Carbon Tetrachloride
- Formula: CCl4
- Molecular weight: 153.823
- IUPAC Standard InChIKey: VZGDMQKNWNREIO-UHFFFAOYSA-N
- CAS Registry Number: 56-23-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Methane, tetrachloro-; Benzinoform; Carbon chloride (CCl4); Carbona; Fasciolin; Flukoids; Freon 10; Necatorina; Perchloromethane; Tetrachlorocarbon; Tetrachloromethane; Tetrafinol; Tetraform; Tetrasol; Univerm; Vermoestricid; CCl4; Benzenoform; Carbon tet; Methane tetrachloride; Czterochlorek wegla; ENT 4,705; Halon 1040; Necatorine; R 10; Tetrachloorkoolstof; Tetrachloormetaan; Tetrachlorkohlenstoff, tetra; Tetrachlormethan; Tetrachlorure de carbone; Tetraclorometano; Tetracloruro di carbonio; Chlorid uhlicity; ENT 27164; Rcra waste number U211; UN 1846; Katharin; Seretin; Thawpit; NSC 97063; R 10 (Refrigerant)
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -128.1 ± 2.5 | kJ/mol | Review | Manion, 2002 | adopted combustion calorimetry data of Hu and Sinke, 1969 with increased uncertainty to reflect other data; DRB |
ΔfH°liquid | -128.4 | kJ/mol | Ccr | Hu and Sinke, 1969, 2 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -359.9 | kJ/mol | Ccr | Hu and Sinke, 1969, 2 | ALS |
ΔcH°liquid | -365.7 ± 8.4 | kJ/mol | Ccb | Smith, Bjellerup, et al., 1953 | Reanalyzed by Cox and Pilcher, 1970, Original value = -370. ± 10. kJ/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 214.39 | J/mol*K | N/A | Hicks, Hooley, et al., 1944 | DH |
S°liquid | 205.4 | J/mol*K | N/A | Latimer, 1922 | DH |
S°liquid | 219.2 | J/mol*K | N/A | Stull, 1937 | Extrapolation below 91 K; 74.31 J/mol*K.; DH |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
131.3 | 298.15 | Shehatta, 1993 | DH |
133.35 | 298.15 | Lainez, Rodrigo, et al., 1989 | DH |
133.0 | 298.15 | Petrov, Peshekhodov, et al., 1989 | T = 258.15, 278.15, 298.15, 318.15 K.; DH |
132.9 | 298.15 | Nkinamubanzi, Charlet, et al., 1985 | DH |
131.34 | 298.15 | Tanaka, 1982 | T = 293.15, 298.15, 303.15 K. Data at three temperatures.; DH |
129.8 | 293.15 | Atalla, El-Sharkawy, et al., 1981 | DH |
131.6 | 298.15 | Grolier, Hamedi, et al., 1979 | DH |
131.40 | 298.15 | Vesely, Zabransky, et al., 1979 | DH |
131.36 | 298.15 | Wilhelm, Faradjzadeh, et al., 1979 | DH |
131.57 | 298.15 | Grolier, Wilhelm, et al., 1978 | DH |
131.40 | 298.15 | Vesely, Svoboda, et al., 1977 | T = 298 to 318 K.; DH |
131.36 | 298.15 | Fortier, Benson, et al., 1976 | DH |
131.401 | 298.15 | Fortier and Benson, 1976 | DH |
131.9 | 298.15 | Grolier, Benson, et al., 1975 | DH |
131.66 | 293.15 | Wilhelm, Zettler, et al., 1974 | T = 273 to 323 K.; DH |
130.8 | 298.15 | Subrahmanyam and Rajagopal, 1973 | T = 298 to 323 K.; DH |
131.8 | 256.10 | Arentsen and Van Miltenburg, 1972 | T = 243 to 256 K. Value is unsmoothed experimental datum.; DH |
131.0 | 298. | Deshpande and Bhatagadde, 1971 | T = 298 to 318 K.; DH |
131.5 | 293. | Rastorguev and Ganiev, 1967 | T = 293 to 333 K.; DH |
130.9 | 300. | Harrison and Moelwyn-Hughes, 1957 | T = 243 to 303 K.; DH |
130.5 | 303.3 | Harrison and Moelwyn-Hughes, 1957 | T = 254 to 303 K. Unsmoothed experimental datum.; DH |
132.59 | 298. | Staveley, Tupman, et al., 1955 | T = 295 to 339 K.; DH |
128.8 | 298. | Kurbatov, 1948 | T = -20 to 72°C. Mean Cp, four temperatures.; DH |
131.67 | 298.15 | Hicks, Hooley, et al., 1944 | T = 15 to 300 K.; DH |
132.2 | 298.1 | Zhdanov, 1941 | T = 5 to 46°C.; DH |
133.1 | 301.2 | Phillip, 1939 | DH |
132.63 | 298.1 | Stull, 1937 | T = 90 to 320 K.; DH |
133.1 | 298. | Vold, 1937 | DH |
133.0 | 298. | Vold, 1937 | Cp given as 0.2066 cal/g*K.; DH |
126.4 | 288.3 | Kolosovskii and Udovenko, 1934 | DH |
