12.69 ± 0.03 | PE | Berkowitz, Dehmer, et al., 1973 | LLK |
12.71 ± 0.01 | PI | Berkowitz, Appelman, et al., 1973 | LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
HO+ | 15.07 | F | PI | Berkowitz, Appelman, et al., 1973 | LLK |
O+ | 14.34 | HF | PI | Berkowitz, Appelman, et al., 1973 | LLK |
De-protonation reactions
FO- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 362.5 ± 3.3 | kcal/mol | Acid | Gilles, Polak, et al., 1992 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 356.1 ± 3.6 | kcal/mol | H-TS | Gilles, Polak, et al., 1992 | gas phase; B |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Studier and Appleman, 1971
Studier, M.H.; Appleman, E.H.,
Hypofluorous Acid,
J. Am. Chem. Soc., 1971, 93, 2349. [all data]
Berkowitz, Dehmer, et al., 1973
Berkowitz, J.; Dehmer, J.L.; Appelman, E.H.,
Photoelectron spectrum of hypofluorous acid, HOF,
Chem. Phys. Lett., 1973, 19, 334. [all data]
Berkowitz, Appelman, et al., 1973
Berkowitz, J.; Appelman, E.H.; Chupka, W.A.,
Photoionization of HOF with mass analysis,
J. Chem. Phys., 1973, 58, 1950. [all data]
Gilles, Polak, et al., 1992
Gilles, M.K.; Polak, M.L.; Lineberger, W.C.,
Photoelectron Spectroscopy of the Halogen Oxide Anions FO-, ClO-, BrO-, IO-, OClO-, and OIO-,
J. Chem. Phys., 1992, 96, 11, 8012, https://doi.org/10.1063/1.462352
. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy Tfus Fusion (melting) point ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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