Benzene, 1,4-dichloro-
- Formula: C6H4Cl2
- Molecular weight: 147.002
- IUPAC Standard InChIKey: OCJBOOLMMGQPQU-UHFFFAOYSA-N
- CAS Registry Number: 106-46-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Benzene, p-dichloro-; p-Chlorophenyl chloride; p-Dichlorobenzene; Di-chloricide; Evola; Paradi; Paradow; Paramoth; Persia-Perazol; PDB; Santochlor; 1,4-Dichlorobenzene; p-Dichlorobenzol; Paradichlorobenzol; para-Dichlorobenzene; p-Dichloorbenzeen; p-Dichlorbenzol; p-Diclorobenzene; Dichlorobenzene; Dichlorobenzene, p-; NCI-C54955; para crystals; Paracide; Paranuggets; Parazene; 1,4-Dichloorbenzeen; 1,4-Dichlor-benzol; 1,4-Diclorobenzene; Dichlorobenzene, para; Globol; Paradichlorbenzol; Rcra waste number U070; Rcra waste number U071; Rcra waste number U072; UN 1592; Dichlorocide; Kaydox; p-Dichlorbenzene; NSC 36935; 1,4-chlorobenzene
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Phase change data
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 447.3 ± 0.6 | K | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 326.1 ± 0.8 | K | AVG | N/A | Average of 26 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 326.150 | K | N/A | Dworkin, Figuiere, et al., 1976 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.01 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 54.8 | kJ/mol | GC | Spieksma, Luijk, et al., 1994 | Based on data from 413. to 453. K.; AC |
ΔvapH° | 47.8 | kJ/mol | N/A | Boublik, Fried, et al., 1984 | Based on data from 370. to 450. K. See also Basarová and Svoboda, 1991.; AC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 64.75 ± 0.15 | kJ/mol | DM | Oonk, van Genderen, et al., 2000 | AC |
ΔsubH° | 65.2 ± 2.0 | kJ/mol | C | An and Zheng, 1989 | AC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
46.4 | 326. | N/A | Rohác, Ruzicka, et al., 1999 | AC |
44.2 | 373. | EB | Rohác, Ruzicka, et al., 1998 | Based on data from 358. to 448. K.; AC |
45.0 | 356. | A | Stephenson and Malanowski, 1987 | Based on data from 341. to 448. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference |
---|---|---|---|---|
341.12 to 447.21 | 4.123 | 1575.11 | -64.637 | McDonald, Shrader, et al., 1959 |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
53.1 | 258. to 313. | N/A | Liu and Dickhut, 1994 | AC |
65.4 | 313. | GS | Shaub, 1985 | Based on data from 303. to 423. K.; AC |
64.8 ± 0.4 | 303. | V | Walsh and Smith, 1961 | ALS |
64.8 ± 0.8 | 303. | N/A | Walsh and Smith, 1961, 2 | Based on data from 293. to 311. K. See also Cox and Pilcher, 1970.; AC |
63. ± 0.4 | 318. | N/A | Walsh and Smith, 1961, 2 | Based on data from 311. to 325. K.; AC |
56.9 | 275. | ME | Darkis, Vermillion, et al., 1940 | Based on data from 248. to 303. K. See also Jones, 1960.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
18.19 | 326.2 | DSC | Wei and Jin, 2009 | See also Wei, 2008.; AC |
17.91 | 326.2 | AC | van der Linde, van Miltenburg, et al., 2005 | Based on data from 5. to 380. K.; AC |
18.16 | 326. | N/A | Acree, 1991 | AC |
18.050 | 326.15 | N/A | Booss and Hauschildt, 1972 | DH |
18.160 | 326. | N/A | Ueberreiter and Orthmann, 1950 | DH |
18.144 | 326.05 | N/A | Narbutt, 1918 | DH |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
55.3 | 326.15 | Booss and Hauschildt, 1972 | DH |
55.7 | 326. | Ueberreiter and Orthmann, 1950 | DH |