126.4 | 288.3 | de Kolossowsky and Udowenko, 1933 | DH |
130.5 | 298.1 | Richards and Wallace, 1932 | T = 293 to 323 K.; DH |
128.0 | 293.2 | Williams and Daniels, 1925 | T = 20 to 50°C.; DH |
128.9 | 303. | Willams and Daniels, 1924 | T = 303 to 330 K. Equation only.; DH |
133.9 | 290. | Latimer, 1922 | T = 39.1 to 290 K.; DH |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
44.22 | 46. | Atake and Chihara, 1971 | T = 3 to 46 K.; DH |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 349.8 ± 0.3 | K | AVG | N/A | Average of 82 out of 89 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 250.3 ± 0.3 | K | AVG | N/A | Average of 31 out of 37 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 249. ± 3. | K | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 556.36 | K | N/A | Altunin, Geller, et al., 1987 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tc | 556.4 | K | N/A | Majer and Svoboda, 1985 | |
Tc | 556.3 | K | N/A | Campbell and Chatterjee, 1969 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tc | 558.35 | K | N/A | Livingston, Morgan, et al., 1908 | Uncertainty assigned by TRC = 5. K; calculation based on extrap. of density and surface tension; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 44.93 | bar | N/A | Altunin, Geller, et al., 1987 | Uncertainty assigned by TRC = 0.50 bar; TRC |
Pc | 45.576 | bar | N/A | Campbell and Chatterjee, 1969 | Uncertainty assigned by TRC = 0.1013 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 3.62 | mol/l | N/A | Campbell and Chatterjee, 1969 | Uncertainty assigned by TRC = 0.02 mol/l; TRC |
ρc | 3.625 | mol/l | N/A | Kordes, 1954 | Uncertainty assigned by TRC = 0.02 mol/l; TRC |
ρc | 3.625 | mol/l | N/A | Lewis, 1953 | Uncertainty assigned by TRC = 0.03 mol/l; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 32. ± 2. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
29.82 | 349.9 | N/A | Majer and Svoboda, 1985 | |
30.4 | 364. | A | Stephenson and Malanowski, 1987 | Based on data from 349. to 416. K.; AC |
29.2 | 427. | A | Stephenson and Malanowski, 1987 | Based on data from 412. to 497. K.; AC |
30.6 | 509. | A | Stephenson and Malanowski, 1987 | Based on data from 494. to 555. K.; AC |
33.7 | 277. | A,EB | Stephenson and Malanowski, 1987 | Based on data from 262. to 349. K. See also Boublík and Aim, 1972.; AC |
32.3 | 308. | N/A | Hildenbrand and McDonald, 1959 | Based on data from 293. to 351. K.; AC |
31.7 | 325. | N/A | Barker, Brown, et al., 1953 | Based on data from 313. to 338. K.; AC |
Enthalpy of vaporization
ΔvapH =
A exp(-βTr) (1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kJ/mol)
Tr = reduced temperature (T / Tc)
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Temperature (K) | A (kJ/mol) | β | Tc (K) | Reference | Comment |
---|---|---|---|---|---|
298. to 358. | 45.85 | 0.2656 | 556.4 | Majer and Svoboda, 1985 |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
293.03 to 350.86 | 4.02291 | 1221.781 | -45.739 | Hildenbrand and McDonald, 1959, 2 | Coefficents calculated by NIST from author's data. |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
37.9 | 227. to 248. | N/A | Goto, Fujinawa, et al., 1996 | AC |
43.3 | 226. | B | Bondi, 1963 | AC |
38.8 | 217. | N/A | Jones, 1960 | Based on data from 209. to 225. K. See also Goto, Fujinawa, et al., 1996.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.69 | 249. | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
20.49 | 224.6 | Domalski and Hearing, 1996 | CAL |
10.82 | 249. | ||
20.3 | 225.4 | ||
10.1 | 250.3 | ||
20.5 | 225.7 | ||
10.2 | 250.5 |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
