Acetic acid ethenyl ester

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-74.95kcal/molN/AVilcu and Perisanu, 1980Value computed using ΔfHliquid° value of -350.8 kj/mol from Vilcu and Perisanu, 1980 and ΔvapH° value of 37.2±0.84 kj/mol from missing citation.; DRB
Δfgas-73.8 ± 2.4kcal/molN/AVilcu and Perisanu, 1980Value computed using ΔfHliquid° value of -346±10 kj/mol from Vilcu and Perisanu, 1980 and ΔvapH° value of 37.2±0.84 kj/mol from missing citation.; DRB

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
12.64100.Kudchadker S.A., 1975GT
17.91200.
22.17273.15
23.66298.15
23.77300.
29.567400.
34.649500.
38.901600.
42.440700.
45.418800.
47.947900.
50.1051000.
51.9551100.
53.5471200.
54.9191300.
56.1071400.
57.1391500.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-83.84kcal/molChydVilcu and Perisanu, 1980ALS
Δfliquid-82.7 ± 2.5kcal/molCcbVilcu and Perisanu, 1980ALS
Quantity Value Units Method Reference Comment
Δcliquid-498.5 ± 2.5kcal/molCcbVilcu and Perisanu, 1980Corresponding Δfliquid = -82.66 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
40.51298.Bengough and Thomson, 1959Mean value 23 to 50°C.; DH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-5546
NIST MS number 228294

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vilcu and Perisanu, 1980
Vilcu, R.; Perisanu, S., The ideal gas state enthalpies of formation of some monomers, Rev. Roum. Chim., 1980, 25, 619-624. [all data]

Kudchadker S.A., 1975
Kudchadker S.A., Thermodynamic properties of oxygen compounds. I. Vinyl acetate, Thermochim. Acta, 1975, 11, 361-365. [all data]

Bengough and Thomson, 1959
Bengough, W.I.; Thomson, R.A.M., A dilatometric method of measuring the heats of radiation-induced reactions. Part 2.- The heat of photochemical addition of bromotrichloromethane to vinyl acetate, Trans. Faraday Soc., 1959, 55, 268-271. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References