beryllium fluoride

• Formula: BeF₂
• Molecular weight: 47.008988
• CAS Registry Number: 7787-49-7
• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • Ion clustering data
  • Vibrational and/or electronic energy levels
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Enthalpy of sublimation

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Greenbaum, Foster, et al., 1963
Greenbaum, Michael A.; Foster, James N.; Arin, M. Louis; Farber, Milton, THE THERMODYNAMIC AND PHYSICAL PROPERTIES OF BERYLLIUM COMPOUNDS. I. ENTHALPY AND ENTROPY OF VAPORIZATION OF BERYLLIUM FLUORIDE ^1,2, J. Phys. Chem., 1963, 67, 1, 36-40, https://doi.org/10.1021/j100795a009 . [all data]

Novoselova, Semenenko, et al., 1958
Novoselova, A.V.; Semenenko, K.N.; Turova, O.Ya., Vestn. Mosk. Univ., Ser. Mat., Mekh., Astron., Fiz., Khim., 1958, 13, 139. [all data]

Sense and Stone, 1958
Sense, Karl A.; Stone, Richard W., Vapor Pressures and Molecular Composition of Vapors of the Sodium Fluoride-Beryllium Fluoride System, J. Phys. Chem., 1958, 62, 4, 453-457, https://doi.org/10.1021/j150562a020 . [all data]

Sense, Snyder, et al., 1954
Sense, K.A.; Snyder, M.J.; Clegg, J.W., The Vapor Pressure of Beryllium Fluoride, J. Phys. Chem., 1954, 58, 3, 223-224, https://doi.org/10.1021/j150513a008 . [all data]

Cantor, 1965
Cantor, S., Vapor Pressures of BeF₂ and NiF₂, J. Chem. Eng. Data, 1965, 10, 3, 237-238, https://doi.org/10.1021/je60026a008 . [all data]

Blauer, Greenbaum, et al., 1965
Blauer, Jay A.; Greenbaum, Michael A.; Farber, Milton, The Thermodynamic and Physical Properties of Beryllium Compounds. VII. Enthalpy and Entropy of Sublimation of Beryllium Fluoride, J. Phys. Chem., 1965, 69, 3, 1069-1070, https://doi.org/10.1021/j100887a508 . [all data]

Farber and Srivastava, 1974
Farber, M.; Srivastava, R.D., Dissociation energies of BeF and BeCl and the heat of formation of BeClF, J. Chem. Soc. Faraday Trans. 1, 1974, 70, 1581. [all data]

Hildenbrand and Murad, 1966
Hildenbrand, D.L.; Murad, E., Mass-spectrometric determination of the dissociation energy of beryllium monofluoride, J. Chem. Phys., 1966, 44, 1524. [all data]

Hildenbrand and Theard, 1965
Hildenbrand, D.L.; Theard, L.P., Effusion studies, mass spectra, and thermodynamics of beryllium fluoride vapor, J. Chem. Phys., 1965, 42, 3230. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔsubH	Enthalpy of sublimation
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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