55.6 | 326.05 | Narbutt, 1918 | DH |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.200 | 304.0 | crystaline, II | crystaline, I | Petropavlov, Tsygankova, et al., 1988 | DH |
1.256 | 271.77 | crystaline, III | crystaline, II | Dworkin, Figuiere, et al., 1976, 2 | DH |
0.2145 | 304.35 | crystaline, II | crystaline, I | Dworkin, Figuiere, et al., 1976, 2 | DH |
18.187 | 326.14 | crystaline, I | liquid | Dworkin, Figuiere, et al., 1976, 2 | DH |
1.256 | 271.77 | crystaline, III | crystaline, II | Dworkin, Figuiere, et al., 1975 | DH |
0.2145 | 304.35 | crystaline, II | crystaline, I | Dworkin, Figuiere, et al., 1975 | DH |
18.187 | 326.14 | crystaline, I | liquid | Dworkin, Figuiere, et al., 1975 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.6 | 304.0 | crystaline, II | crystaline, I | Petropavlov, Tsygankova, et al., 1988 | DH |
4.62 | 271.77 | crystaline, III | crystaline, II | Dworkin, Figuiere, et al., 1976, 2 | DH |
0.705 | 304.35 | crystaline, II | crystaline, I | Dworkin, Figuiere, et al., 1976, 2 | DH |
55.76 | 326.14 | crystaline, I | liquid | Dworkin, Figuiere, et al., 1976, 2 | DH |
4.62 | 271.77 | crystaline, III | crystaline, II | Dworkin, Figuiere, et al., 1975 | DH |
0.705 | 304.35 | crystaline, II | crystaline, I | Dworkin, Figuiere, et al., 1975 | DH |
55.76 | 326.14 | crystaline, I | liquid | Dworkin, Figuiere, et al., 1975 | DH |
Gas phase ion energetics data
Go To: Top, Phase change data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 8.92 ± 0.03 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH°(+) ion | 883.2 | kJ/mol | N/A | N/A | |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH(+) ion,0K | 895.8 | kJ/mol | N/A | N/A |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.95 | PE | Fujisawa, Oonishi, et al., 1991 | LL |
8.92 ± 0.02 | PIPECO | Olesik, Baer, et al., 1986 | LBLHLM |
8.97 ± 0.03 | PE | Ruscic, Klasinc, et al., 1981 | LLK |
8.94 | PE | Kimura, Katsumata, et al., 1981 | LLK |
8.98 ± 0.02 | PE | Maier and Marthaler, 1978 | LLK |
8.89 ± 0.01 | EQ | Lias and Ausloos, 1978 | LLK |
8.94 ± 0.01 | PI | Watanabe, Nakayama, et al., 1962 | RDSH |
8.95 | PI | Bralsford, Harris, et al., 1960 | RDSH |
8.988 | PE | Potts, Lyus, et al., 1980 | Vertical value; LLK |
9.00 | PE | Streets and Ceasar, 1973 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C6H4Cl+ | 13.2 ± 0.1 | Cl | EI | Brown, 1970 | RDSH |
De-protonation reactions
C6H3Cl2- + =
By formula: C6H3Cl2- + H+ = C6H4Cl2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1577. ± 8.8 | kJ/mol | G+TS | Schlosser, Marzi, et al., 2001 | gas phase; Acid: p-dichlorobenzene.; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1543. ± 8.4 | kJ/mol | IMRE | Schlosser, Marzi, et al., 2001 | gas phase; Acid: p-dichlorobenzene.; B |
Gas Chromatography
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | DB-5 | 100. | 1023.15 | Harangi, 2003 | 60. m/0.32 mm/1. μm, He |
Capillary | DB-5 | 100. | 1023.18 | Harangi, 2003 | 60. m/0.32 mm/1. μm, He |
Capillary | DB-5 | 120. | 1032.51 | Harangi, 2003 | 60. m/0.32 mm/1. μm, He |
Capillary | DB-5 | 120. | 1032.76 | Harangi, 2003 | 60. m/0.32 mm/1. μm, He |
Capillary | SE-30 | 160. | 1016.0 | Santiuste, Harangi, et al., 2003 | |
Capillary | HP-5 | 120. | 1037.4 | Santiuste, Harangi, et al., 2003 | |
Capillary | HP-5 | 120. | 1037.4 | Santiuste J.M. and Takacs J.M., 2003 | 60. m/0.25 mm/0.25 μm, N2 |
Capillary | HP-5 | 140. | 1046. | Santiuste J.M. and Takacs J.M., 2003 | 60. m/0.25 mm/0.25 μm, N2 |