4.631 | 225.7 | crystaline, II | crystaline, I | Morrison and Richards, 1976 | DH |
2.562 | 250.53 | crystaline, I | liquid | Morrison and Richards, 1976 | DH |
1.848 | 245.70 | crystaline, II | liquid | Arentsen and Van Miltenburg, 1972 | DH |
2.588 | 250.28 | crystaline, I | liquid | Arentsen and Van Miltenburg, 1972 | Stable phase.; DH |
4.581 | 225.35 | crystaline, II | crystaline, I | Chang and Westrum, 1970 | DH |
2.515 | 250.3 | crystaline, I | liquid | Chang and Westrum, 1970 | DH |
4.582 | 225.35 | crystaline, II | crystaline, I | Hicks, Hooley, et al., 1944 | DH |
2.515 | 250.3 | crystaline, I | liquid | Hicks, Hooley, et al., 1944 | DH |
4.600 | 224.6 | crystaline, II | crystaline, I | Latimer, 1922 | DH |
2.694 | 249. | crystaline, I | liquid | Latimer, 1922 | DH |
4.602 | 225.63 | crystaline, II | crystaline, I | Stull, 1937 | DH |
2.431 | 250.37 | crystaline, I | liquid | Stull, 1937 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
20.52 | 225.7 | crystaline, II | crystaline, I | Morrison and Richards, 1976 | DH |
10.226 | 250.53 | crystaline, I | liquid | Morrison and Richards, 1976 | DH |
7.52 | 245.70 | crystaline, II | liquid | Arentsen and Van Miltenburg, 1972 | DH |
10.22 | 250.28 | crystaline, I | liquid | Arentsen and Van Miltenburg, 1972 | Stable; DH |
20.33 | 225.35 | crystaline, II | crystaline, I | Chang and Westrum, 1970 | DH |
10.04 | 250.3 | crystaline, I | liquid | Chang and Westrum, 1970 | DH |
20.33 | 225.35 | crystaline, II | crystaline, I | Hicks, Hooley, et al., 1944 | DH |
10.05 | 250.3 | crystaline, I | liquid | Hicks, Hooley, et al., 1944 | DH |
20.5 | 224.6 | crystaline, II | crystaline, I | Latimer, 1922 | DH |
10.8 | 249. | crystaline, I | liquid | Latimer, 1922 | DH |
26.40 | 225.63 | crystaline, II | crystaline, I | Stull, 1937 | DH |
9.71 | 250.37 | crystaline, I | liquid | Stull, 1937 | DH |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 11.47 ± 0.01 | eV | N/A | N/A | L |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.80 ± 0.34 | IMRB | Staneke, Groothuis, et al., 1995 | EA > EA(CH2S-.), and Cl-A(CCl3.) < Cl-A(CCl4); B |
2.00 ± 0.20 | NBIE | Lacmann, Maneira, et al., 1983 | B |
2.00 ± 0.20 | NBIE | Dispert and Lacmann, 1978 | B |
2.12 ± 0.10 | SI | Gaines, Kay, et al., 1966 | The Magnetron method, lacking mass analysis, is not considered reliable.; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.5 ± 0.1 | EI | Kime, Driscoll, et al., 1987 | LBLHLM |
11.3 | PE | Von Niessen, Asbrink, et al., 1982 | LBLHLM |
11.47 ± 0.08 | PE | Bassett and Lloyd, 1971 | LLK |
11.47 | PE | Dewar and Worley, 1969 | RDSH |
11.47 ± 0.01 | PI | Watanabe, 1957 | RDSH |
11.0 ± 1.0 | EI | Baker and Tate, 1938 | RDSH |
11.69 | PE | Kimura, Katsumata, et al., 1981 | Vertical value; LLK |
11.69 | PE | Dixon, Murrell, et al., 1971 | Vertical value; LLK |
Appearance energy determinations
Mass spectrum (electron ionization)
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | NIST Mass Spectrometry Data Center, 1998. |
NIST MS number | 291258 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Manion, 2002
Manion, J.A.,
Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons,
J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703
. [all data]
Hu and Sinke, 1969
Hu, A.T.; Sinke, G.C.,
Combustion calorimetry of some chlorinated organic compounds,
J. Chem. Thermodyn., 1969, 1, 6, 507, https://doi.org/10.1016/0021-9614(69)90010-X
. [all data]
Hu and Sinke, 1969, 2
Hu, A.T.; Sinke, G.C.,
Combustion calorimetry of some chlorinated organic compounds,
J. Chem. Thermodyn., 1969, 1, 507-513. [all data]
