Ozone

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Phase change data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil161.3KN/AStreng, 1971Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus80.7KN/AStreng, 1971Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tc261.15KN/AJenkins and Birdsall, 1952Uncertainty assigned by TRC = 1.5 K; by disappearence of meniscus, with some decomposition; TRC
Tc261.05KN/AJenkins and Birdsall, 1952Uncertainty assigned by TRC = 1. K; by disappearance and appearance of meniscus. with some decomposition; TRC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
92.8 to 162.04.23637712.4876.982Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Quantity Value Units Method Reference Comment
IE (evaluated)12.53 ± 0.08eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)625.5kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity595.9kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
2.1030 ± 0.0040LPESArnold, Xu, et al., 1994B
2.1028 ± 0.0026LPESNovich, Engelking, et al., 1979B
2.14 ± 0.15NBIERothe, Tang, et al., 1975B
1.91 ± 0.14PDWong, Vorburger, et al., 1971B
>1.82338IMRBDotan, Davidson, et al., 1977B
>1.96002EndoBerkowitz, Chupka, et al., 1971I- + O3 ->.; B

Ionization energy determinations

IE (eV) Method Reference Comment
12.43PEKatsumata, Shiromaru, et al., 1984LBLHLM
12.519 ± 0.004PIWeiss, Berkowitz, et al., 1977LLK
12.5 ± 0.1PEFrost, Lee, et al., 1974LLK
12.44 ± 0.01PEDyke, Golob, et al., 1974LLK
12.56PEBrundle, 1974LLK
12.67PICook, 1968RDSH
12.3 ± 0.1PERadwan and Turner, 1966RDSH
12.89 ± 0.10EICurran, 1961RDSH
12.80 ± 0.05EIHerron and Schiff, 1956RDSH
12.73PEKatsumata, Shiromaru, et al., 1984Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
O+15.2 ± 0.1O2PIWeiss, Berkowitz, et al., 1977LLK
O2+13.125 ± 0.004OPIWeiss, Berkowitz, et al., 1977LLK

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Streng, 1971
Streng, A.G., Miscibility and Compatibility of Some Liquid and Solidified Gases at Low Temperature, J. Chem. Eng. Data, 1971, 16, 357. [all data]

Jenkins and Birdsall, 1952
Jenkins, A.C.; Birdsall, C.M., The Vapor Pressures and Critical Constants of Pure Ozone, J. Chem. Phys., 1952, 20, 1158-61. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Arnold, Xu, et al., 1994
Arnold, D.W.; Xu, C.S.; Kim, E.H.; Neumark, D.M., Study of low-lying electronic states of ozone by anion photoelectron spectroscopy of O-3(-), J. Chem. Phys., 1994, 101, 2, 912, https://doi.org/10.1063/1.467745 . [all data]

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O3-, J. Chem. Phys., 1979, 70, 2652. [all data]

Rothe, Tang, et al., 1975
Rothe, E.W.; Tang, S.Y.; Reck, G.P., Measurement of electron affinities of O3, SO2, and SO3 by collisional ionization, J. Chem. Phys., 1975, 62, 3829. [all data]

Wong, Vorburger, et al., 1971
Wong, S.F.; Vorburger, T.V.; Woo, S.V., Photodetachment of O3-, Bull. Am. Phys. Soc., 1971, 16, 213. [all data]

Dotan, Davidson, et al., 1977
Dotan, I.; Davidson, J.A.; Streit, G.E.; Albritton, D.L.; Fehsenfeld, F.C., A study of the reaction O3- + CO2 = CO3- + O2 and its implication on the thermochemistry of CO3 and O3 and their negative ions, J. Chem. Phys., 1977, 67, 2874. [all data]

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Gutman, D., Electron Affinities of O2, O3, NO, NO2, and NO3 by Endothermic Charge Transfer, J. Chem. Phys., 1971, 55, 6, 2733, https://doi.org/10.1063/1.1676488 . [all data]

Katsumata, Shiromaru, et al., 1984
Katsumata, S.; Shiromaru, H.; Kimura, T., Photoelectron angular distribution and assignment of photoelectron spectrum of ozone, Bull. Chem. Soc. Jpn., 1984, 57, 1784. [all data]

Weiss, Berkowitz, et al., 1977
Weiss, M.J.; Berkowitz, J.; Appelman, E.H., Photoionization of ozone: Formation of O4+ and O5+, J. Chem. Phys., 1977, 66, 2049. [all data]

Frost, Lee, et al., 1974
Frost, D.C.; Lee, S.T.; McDowell, C.A., High resolution photoelectron spectroscopy of ozone, Chem. Phys. Lett., 1974, 24, 149. [all data]

Dyke, Golob, et al., 1974
Dyke, J.M.; Golob, L.; Jonathan, N.; Morris, A.; Okuda, M., Vacuum ultraviolet photoelectron spectroscopy of transient species. Part 4. Difluoromethylene and ozone, J. Chem. Soc. Faraday Trans. 2, 1974, 70, 1828. [all data]

Brundle, 1974
Brundle, C.R., He (I) and He (II) photoelectron spectra of ozone, Chem. Phys. Lett., 1974, 26, 25. [all data]

Cook, 1968
Cook, G.R., Photoionization and absorption cross sections of ozone, Trans. Am. Geophys. Union, 1968, 49, 736. [all data]

Radwan and Turner, 1966
Radwan, T.N.; Turner, D.W., Molecular photoelectron spectroscopy. Part V. Ozone, J. Chem. Soc. A, 1966, 85. [all data]

Curran, 1961
Curran, R.K., Negative ion formation in ozone, J. Chem. Phys., 1961, 35, 1849. [all data]

Herron and Schiff, 1956
Herron, J.T.; Schiff, H.I., Mass spectrometry of ozone, J. Chem. Phys., 1956, 24, 1266. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, References