Capillary | SPB-1 | 140. | 1012. | Vezzani, Bertocchi, et al., 1998 | 30. m/0.32 mm/0.25 μm |
Capillary | SE-30 | 0. | 993. | Spieksma, Luijk, et al., 1994 | |
Capillary | SE-30 | 160. | 970. | Evans and Haken, 1989 | Column length: 25. m; Column diameter: 0.32 mm |
Capillary | SE-30 | 160. | 1016. | Tarjan, Nyiredy, et al., 1989 | |
Capillary | SE-30 | 120. | 970. | Haken and Korhonene, 1983 | N2; Column length: 25. m; Column diameter: 0.22 mm |
Capillary | SE-30 | 140. | 1015. | Haken and Korhonene, 1983 | N2; Column length: 25. m; Column diameter: 0.22 mm |
Capillary | SE-30 | 160. | 1016. | Haken and Korhonene, 1983 | N2; Column length: 25. m; Column diameter: 0.22 mm |
Kovats' RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5 | 1016. | Ramarathnam, Rubin, et al., 1993 | He, 30. C @ 2. min, 10. K/min, 280. C @ 3. min; Column length: 30. m; Column diameter: 0.13 mm |
Kovats' RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Packed | SE-30 | 1000. | Ramsey, Lee, et al., 1980 | He, Chromosorb G HP (80-100 mesh); Column length: 1.5 m; Program: not specified |
Kovats' RI, polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | ZB-Wax | 120. | 1483.2 | Pérez-Parajón, Santiuste, et al., 2004 | 60. m/0.25 mm/0.25 μm |
Capillary | Carbowax 20M | 160. | 1438. | Evans and Haken, 1989 | Column length: 22. m; Column diameter: 0.3 mm |
Capillary | Carbowax 20M | 140. | 1438. | Haken and Korhonene, 1983 | N2; Column length: 22. m; Column diameter: 0.3 mm |
Capillary | Carbowax 20M | 160. | 1471. | Haken and Korhonene, 1983 | N2; Column length: 22. m; Column diameter: 0.3 mm |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5 | 1021.24 | Harangi, 2003 | 60. m/0.32 mm/1. μm, He, 60. C @ 2.8 min, 3. K/min; Tend: 180. C |
Capillary | DB-5 | 1021.56 | Harangi, 2003 | 60. m/0.32 mm/1. μm, He, 60. C @ 2.8 min, 3. K/min; Tend: 180. C |
Capillary | DB-5 | 1024.00 | Harangi, 2003 | 60. m/0.32 mm/1. μm, He, 60. C @ 2.8 min, 4. K/min; Tend: 180. C |
Capillary | DB-5 | 1025.03 | Harangi, 2003 | 60. m/0.32 mm/1. μm, He, 60. C @ 2.8 min, 4. K/min; Tend: 180. C |
Capillary | DB-5 | 1014.9 | Xu, van Stee, et al., 2003 | 30. m/0.25 mm/1. μm, He, 2.5 K/min; Tstart: 50. C; Tend: 200. C |
Capillary | Ultra-1 | 991.21 | Richmond and Pombo-Villar, 1997 | 25. m/0.32 mm/0.52 μm, 15. K/min, 320. C @ 10. min; Tstart: 35. C |
Capillary | OV-1 | 990.6 | Gautzsch and Zinn, 1996 | 8. K/min; Tstart: 35. C; Tend: 300. C |
Capillary | DB-1 | 989.5 | Helmig, Pollock, et al., 1996 | 30. m/0.25 mm/1. μm, 6. K/min; Tstart: -50. C; Tend: 180. C |
Capillary | DB-1 | 1014. | Gerbino and Castello, 1995 | 30. m/0.235 mm/0.25 μm, N2, 100. C @ 0. min, 10. K/min |
Capillary | DB-1 | 1009. | Gerbino and Castello, 1995 | 30. m/0.235 mm/0.25 μm, N2, 100. C @ 0. min, 5. K/min |
Capillary | DB-1 | 996. | Gerbino and Castello, 1995 | 30. m/0.235 mm/0.25 μm, N2, 50. C @ 0. min, 10. K/min |
Capillary | DB-1 | 991. | Gerbino and Castello, 1995 | 30. m/0.235 mm/0.25 μm, N2, 50. C @ 0. min, 5. K/min |
Capillary | Petrocol DH | 987. | White, Hackett, et al., 1992 | 100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | 5 % Phenyl methyl siloxane | 1009. | Yasuhara, Shiraishi, et al., 1997 | 25. m/0.31 mm/0.52 μm, He; Program: 50C(2min) => (20C/min) => 120C => (7C/min) => 310C(10min) |
Packed | SE-30 | 1024. | Peng, Ding, et al., 1988 | Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min) |