Smith, Bjellerup, et al., 1953
Smith, L.; Bjellerup, L.; Krook, S.; Westermark, H.,
Heats of combustion of organic chloro compounds determined by the "quartz wool" method,
Acta Chem. Scand., 1953, 7, 65. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Hicks, Hooley, et al., 1944
Hicks, J.F.G.; Hooley, J.G.; Stephenson, C.C.,
The heat capacity of carbon tetrachloride from 15 to 300K. The heats of transition and of fusion. The entropy from thermal measurments compared with the entropy from molecular data,
J. Am. Chem. Soc., 1944, 66, 1064-1067. [all data]
Latimer, 1922
Latimer, W.M.,
The distribution of thermal energy in the tetrachlorides of carbon, silicon, titantium and tin,
J. Am. Chem. Soc., 1922, 44, 90-97. [all data]
Stull, 1937
Stull, D.R.,
A semi-micro calorimeter for measuring heat capacities at low temperatures,
J. Am. Chem. Soc., 1937, 59, 2726-2733. [all data]
Shehatta, 1993
Shehatta, I.,
Heat capacity at constant pressure of some halogen compounds,
Thermochim. Acta, 1993, 213, 1-10. [all data]
Lainez, Rodrigo, et al., 1989
Lainez, A.; Rodrigo, M.M.; Wilhelm, E.; Grolier, J.-P.E.,
Excess volumes and excess heaat capacitiies of some mixtures with trans,trans,cis-1,5,9-cyclododecatriene at 298.15K,
J. Chem. Eng. Data, 1989, 34, 332-335. [all data]
Petrov, Peshekhodov, et al., 1989
Petrov, A.N.; Peshekhodov, P.B.; Al'per, G.A.,
Heat capacity of non-aqueous solutions of non-electrolyts with N,N-dimethylformamide as a base, Sbornik Nauch. Trud., Termodin. Rast. neelect., Ivanovo,
Inst. nevod. rast., 1989, Akad. [all data]
Nkinamubanzi, Charlet, et al., 1985
Nkinamubanzi, P.; Charlet, G.; Delmas, G.,
Excess enthalpies, excess heat capacities and excess volumes of tetraalkoxysilanes with cyclohexane and carbon tetrachloride,
Fluid Phase Equilibria, 1985, 20, 57-73. [all data]
Tanaka, 1982
Tanaka, R.,
Determination of excess heat capacities of (benzene + tetrachloromethane and + cyclohexane) between 293.15 and 303.15 K by use of a Picker flow calorimeter,
J. Chem. Thermodynam., 1982, 14, 259-268. [all data]
Atalla, El-Sharkawy, et al., 1981
Atalla, S.R.; El-Sharkawy, A.A.; Gasser, F.A.,
Measurement of thermal properties of liquids with an AC heated-wire technique,
Inter. J. Thermophys., 1981, 2(2), 155-162. [all data]
Grolier, Hamedi, et al., 1979
Grolier, J-P.E.; Hamedi, M.H.; Wilhelm, E.; Kehiaian, H.V.,
Excess heat capacities of binary mixtures of carbon tetrachloride with n-alkanes at 298.15 K,
Thermochim. Acta, 1979, 31, 79-84. [all data]
Vesely, Zabransky, et al., 1979
Vesely, F.; Zabransky, M.; Svoboda, V.; Pick, J.,
The use of mixing calorimeter for measuring heat capacities of liquids,
Coll. Czech. Chem. Commun., 1979, 44, 3529-3532. [all data]
Wilhelm, Faradjzadeh, et al., 1979
Wilhelm, E.; Faradjzadeh, A.; Grolier, J.-P.E.,
Molar excess heat capacities and excess volumes of 1,2-dichloroethane + cyclooctane, + mesitylene, and + tetrachloromethane,
J. Chem. Thermodynam., 1979, 11, 979-984. [all data]
Grolier, Wilhelm, et al., 1978
Grolier, J.-P.E.; Wilhelm, E.; Hamedi, M.H.,
Molar heat capacities and isothermal compressibility of binary liquid mixtures: carbon tetrachloride + benzene, carbon tetrachloride + cyclohexane and benzene + cyclohexane,
Ber. Bunsenges. Phys. Chem., 1978, 82, 1282-1290. [all data]
Vesely, Svoboda, et al., 1977
Vesely, F.; Svoboda, V.; Pick, J.,
Heat capacities of some organic liquids determined with the mixing calorimeter,
1st Czech. Conf. Calorimetry (Lect. Short Commun.), 1977, C9-1-C9-4. [all data]
Fortier, Benson, et al., 1976
Fortier, J.-L.; Benson, G.C.; Picker, P.,
Heat capacities of some organic liquids determined with the Picker flow calorimeter,
