Nitrosyl hydride
- Formula: HNO
- Molecular weight: 31.0140
- IUPAC Standard InChI: InChI=1S/HNO/c1-2/h1H
- IUPAC Standard InChIKey: ODUCDPQEXGNKDN-UHFFFAOYSA-N
- CAS Registry Number: 14332-28-6
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
View reactions leading to HNO+ (ion structure unspecified)
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.338 ± 0.015 | LPES | Ellis and Ellison, 1983 | B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.1 | DER | Lias, Bartmess, et al., 1988 | LL |
De-protonation reactions
+
=
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 361.27 ± 0.15 | kcal/mol | D-EA | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 354.68 ± 0.34 | kcal/mol | H-TS | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion; B |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ellis and Ellison, 1983
Ellis, H.B., Jr.; Ellison, G.B.,
Photoelectron spectroscopy of HNO- and DNO-,
J. Chem. Phys., 1983, 78, 6541. [all data]
Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G.,
Gas-phase ion and neutral thermochemistry,
J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]
Travers, Cowles, et al., 1989
Travers, M.J.; Cowles, D.C.; Ellison, G.B.,
Reinvestigation of the Electron Affinities of O2 and NO,
Chem. Phys. Lett., 1989, 164, 5, 449, https://doi.org/10.1016/0009-2614(89)85237-6
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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