Naphthalene-D8
- Formula: C10D8
- Molecular weight: 136.2198
- IUPAC Standard InChIKey: UFWIBTONFRDIAS-PGRXLJNUSA-N
- CAS Registry Number: 1146-65-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Perdeuteronaphthalene; [2H8]Naphthalene; D8-Naphthalene
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Phase change data
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 13.1 | kcal/mol | CGC | Zhao, Unhannanant, et al., 2008 |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
16.9 ± 0.1 | 303. | GS | Sonnefeld, Zoller, et al., 1983 | Based on data from 282. to 323. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.12 ± 0.02 | TRPI | Gotkis, Oleinikova, et al., 1993 | LL |
8.12 ± 0.01 | PIPECO | Ruhl, Price, et al., 1989 | LL |
8.138 ± 0.008 | S | Angus, Christ, et al., 1968 | RDSH |
Appearance energy determinations
Gas Chromatography
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Lee's RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5 | 199.3 | Donnelly, Abdel-Hamid, et al., 1993 | 30. m/0.32 mm/0.25 μm, He, 40. C @ 3. min, 8. K/min, 285. C @ 29.5 min |
Lee's RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | HP-5 | 199.48 | Reckendorf, 1997 | 25. m/0.2 mm/0.11 μm, He; Program: 106C(0.2min) => 40C/min => 120C => 3C/min => 310C(10min) |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zhao, Unhannanant, et al., 2008
Zhao, Hui; Unhannanant, Patamaporn; Hanshaw, William; Chickos, James S.,
Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects,
J. Chem. Eng. Data, 2008, 53, 7, 1545-1556, https://doi.org/10.1021/je800091s
. [all data]
Sonnefeld, Zoller, et al., 1983
Sonnefeld, W.J.; Zoller, W.H.; May, W.E.,
Dynamic coupled-column liquid-chromatographic determination of ambient-temperature vapor pressures of polynuclear aromatic hydrocarbons,
Anal. Chem., 1983, 55, 2, 275-280, https://doi.org/10.1021/ac00253a022
. [all data]
Gotkis, Oleinikova, et al., 1993
Gotkis, Y.; Oleinikova, M.; Naor, M.; Lifshitz, C.,
Time-independent mass spectra and breakdown graphs. 17. Naphthalene and phenanthrene,
J. Phys. Chem., 1993, 97, 12282. [all data]
Ruhl, Price, et al., 1989
Ruhl, E.; Price, S.D.; Leach, S.,
Single and double photoionization processes in naphthalene between 8 and 35 eV,
J. Phys. Chem., 1989, 93, 6312. [all data]
Angus, Christ, et al., 1968
Angus, J.G.; Christ, B.J.; Morris, G.C.,
Absorption spectra in the vacuum ultraviolet and the ionization potentials of naphthalene and naphthalene-d, molecules,
Australian J. Chem., 1968, 21, 2153. [all data]
Jochims, Rasekh, et al., 1993
Jochims, H.-W.; Rasekh, H.; Ruhl, E.; Baumgartel, H.; Leach, S.,
Deuterium isotope effects in the photofragmentation of naphthalene monocations,
J. Phys. Chem., 1993, 97, 1312. [all data]
Donnelly, Abdel-Hamid, et al., 1993
Donnelly, J.R.; Abdel-Hamid, M.S.; Jeter, J.L.; Gurka, D.F.,
Application of gas chromatographic retention properties to the identification of environmental contaminants,
J. Chromatogr., 1993, 642, 1-2, 409-415, https://doi.org/10.1016/0021-9673(93)80106-I
. [all data]
Reckendorf, 1997
Reckendorf, R.M.,
Identification of phenyl-substituted polycyclic aromatic compounds in ring furnace gases using GC-MS and GC-AED,
Chromatographia, 1997, 45, 1, 173-182, https://doi.org/10.1007/BF02505557
. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, References
- Symbols used in this document:
AE Appearance energy ΔsubH Enthalpy of sublimation ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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