Oxirane, (chloromethyl)-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-108. ± 4.2kJ/molCcrBjellerup and Smith, 1954Heat of formation derived by Cox and Pilcher, 1970

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-149. ± 0.4kJ/molCcrBjellerup and Smith, 1954At 293 K
Quantity Value Units Method Reference Comment
Δcliquid-1770. ± 0.4kJ/molCcrBjellerup and Smith, 1954At 293 K
Δcliquid-1761.64 ± 0.77kJ/molCcbNilsson and Smith, 1944 
Δcliquid-1235.80 ± 0.85kJ/molCcbSmith and Schjdnberg, 1931Not corrected for CODATA value of ΔfH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil389.2KN/AWeast and Grasselli, 1989BS
Tboil390.KN/ARofman, Yakubov, et al., 1976Uncertainty assigned by TRC = 2. K; TRC
Tboil389.6KN/ALecat, 1947Uncertainty assigned by TRC = 0.7 K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
41. ± 4.2293.EBjellerup and Smith, 1954Heat of formation derived by Cox and Pilcher, 1970; ALS
42.9272.N/AStull, 1947Based on data from 256. to 391. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
256.7 to 391.14.668291642.508-38.8Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bjellerup and Smith, 1954
Bjellerup, L.; Smith, L., Heats of combustion of some organic chloro-compounds, Kgl. Fysiograph. Sallskap. Lund Forh., 1954, 24, 1-13. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Nilsson and Smith, 1944
Nilsson, A.T.; Smith, L., Om de isomera epiklorhydrinerna, Svensk. Kim. Tidr., 1944, 56, 156-175. [all data]

Smith and Schjdnberg, 1931
Smith, L.; Schjdnberg, E., Uber die Verbrennung von chlorhaltigen Substanzen in Berthelots Bombe, Svensk Kemisk Tidskrift, 1931, 213-226. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Rofman, Yakubov, et al., 1976
Rofman, V.M.; Yakubov, R.D.; Trofimov, B.A.; Maksimov, S.M., Liq-vap. equil. in system formed by products of vinylation of triethylene glycol & product of epoxidation of ethylene glycol monovinyl ether witrh epichlorohydrin, Zh. Prikl. Khim. (Leningrad), 1976, 49, 1159-61. [all data]

Lecat, 1947
Lecat, M., Orthobaric Azeotropes of Sulfides, Bull. Cl. Sci., Acad. R. Belg., 1947, 33, 160-82. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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