Boron dihydride
- Formula: BH2
- Molecular weight: 12.827
- CAS Registry Number: 14452-64-3
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to H2B+ (ion structure unspecified)
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.8 ± 0.2 | EI | Fehlner and Koski, 1964 | RDSH |
De-protonation reactions
HB- + = H2B
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 389.3 ± 6.6 | kcal/mol | D-EA | Reid, 1993 | gas phase; B |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Fehlner and Koski, 1964
Fehlner, T.P.; Koski, W.S.,
Direct detection of the borane molecule and the boryl radical by mass spectrometry,
J. Am. Chem. Soc., 1964, 86, 2733. [all data]
Reid, 1993
Reid, C.J.,
Electron Affinities of BH, B2, BC, and BN molecules determined using Charge Inversion Spectrometry,
Int. J. Mass Spectrom. Ion Proc., 1993, 127, 147, https://doi.org/10.1016/0168-1176(93)87087-9
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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