Dirhenium decacarbonyl
- Formula: C10O10Re2
- Molecular weight: 652.515
- IUPAC Standard InChIKey: ZIZHEHXAMPQGEK-UHFFFAOYSA-N
- CAS Registry Number: 14285-68-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Re2(CO)10; Rhenium carbonyl; Rhenium, decacarbonyldi-,; Decacarbonyldirhenium; Rhenium carbonyl (Re2(CO)10); Rhenium, decacarbonyldi-, (Re-Re)
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.49 ± 0.02 | EI | Michels and Svec, 1981 | LLK |
8.36 ± 0.03 | EI | Junk and Svec, 1970 | RDSH |
8.07 | PE | Higginson, Lloyd, et al., 1975 | Vertical value; LLK |
8.86 | PE | Hall, 1975 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CORe2+ | 26.26 | 9CO | EI | Svec and Junk, 1967 | RDSH |
C2O2Re2+ | 23.55 | 8CO | EI | Svec and Junk, 1967 | RDSH |
C3O3Re2+ | 21.46 | 7CO | EI | Svec and Junk, 1967 | RDSH |
C4O4Re+ | 13.30 | ? | EI | Svec and Junk, 1967 | RDSH |
C4O4Re2+ | 19.31 | 6CO | EI | Svec and Junk, 1967 | RDSH |
C5O5Re+ | 10.34 | ? | EI | Junk and Svec, 1970 | RDSH |
C5O5Re2+ | 16.71 | 5CO | EI | Svec and Junk, 1967 | RDSH |
C6O6Re2+ | 15.01 | 4CO | EI | Svec and Junk, 1967 | RDSH |
C7O7Re2+ | 13.55 | 3CO | EI | Svec and Junk, 1967 | RDSH |
C8O8Re2+ | 10.89 | 2CO | EI | Svec and Junk, 1967 | RDSH |
C9O9Re2+ | 9.57 | CO | EI | Svec and Junk, 1967 | RDSH |
Re+ | 37.55 | ? | EI | Svec and Junk, 1967 | RDSH |
Re2+ | 28.96 | 10CO | EI | Svec and Junk, 1967 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Michels and Svec, 1981
Michels, G.D.; Svec, H.J.,
Characterization of MnTc(CO)10 and TcRe(CO)10,
Inorg. Chem., 1981, 20, 3445. [all data]
Junk and Svec, 1970
Junk, G.A.; Svec, H.J.,
The mass spectra, ionization potentials, and bond energies of the group VIIA decacarbonyls,
J. Chem. Soc. A, 1970, 2102. [all data]
Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F.,
Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls,
J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]
Hall, 1975
Hall, M.B.,
The use of spin-orbit coupling in the interpretation of photoelectron spectra. I. Application to substituted rhenium pentacarbonyls,
J. Am. Chem. Soc., 1975, 97, 2057. [all data]
Svec and Junk, 1967
Svec, H.J.; Junk, G.A.,
Energetics of the ionization and dissociation of Mn2(CO)10, Re2(CO)10, and ReMn(CO)10,
J. Am. Chem. Soc., 1967, 89, 2836. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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