Propane, 2-(methylthio)-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
8.7 ± 0.2EIHobrock and Kiser, 1963

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHS+16.4 ± 0.4?EIHobrock and Kiser, 1963 
CH2S+15.5 ± 0.4?EIHobrock and Kiser, 1963 
CH3+19.4 ± 0.5?EIHobrock and Kiser, 1963 
CH3S+15.3 ± 0.2?EIHobrock and Kiser, 1963 
CH4S+12.0 ± 0.2?EIHobrock and Kiser, 1963 
CH5S+12.1 ± 0.2?EIHobrock and Kiser, 1963 
C2H3+16.5 ± 0.5?EIHobrock and Kiser, 1963 
C2H3S+16.1 ± 0.3?EIHobrock and Kiser, 1963 
C2H5S+13.5 ± 0.3?EIHobrock and Kiser, 1963 
C3H3+21.0 ± 0.5?EIHobrock and Kiser, 1963 
C3H5+15.2 ± 0.2?EIHobrock and Kiser, 1963 
C3H6+13.5?EIHobrock and Kiser, 1963 
C3H7+12.7 ± 0.2?EIHobrock and Kiser, 1963 
C3H7S+11.7 ± 0.2CH3EIHobrock and Kiser, 1963 

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApiezon M130.675.Garbuzov, Misharina, et al., 1985He or N2, Chromosorb W, AW-DMCS; Column length: 2.1 m

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryApiezon M675.N/AProgram: not specified
CapillaryApiezon M675.Liu, Cao, et al., 2005Program: not specified
CapillaryPolydimethyl siloxanes665.Zenkevich, 1998Program: not specified
CapillarySE-52676.van Langenhove and Schamp, 1986Column length: 100. m; Column diameter: 0.50 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.650.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hobrock and Kiser, 1963
Hobrock, B.G.; Kiser, R.W., Electron impact investigations of sulfur compounds. II. 3-Methyl-2-thiabutane, 4-thia-1-pentene, and 3,4-dithiahexane, J. Phys. Chem., 1963, 67, 648. [all data]

Garbuzov, Misharina, et al., 1985
Garbuzov, V.G.; Misharina, T.A.; Aerov, A.F.; Golovnya, R.V., Gas chromatographic retention indices for sulphur(II)-containing organic substances, J. Anal. Chem. USSR (Engl. Transl.), 1985, 40, 4, 576-586. [all data]

Liu, Cao, et al., 2005
Liu, L.; Cao, C.-Z.; Xie, B.; Zou, L.-K., Research of QSSR on chromatography retention index of sulfides and mercaptans, Journal of Hunan University of Science and Technology, 2005, 20, 4, 74-80. [all data]

Zenkevich, 1998
Zenkevich, I.G., The Principle of Structural Analogy in the Calculation of Gas Chromatographic Retention Indices using Physico-Chemical Constants of Organic Compounds, Zh. Anal. Khim. (Rus.), 1998, 53, 1, 43-49. [all data]

van Langenhove and Schamp, 1986
van Langenhove, H.; Schamp, N., Identification of Volatiles in the Head Space of Acid-Treated Phosphate Rock by Gas Chromatography-Mass Spectromety, J. Chromatogr., 1986, 351, 65-75, https://doi.org/10.1016/S0021-9673(01)83473-7 . [all data]

Waggott and Davies, 1984
Waggott, A.; Davies, I.W., Identification of organic pollutants using linear temperature programmed retention indices (LTPRIs) - Part II, 1984, retrieved from http://dwi.defra.gov.uk/research/completed-research/reports/dwi0383.pdf. [all data]


Notes

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