Van Den Dool and Kratz RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | CP-Wax 52CB | 1438. | Alasalvar, Taylor, et al., 2005 | 60. m/0.25 mm/0.25 μm, 35. C @ 4. min, 3. K/min; Tend: 203. C |
Capillary | Supelcowax-10 | 1449. | Chung, Yung, et al., 2002 | 60. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min |
Capillary | Supelcowax-10 | 1449. | Chung, Yung, et al., 2001 | 60. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min |
Capillary | Supelcowax-10 | 1450. | Chung, 1999 | 60. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min |
Capillary | DB-Wax | 1446.09 | Gerbino and Castello, 1995 | 30. m/0.235 mm/0.5 μm, N2, 5. K/min; Tstart: 50. C |
Capillary | DB-Wax | 1450. | Shiratsuchi, Shimoda, et al., 1994 | 60. m/0.25 mm/0.25 μm, He, 2. K/min, 230. C @ 60. min; Tstart: 50. C |
Capillary | DB-Wax | 1446. | Sumitani, Suekane, et al., 1994 | He, 40. C @ 5. min, 3. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 200. C |
Capillary | Supelcowax-10 | 1453. | Matiella and Hsieh, 1990 | 60. m/0.25 mm/0.25 μm, 40. C @ 5. min, 2. K/min, 175. C @ 20. min |
Normal alkane RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | E-301 | 100. | 1010. | Bermejo, Moinelo, et al., 1980 | N2; Column length: 50. m; Column diameter: 0.25 mm |
Capillary | Squalane | 100. | 998. | Bermejo, Moinelo, et al., 1980 | N2; Column length: 50. m; Column diameter: 0.25 mm |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | HP-5 | 1013. | Zenkevich, Moeder, et al., 2004 | 30. m/0.25 mm/0.25 μm, Helium, 50. C @ 3. min, 3. K/min, 280. C @ 20. min |
Capillary | BP-1 | 1004. | Health Safety Executive, 2000 | 50. m/0.22 mm/0.75 μm, He, 5. K/min; Tstart: 50. C; Tend: 200. C |
Capillary | BP-1 | 1004. | Health Safety Executive, 2000 | 50. m/0.22 mm/0.75 μm, He, 5. K/min; Tstart: 50. C; Tend: 200. C |
Capillary | OV-101 | 960. | Messadi and Ali-Mokhnache, 1993 | 2. K/min; Column length: 25. m; Column diameter: 0.20 mm; Tstart: 80. C |
Capillary | OV-101 | 970. | Messadi and Ali-Mokhnache, 1993 | 2. K/min; Column length: 25. m; Column diameter: 0.20 mm; Tstart: 80. C |
Capillary | OV-101 | 974. | Messadi and Ali-Mokhnache, 1993 | 2. K/min; Column length: 25. m; Column diameter: 0.20 mm; Tstart: 80. C |
Capillary | SE-54 | 1008. | Harland, Cumming, et al., 1986 | He, 50. C @ 2. min, 8. K/min, 250. C @ 12. min; Column length: 25. m; Column diameter: 0.32 mm |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Polydimethyl siloxane with 5 % Ph groups | 1015. | Robinson, Adams, et al., 2012 | Program: not specified |
Capillary | Polydimethyl siloxane with 5 % Ph groups | 1024. | Robinson, Adams, et al., 2012 | Program: not specified |
Capillary | Polydimethyl siloxane, 5 % phenyl | 1007. | Skogerson, Wohlgemuth, et al., 2011 | Program: not specified |
Capillary | RTX-5 MS | 1014. | Mebazaa, Mahmoudi, et al., 2009 | 30. m/0.25 mm/0.25 μm, Helium; Program: 50 0C (5 min) 2 0C/min -> 100 0C (5 min) 5 0C/min -> 300 0C |
Capillary | RTX-5 MS | 1016. | Mebazaa, Mahmoudi, et al., 2009 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
Capillary | Polydimethyl siloxanes | 1057. | Zenkevich, Eliseenkov, et al., 2006 | Program: not specified |
Capillary | Methyl Silicone | 970. | Yu and Zazhi, 2005 | Program: not specified |
Capillary | CP Sil 2 | 989. | Fuhrer, Deissler, et al., 1997 | 55. m/0.25 mm/0.25 μm, N2; Program: 40C(3min) => 20C/min => 80C => 2C/min => 240C(45min) |
