uranium
- Formula: U
- Molecular weight: 238.02891
- IUPAC Standard InChIKey: JFALSRSLKYAFGM-UHFFFAOYSA-N
- CAS Registry Number: 7440-61-1
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to U+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 6.19405 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 237.9 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 232.6 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
6.19405 | EVAL | Lide, 1992 | LL |
6.22 ± 0.02 | PE | Allen, Baerends, et al., 1988 | LL |
6.0 ± 0.3 | EI | Lau and Hildenbrand, 1987 | LBLHLM |
6.09 ± 0.11 | SI | Chetverikov, Gabeskiriya, et al., 1981 | LLK |
6.0 ± 0.5 | EI | Gupta and Gingerich, 1979 | LLK |
6.0 ± 0.5 | EI | Gingerich and Gupta, 1978 | LLK |
6.1941 ± 0.0005 | LS | Solarz, May, et al., 1976 | LLK |
6.187 ± 0.002 | LS | Janes, Itzkan, et al., 1976 | LLK |
6.05 ± 0.07 | EVAL | Sugar, 1974 | LLK |
6.1 ± 0.1 | EI | Rauh and Ackermann, 1974 | LLK |
6.05 ± 0.07 | S | Sugar, 1973 | LLK |
6.3 ± 0.3 | SI | Avni and Klein, 1973 | LLK |
6.8 ± 1.5 | EI | Blackburn and Danielson, 1972 | LLK |
6.2 ± 0.5 | S | Radziemski, Steinhaus, et al., 1970 | RDSH |
6.19 ± 0.06 | EI | Emel'yanov, Khodeev, et al., 1970 | RDSH |
6.1 ± 0.3 | EI | Pattoret, Drowart, et al., 1968 | RDSH |
~6. ± 0.5 | EI | Cater, Rauh, et al., 1968 | RDSH |
6.19 ± 0.06 | SI | Hertel, 1967 | RDSH |
6.11 ± 0.05 | EI | Mann, 1964 | RDSH |
6.08 ± 0.08 | SI | Bakulina and Ionov, 1959 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Lide, 1992
Lide, D.R. (Editor),
Ionization potentials of atoms and atomic ions
in Handbook of Chem. and Phys., 1992, 10-211. [all data]
Allen, Baerends, et al., 1988
Allen, G.C.; Baerends, E.J.; Vernooijs, P.; Dyke, J.M.; Ellis, A.M.; Feher, M.; Morris, A.,
High temperature photoelectron spectroscopy: A study of U, UO, and UO2.,
J. Chem. Phys., 1988, 89, 5363. [all data]
Lau and Hildenbrand, 1987
Lau, K.H.; Hildenbrand, D.L.,
Thermochemistry of the gaseous uranium bromides UBr through UBr5(a),
J. Chem. Phys., 1987, 86, 2949. [all data]
Chetverikov, Gabeskiriya, et al., 1981
Chetverikov, A.P.; Gabeskiriya, V.Y.; Puchkov, V.V.,
Ionization of uranium, plutonium, americium, rhenium, curium, and californium on a rhenium surface,
Sov. Phys. Tech. Phys., 1981, 26, 73. [all data]
Gupta and Gingerich, 1979
Gupta, S.K.; Gingerich, K.A.,
Observation and atomization energies of the gaseous uranium carbides, UC, UC2, UC3, UC4, UC5, and UC6 by high temperature mass spectrometry,
J. Chem. Phys., 1979, 71, 3072. [all data]
Gingerich and Gupta, 1978
Gingerich, K.A.; Gupta, K.A.,
Dissociation energies of the molecules RhTh and RhU from high temperature mass spectrometry and predicted thermodynamic stabilities of selected diatomic actinide-platinum metal intermetallic molecules,
J. Chem. Phys., 1978, 69, 505. [all data]
Solarz, May, et al., 1976
Solarz, R.W.; May, C.A.; Carlson, L.R.; Worden, E.F.; Johnson, S.A.; Paisner, J.A.; Radziemski, L.J., Jr.,
Detection of Rydberg states in atomic uranium using time-resolved stepwise laser photoionization,
Phys. Rev. A:, 1976, 14, 1129. [all data]
Janes, Itzkan, et al., 1976
Janes, G.S.; Itzkan, I.; Pike, C.T.; Levy, R.H.; Levin, L.,
Two-photon laser isotope separation of atomic uranium: Spectroscopic studies, excited-state, and photoionization cross section,
IEEE J. Quantum Electron., 1976, 12, 111. [all data]
Sugar, 1974
Sugar, J.,
Revised ionization energies of the neutral actinides,
J. Chem. Phys., 1974, 60, 4103. [all data]
Rauh and Ackermann, 1974
Rauh, E.G.; Ackermann, R.J.,
First ionization potentials of some refractory oxide vapors,
J. Chem. Phys., 1974, 60, 1396. [all data]
Sugar, 1973
Sugar, J.,
Ionization energies of the neutral actinides,
J. Chem. Phys., 1973, 59, 788. [all data]
Avni and Klein, 1973
Avni, R.; Klein, F.S.,
The first ionization potential of uranium and thorium measured in a d.c. arc plasma,
Spectrochim. Acta Part B, 1973, 25, 331. [all data]
Blackburn and Danielson, 1972
Blackburn, P.E.; Danielson, P.M.,
Electron impact relative ionization cross sections fragmentation of U, UO, UO2, and UO3,
J. Chem. Phys., 1972, 56, 6156. [all data]
Radziemski, Steinhaus, et al., 1970
Radziemski, L.J., Jr.; Steinhaus, D.W.; Cowan, R.D.,
Present status of the analysis of UI UII as derived from measurements of optical spectra,
J. Opt. Soc. Am., 1970, 60, 1556. [all data]
Emel'yanov, Khodeev, et al., 1970
Emel'yanov, A.M.; Khodeev, Y.S.; Gorokhov, L.N.,
Determination of ionization potentials of atomic uranium by electron impact method. I. Measurement of first ionization potential of uranium,
Teplofiz. Vys. Temp., 1970, 8, 279, In original 296. [all data]
Pattoret, Drowart, et al., 1968
Pattoret, A.; Drowart, J.; Smoes, S.,
Etudes thermodynamiques par spectrometrie de masse sur le systeme uranium-oxygene
in Thermodyn. Nucl. Mater. Proc. Symp., 1967 Vienna, 1968, 613. [all data]
Cater, Rauh, et al., 1968
Cater, E.D.; Rauh, E.G.; Thorn, R.J.,
Thermochemistry of UOS; evaporation of US-UO2 mixtures; on the attainment of equilibrium in Knudsen cells,
J. Chem. Phys., 1968, 49, 5244. [all data]
Hertel, 1967
Hertel, G.R.,
Surface ionization. II. The first ionization potential of uranium,
J. Chem. Phys., 1967, 47, 335. [all data]
Mann, 1964
Mann, J.B.,
Ionization of U, UO, and UO2 by electron impact,
J. Chem. Phys., 1964, 40, 1632. [all data]
Bakulina and Ionov, 1959
Bakulina, I.N.; Ionov, N.I.,
Determination of the ionization potential of uranium atoms by the surface ionization method,
Zh. Eksperim. i Teor. Fiz., 1959, 36, 1001. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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