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Oxirane, (chloromethyl)-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.66EIVorob'ev, Furlei, et al., 1989Vertical value; LL
10.60PEMcAlduff and Houk, 1977Vertical value; LLK
10.64PEBaker, Betteridge, et al., 1971Vertical value; LLK
10.64PEBaker, Betteridge, et al., 1971Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHO+12.0 ± 0.5?EIWada and Kiser, 1962RDSH
CH2+21.6 ± 0.5?EIWada and Kiser, 1962RDSH
CH2Cl+12.5 ± 0.1?EIWada and Kiser, 1962RDSH
CH3+14.6?EIWada and Kiser, 1962RDSH
CH3O+13.4 ± 0.2?EIWada and Kiser, 1962RDSH
C2H2+16.6 ± 0.1?EIWada and Kiser, 1962RDSH
C2H2O+12.1 ± 0.1?EIWada and Kiser, 1962RDSH
C2H3+14.0 ± 0.4?EIWada and Kiser, 1962RDSH
C2H4+13.6 ± 0.4?EIWada and Kiser, 1962RDSH
C3H5O+11.4 ± 0.3ClEIWada and Kiser, 1962RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vorob'ev, Furlei, et al., 1989
Vorob'ev, A.S.; Furlei, I.I.; Sultanov, A.S.; Khvostenko, V.I.; Leplyanin, G.V.; Derzhinskii, A.R.; Tolstikov, G.A., Mass spectrometry of reasonance capture of electrons and photoelectron spectroscopy of molecules of ethylene oxide, ethylene sulfide, and their derivatives, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 1388. [all data]

McAlduff and Houk, 1977
McAlduff, E.J.; Houk, K.N., Photoelectron spectra of substituted oxiranes and thiiranes. Substituent effects on ionization potentials involving «sigma» orbitals, Can. J. Chem., 1977, 55, 318. [all data]

Baker, Betteridge, et al., 1971
Baker, A.D.; Betteridge, D.; Kemp, N.R.; Kirby, R.E., Application of photoelectron spectrometry to pesticide analysis. II.Photoelectron spectra of hydroxy-, and halo-alkanes and halohydrins, Anal. Chem., 1971, 43, 375. [all data]

Wada and Kiser, 1962
Wada, Y.; Kiser, R.W., Electron impact spectroscopy of some substituted oxiranes, J. Phys. Chem., 1962, 66, 1652. [all data]


Notes

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