J. Chem. Thermodynam., 1976, 8, 289-299. [all data]
Fortier and Benson, 1976
Fortier, J.-L.; Benson, G.C.,
Excess heat capacities of binary liquid mixtures determined with a Picker flow calorimeter,
J. Chem. Thermodynam., 1976, 8, 411-423. [all data]
Grolier, Benson, et al., 1975
Grolier, J-P.E.; Benson, G.C.; Picker, P.,
Simultaneous measurements of heat capacities and densities of organic liquid mixtures-systems containing ketones,
J. Chem. Eng. Data, 1975, 20, 243-246. [all data]
Wilhelm, Zettler, et al., 1974
Wilhelm, E.; Zettler, M.; Sackmann, H.,
Molar heat capacities for the binary systems cyclohexane, carbon tetrachloride,
silicon tetrachloride and tin tetrachloride Ber. Bunsenges. Phys. Chem., 1974, 78, 795-804. [all data]
Subrahmanyam and Rajagopal, 1973
Subrahmanyam, S.V.; Rajagopal, E.,
Excess thermodynamic functions of the systems isooctane + carbon tetrachloride and isooctane + cyclohexane,
Z. Phys. Chem. [NF], 1973, 85, 256-268. [all data]
Arentsen and Van Miltenburg, 1972
Arentsen, J.G.; Van Miltenburg, J.C.,
Carbon tetrachloride. Determination of the enthalpy of transition from metastable face-centered cubic carbon tetrachloride to the stable rhombohedral modification,
J. Chem. Thermodynam., 1972, 4, 789-791. [all data]
Deshpande and Bhatagadde, 1971
Deshpande, D.D.; Bhatagadde, L.G.,
Heat capacities at constant volume, free volumes, and rotational freedom in some liquids,
Aust. J. Chem., 1971, 24, 1817-1822. [all data]
Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A.,
Study of the heat capacity of selected solvents,
Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]
Harrison and Moelwyn-Hughes, 1957
Harrison, D.; Moelwyn-Hughes, E.A.,
The heat capacities of certain liquids,
Proc. Roy. Soc. (London), 1957, A239, 230-246. [all data]
Staveley, Tupman, et al., 1955
Staveley, L.A.K.; Tupman, W.I.; Hart, K.R.,
Some thermodynamice properties of the systems benzene + ethylene dichloride, benzene + carbon tetrachloride, acetone + chloroform, and acetone + carbon disulphide,
Trans. Faraday Soc., 1955, 51, 323-342. [all data]
Kurbatov, 1948
Kurbatov, V.Ya.,
Heat capacity of liquids. 2. Heat capacity and the temperature dependence of heat capacity from halogen derivatives of acylic hydrocarbons,
Zh. Obshch. Kim., 1948, 18, 372-389. [all data]
Zhdanov, 1941
Zhdanov, A.K.,
Specific heats of some liquids and azeotropic mixtures,
Zhur. Obshch. Khim., 1941, 11, 471-482. [all data]
Phillip, 1939
Phillip, N.M.,
Adiabatic and isothermal compressibilities of liquids,
Proc. Indian Acad. Sci., 1939, A9, 109-120. [all data]
Vold, 1937
Vold, R.D.,
A calorimetric test of the solubility equation for regular solutions,
J. Am. Chem. Soc., 1937, 59, 1515-1521. [all data]
Kolosovskii and Udovenko, 1934
Kolosovskii, N.A.; Udovenko, W.W.,
Specific heat of liquids. II.,
Zhur. Obshchei Khim., 1934, 4, 1027-1033. [all data]
de Kolossowsky and Udowenko, 1933
de Kolossowsky, N.A.; Udowenko, W.W.,
Mesure des chaleurs specifique moleculaires de quelques liquides,
Compt. rend., 1933, 197, 519-520. [all data]
Richards and Wallace, 1932
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Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References
- Symbols used in this document:
AE Appearance energy Cp,liquid Constant pressure heat capacity of liquid Cp,solid Constant pressure heat capacity of solid EA Electron affinity IE (evaluated) Recommended ionization energy Pc Critical pressure S°liquid Entropy of liquid at standard conditions Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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