titanium trifluoride
- Formula: F3Ti
- Molecular weight: 104.862
- CAS Registry Number: 13470-08-1
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 56.69 ± 0.41 | 810. | Zmbov and Margrave, 1967 | Based on data from 759. to 865. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference |
|---|---|---|
| 10.5 ± 0.5 | EI | Zmbov and Margrave, 1967, 2 |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| TiF+ | 15.5 | ? | EI | Zmbov and Margrave, 1967, 2 | |
| TiF2+ | 14.0 | F | EI | Zmbov and Margrave, 1967, 2 | |
| Ti+ | 21.3 | ? | EI | Zmbov and Margrave, 1967, 2 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zmbov and Margrave, 1967
Zmbov, Kiro F.; Margrave, John L.,
Mass spectrometric studies at high temperatures. XVI. Sublimation pressures for titanium(III)fluoride and the stabilities of TiF2(g) and TiF(g),
J. Phys. Chem., 1967, 71, 9, 2893-2895, https://doi.org/10.1021/j100868a021
. [all data]
Zmbov and Margrave, 1967, 2
Zmbov, K.F.; Margrave, J.L.,
Mass spectrometric studies at high temperatures. XVI.Sublimation pressures for TiF.and the stabilities of TiF2(g) and TiF(g),
J. Phys. Chem., 1967, 71, 2893. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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