Argon
- Formula: Ar
- Molecular weight: 39.948
- IUPAC Standard InChIKey: XKRFYHLGVUSROY-UHFFFAOYSA-N
- CAS Registry Number: 7440-37-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Ar; UN 1006; UN 1951; argon atom
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- X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 15.759 ± 0.001 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 88.24 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 82.77 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
15.763 | PIPECO | Weitzel, Mahnert, et al., 1994 | LL |
15.75962 | EVAL | Lide, 1992 | LL |
15.82 | EI | Wetzel, Baiocchi, et al., 1987 | LBLHLM |
15.760 | S | Kelly, 1987 | LBLHLM |
15.759 | PE | Kimura, Katsumata, et al., 1981 | LLK |
15.88 | EI | Clare and Sowerby, 1981 | LLK |
15.7 | EI | Freiser, 1980 | LLK |
15.75962 ± 0.00001 | S | Minnhagen, 1973 | LLK |
15.753 ± 0.002 | TE | Spohr, Guyon, et al., 1971 | LLK |
15.75962 ± 0.00001 | S | Yoshino, 1970 | RDSH |
15.759 | S | Yoshino, 1969 | RDSH |
15.713 ± 0.003 | CI | Hotop and Niehaus, 1969 | RDSH |
15.757 ± 0.005 | PE | Collin and Natalis, 1968 | RDSH |
15.74 ± 0.05 | EI | Gallegos and Klaver, 1967 | RDSH |
15.78 ± 0.03 | EI | Winters, Collins, et al., 1966 | RDSH |
15.79 | PE | Al-Joboury and Turner, 1963 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Weitzel, Mahnert, et al., 1994
Weitzel, K.-M.; Mahnert, J.; Penno, M.,
ZEKE-PEPICO investigations of dissociation energies in ionic reactions,
Chem. Phys. Lett., 1994, 224, 371. [all data]
Lide, 1992
Lide, D.R. (Editor),
Ionization potentials of atoms and atomic ions
in Handbook of Chem. and Phys., 1992, 10-211. [all data]
Wetzel, Baiocchi, et al., 1987
Wetzel, R.C.; Baiocchi, F.A.; Hayes, T.R.; Freund, R.S.,
Absolute cross sections for electron-impact ionization of the rare-gas atoms by the fast-neutral-beam method,
Phys. Rev. A, 1987, 35, 559. [all data]
Kelly, 1987
Kelly, R.L.,
Atomic and ionic spectrum lines of hydrogen through kryton,
J. Phys. Chem. Ref. Data, 1987, 16. [all data]
Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S.,
Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules
in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Press, Tokyo, 1981. [all data]
Clare and Sowerby, 1981
Clare, P.; Sowerby, D.B.,
Electron impact ionisation energies of some halo-cyclotriphosphazenes,
J. Inorg. Nucl. Chem., 1981, 43, 477. [all data]
Freiser, 1980
Freiser, B.S.,
Electron impact ionization of argon ions by trapped ion cyclotron resonanace spectroscopy,
Int. J. Mass Spectrom. Ion Phys., 1980, 33, 263. [all data]
Minnhagen, 1973
Minnhagen, L.,
Spectrum and the energy levels of neutral argon, Ar I,
J. Opt. Soc. Am., 1973, 63, 1185. [all data]
Spohr, Guyon, et al., 1971
Spohr, R.; Guyon, P.M.; Chupka, W.A.; Berkowitz, J.,
Threshold photoelectron detector for use in the vacuum ultraviolet,
Rev. Sci. Instrum., 1971, 42, 1872. [all data]
Yoshino, 1970
Yoshino, K.,
Absorption spectrum of the argon atom in the vacuum-ultraviolet region,
J. Opt. Soc. Am., 1970, 60, 1220. [all data]
Yoshino, 1969
Yoshino, K.,
Absorption spectrum of the argon atom in the vacuum-ultraviolet region,
J. Opt. Soc. Am., 1969, 59, 1525. [all data]
Hotop and Niehaus, 1969
Hotop, H.; Niehaus, A.,
Reactions of excited atoms molecules with atoms and molecules. II. Energy analysis of penning electrons,
Z. Phys., 1969, 228, 68. [all data]
Collin and Natalis, 1968
Collin, J.E.; Natalis, P.,
Vibrational and electronic ionic states of nitric oxide. An accurate method for measuring ionization potentials by photoelectron spectroscopy,
Intern. J. Mass Spectrom. Ion Phys., 1968, 1, 483. [all data]
Gallegos and Klaver, 1967
Gallegos, E.J.; Klaver, R.F.,
Automatic voltage scanner for a peak switching mass spectrometer,
J.Sci. Instr., 1967, 44, 427. [all data]
Winters, Collins, et al., 1966
Winters, R.E.; Collins, J.H.; Courchene, W.L.,
Resolution of fine structure in ionization-efficiency curves,
J. Chem. Phys., 1966, 45, 1931. [all data]
Al-Joboury and Turner, 1963
Al-Joboury, M.I.; Turner, D.W.,
Molecular photo-electron spectroscopy. Part I. The hydrogen and nitrogen molecules,
J. Chem. Soc., 1963, 5141. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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