Lead oxide


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-48.339kcal/molReviewChase, 1998Data last reviewed in December, 1971
Quantity Value Units Method Reference Comment
liquid,1 bar17.54cal/mol*KReviewChase, 1998Data last reviewed in December, 1971
Quantity Value Units Method Reference Comment
Δfsolid-52.440kcal/molReviewChase, 1998red phase; Data last reviewed in December, 1971

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1159. to 2500.
A 15.53590
B -0.000795
C 0.000411
D -0.000071
E -0.000073
F -52.97101
G 36.33819
H -48.33870
ReferenceChase, 1998
Comment Data last reviewed in December, 1971

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1159.298. to 762.762. to 1159.
A 12.345001.78431511.43963
B 2.50922142.922083.000670
C -0.643847-55.81955-0.000433
D 0.42039526.101100.000099
E -0.1882690.0558870.000048
F -56.85961-54.25024-56.12237
G 29.000607.77834728.42017
H -52.44011-52.44001-52.44001
ReferenceChase, 1998Chase, 1998Chase, 1998
Comment red phase; Data last reviewed in December, 1971 yellow phase; Data last reviewed in December, 1971 yellow phase; Data last reviewed in December, 1971

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Quantity Value Units Method Reference Comment
IE (evaluated)9.1 ± 0.1eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
0.7220 ± 0.0060LPESPolak, Gilles, et al., 1993B

Ionization energy determinations

IE (eV) Method Reference Comment
9.4 ± 0.3EIMakarov and Zbezhneva, 1993LL
9.5 ± 0.4EISemenikhin, Rykov, et al., 1983LBLHLM
9.08 ± 0.10EIZmbov and Miletic, 1978LLK
9.1 ± 0.5EIUy and Drowart, 1969RDSH
9.0 ± 0.5EIDrowart, Colin, et al., 1965RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Pb+11. ± 1.OEIUy and Drowart, 1969RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Polak, Gilles, et al., 1993
Polak, M.L.; Gilles, M.K.; Gunion, R.F.; Lineberger, W.C., Photoelectron Spectroscopy of PbO-, Chem. Phys. Lett., 1993, 210, 1-3, 55, https://doi.org/10.1016/0009-2614(93)89099-4 . [all data]

Makarov and Zbezhneva, 1993
Makarov, A.V.; Zbezhneva, S.G., Use of high-temperature mass spectrometry for analysis of the vapour phase of some substances used in film deposition, Vysokochist. Veshchestva, 1993, 1, 124. [all data]

Semenikhin, Rykov, et al., 1983
Semenikhin, V.I.; Rykov, A.N.; Sidorov, L.N., Mass spectrometric study of the evaporation of lead monoxide, Russ. J. Phys. Chem., 1983, 47, 1008, In original 1663. [all data]

Zmbov and Miletic, 1978
Zmbov, K.F.; Miletic, M., Mass spectrometric determination of the dissociation energy of PbO2 and ionization potentials of PbO and PbO2 molecules, Adv. Mass Spectrom., 1978, 7, 573. [all data]

Uy and Drowart, 1969
Uy, O.M.; Drowart, J., Mass spectrometric determination of the dissociation energies of the molecules BiO, BiS, BiSe and BiTe, J. Chem. Soc. Faraday Trans., 1969, 65, 3221. [all data]

Drowart, Colin, et al., 1965
Drowart, J.; Colin, R.; Exsteen, G., Mass spectrometric study of the vaporization of lead monoxide. Dissociation energy of PbO, J. Chem. Soc. Faraday Trans., 1965, 61, 1376. [all data]


Notes

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