Nitrosyl chloride
- Formula: ClNO
- Molecular weight: 65.459
- IUPAC Standard InChI: InChI=1S/ClNO/c1-2-3
- IUPAC Standard InChIKey: VPCDQGACGWYTMC-UHFFFAOYSA-N
- CAS Registry Number: 2696-92-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Nitrogen chloride oxide (NOCl); Nitrogen oxide chloride (NOCl); Nitrogen oxychloride; Nitrogen oxychloride (NOCl); NOCl; Nitrosyl chloride ((NO)Cl); UN 1069; ONCl; Nitrosonium chloride
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| IE (evaluated) | 10.90 ± 0.03 | eV | N/A | N/A | L |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 12.7 | EI | Binnewies, 1983 | LBLHLM |
| 10.9 ± 0.5 | PE | Alderdice and Dixon, 1977 | LLK |
| 10.87 ± 0.01 | PE | Abbas, Dyke, et al., 1976 | LLK |
| 10.94 | PE | Frost, Lee, et al., 1975 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| NO+ | 11.0 ± 0.02 | Cl | EI | Syrvatka and Gil'burd, 1973 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Binnewies, 1983
Binnewies, M.,
Bildung und stabilitat von gasformigem AsOCl und SbOCl massenspektrometrische untersuchungen,
Z. Anorg. Allg. Chem., 1983, 505, 32. [all data]
Alderdice and Dixon, 1977
Alderdice, D.S.; Dixon, R.N.,
Photoelectron spectra of nitrosyl halides,
J. Chem. Soc. Faraday Trans. 2, 1977, 73, 245. [all data]
Abbas, Dyke, et al., 1976
Abbas, M.I.; Dyke, J.M.; Morris, A.,
Photoelectron spectrum of nitrosyl chloride,
J. Chem. Soc. Faraday Trans. 2, 1976, 72, 814. [all data]
Frost, Lee, et al., 1975
Frost, D.C.; Lee, S.T.; McDowell, C.A.; Westwood, N.P.C.,
Photoelectron spectroscopic studies of some nitrosyl and nitryl halides nitric acid,
J. Electron Spectrosc. Relat. Phenom., 1975, 7, 331. [all data]
Syrvatka and Gil'burd, 1973
Syrvatka, B.G.; Gil'burd, M.M.,
Mass-spectrometric study of trifluoronitrosomethane,
Russ. J. Phys. Chem., 1973, 47, 1215. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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