Dimanganese decacarbonyl


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub80.3 ± 4.2kJ/molN/APilcher and Skinner, 1983See also Good, Fairbrother, et al., 1958.; AC
Δsub92.3 ± 2.1kJ/molCC-RBConnor, Zafarani-Moattar, et al., 1982Other values for the enthalpy of sublimation have been reported: 80.3 ± 4.2 kJ/mol Brown, Connor, et al., 1974 Baev, Dem'yanchuk, et al., 1971 Lemoine, Gross, et al., 1975 (see also Behrens, 1976) and 62.8 ± 4.2 kJ/mol Cotton and Monchamp, 1960; MS
Δsub92.3 ± 2.1kJ/molCConnor, Zafarani-Moattar, et al., 1982, 2AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
60.7 ± 1.3446.Baev, Dem'yanchuk, et al., 1971Based on data from 428. to 463. K.; AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
80.3 ± 2.1390.MMBaev, Dem'yanchuk, et al., 1971Based on data from 351. to 428. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.32 ± 0.01EIMichels and Svec, 1981LLK
7.7PEHigginson, Lloyd, et al., 1975LLK
7.69 ± 0.01PEConnor, Zafarani-Moattar, et al., 1972LLK
8.46 ± 0.03EIJunk and Svec, 1970RDSH
8.4 ± 0.1EIBidinosti and McIntyre, 1970RDSH
8.55 ± 0.10EIWinters and Kiser, 1965RDSH
8.02PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.02PEEvans, Green, et al., 1969Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
MnCO+18.21?EISvec and Junk, 1967RDSH
MnCO+17.5 ± 0.2?EIWinters and Kiser, 1965RDSH
MnC2O2+14.80?EISvec and Junk, 1967RDSH
Mn2C2O2+16.438COEISvec and Junk, 1967RDSH
Mn2C3O3+15.347COEISvec and Junk, 1967RDSH
Mn2C4O4+13.986COEISvec and Junk, 1967RDSH
Mn2C4O4+14.0 ± 0.26COEIWinters and Kiser, 1965RDSH
MnC5O5+9.40?EISvec and Junk, 1967RDSH
MnC5O5+9.3 ± 0.1?EIBidinosti and McIntyre, 1966RDSH
Mn2C5O5+11.915COEISvec and Junk, 1967RDSH
Mn2C5O5+12.6 ± 0.25COEIWinters and Kiser, 1965RDSH
Mn+22.13?EISvec and Junk, 1967RDSH
Mn+20.8 ± 0.4?EIWinters and Kiser, 1965RDSH
Mn2+18.7310COEISvec and Junk, 1967RDSH
Mn2+18.8 ± 0.310COEIWinters and Kiser, 1965RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 153792

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Good, Fairbrother, et al., 1958
Good, W.D.; Fairbrother, D.M.; Waddington, Guy, Manganese Carbonyl: Heat of Formation by Rotating-Bomb Calorimetry, J. Phys. Chem., 1958, 62, 7, 853-856, https://doi.org/10.1021/j150565a021 . [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E., Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]

Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M., J. Chem. Thermodyn., 1975, 7, 913. [all data]

Behrens, 1976
Behrens, R.G., J. Organometal. Chem., 1976, 121, C63. [all data]

Cotton and Monchamp, 1960
Cotton, F.A.; Monchamp, R.R., J. Chem. Soc., 1960, 533.. [all data]

Connor, Zafarani-Moattar, et al., 1982, 2
Connor, Joseph A.; Zafarani-Moattar, Mohamed T.; Bickerton, James; El Saied, Nabila I.; Suradi, Sukiman; Carson, Ronald; Al Takhin, Ghassan; Skinner, Henry A., Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions, Organometallics, 1982, 1, 9, 1166-1174, https://doi.org/10.1021/om00069a011 . [all data]

Michels and Svec, 1981
Michels, G.D.; Svec, H.J., Characterization of MnTc(CO)10 and TcRe(CO)10, Inorg. Chem., 1981, 20, 3445. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Connor, Zafarani-Moattar, et al., 1972
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; ElSaied, N.I.; Suradi, S.; Carson, R.; AlTakhin, G.; Skinner, H.A., [Title unavailable], Organometallics, 1972, 1, 1166. [all data]

Junk and Svec, 1970
Junk, G.A.; Svec, H.J., The mass spectra, ionization potentials, and bond energies of the group VIIA decacarbonyls, J. Chem. Soc. A, 1970, 2102. [all data]

Bidinosti and McIntyre, 1970
Bidinosti, D.R.; McIntyre, N.S., Mass spectrometric study of the thermal decomposition of dimanganese decacarbonyl and dicobalt octacarbonyl, Can. J. Chem., 1970, 48, 593. [all data]

Winters and Kiser, 1965
Winters, R.E.; Kiser, R.W., Ions produced by electron impact with the dimetallic carbonyls of cobalt and manganese, J. Phys. Chem., 1965, 69, 1618. [all data]

Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W., Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Energetics of the ionization and dissociation of Mn2(CO)10, Re2(CO)10, and ReMn(CO)10, J. Am. Chem. Soc., 1967, 89, 2836. [all data]

Bidinosti and McIntyre, 1966
Bidinosti, D.R.; McIntyre, N.S., The metal-metal bond dissociation energy in manganese carbonyl, Chem. Commun., 1966, 555. [all data]


Notes

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