Capillary | Polydimethyl siloxanes | 1009. | Zenkevich and Chupalov, 1996 | Program: not specified |
Capillary | DB-5 | 1050. | Sorimachi, Tanabe, et al., 1995 | He; Column length: 30. m; Program: not specified |
Capillary | DB-1 | 986. | Ciccioli, Cecinato, et al., 1994 | 60. m/0.32 mm/0.25 μm; Program: not specified |
Capillary | SPB-1 | 988. | Vezzani, Moretti, et al., 1994 | Column length: 30. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | PTE-5 | 1047. | Nakano, Fujimori, et al., 1992 | 25. m/0.20 mm/0.33 μm; Program: 50 0C (2 min) 30 0C/min -> 200 0C 8 0C/min -> 280 0C (10 min) |
Capillary | Ultra-2 | 1029. | Nakano, Fujimori, et al., 1992 | 25. m/0.20 mm/0.33 μm; Program: 50 0C (2 min) 30 0C/min -> 200 0C 8 0C/min -> 280 0C (10 min) |
Capillary | SE-30 | 987. | Ibrahim and Suffet, 1988 | N2; Column length: 60. m; Column diameter: 0.32 mm; Program: 50C(8min) => 3C/min => 150C => 35C/min => 275C (10min) |
Capillary | OV-1 | 985. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | OV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc. | 1000. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | OV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc. | 985. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | OV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc. | 988. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | OV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc. | 995. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | OV-1 | 994. | Ramsey and Flanagan, 1982 | Program: not specified |
Other | Methyl Silicone | 1023. | Ardrey and Moffat, 1981 | Program: not specified |
Normal alkane RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-FFAP | 1420. | Mebazaa, Mahmoudi, et al., 2009 | 30. m/0.25 mm/0.25 μm, Helium; Program: 50 0C 2 0C/min -> 100 0C (5 min) 5 0C/min -> 250 0C |
Capillary | DB-FFAP | 1434. | Mebazaa, Mahmoudi, et al., 2009 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
Capillary | BP-20 | 1436. | Pontes, Marques, et al., 2007 | 30. m/0.25 mm/0.25 μm, He; Program: 50C(1min) => 2.5C/min => 100C => 2C/min => 180C => 15C/min => 220C |
Capillary | BP-20 | 1436. | Pontes, Marques, et al., 2007 | 30. m/0.25 mm/0.25 μm, He; Program: 50C(1min) => 2.5C/min => 100C => 2C/min => 180C => 15C/min => 220C |
Capillary | Carbowax 20M | 1495. | Ramsey and Flanagan, 1982 | Program: not specified |
Lee's RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | HP5-MS | 163. | Vrana, Paschke, et al., 2005 | 30. m/0.25 mm/0.25 μm, Helium, 50. C @ 5. min, 5. K/min, 280. C @ 10. min |
Capillary | DB-5 | 162.0 | Donnelly, Abdel-Hamid, et al., 1993 | 30. m/0.32 mm/0.25 μm, He, 40. C @ 3. min, 8. K/min, 285. C @ 29.5 min |
Lee's RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Methyl Silicone | 163.15 | Eckel, Ross, et al., 1993 | Program: not specified |
Capillary | Methyl Silicone | 164.81 | Eckel, Ross, et al., 1993 | Program: not specified |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, References
- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy Tboil Boiling point Tfus Fusion (melting) point Ttriple Triple point temperature ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔfH(+) ion,0K Enthalpy of formation of positive ion at 0K ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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