CS2+2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   1Su
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 84900 gas Eland, 2003

State:   3Su
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 77900 gas Eland, 2003

State:   b
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 11370 ± 10 gas Hochlaf, Hall, et al., 1998
Eland, 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 650 T gas PE Eland, 2003

State:   a
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 6330 ± 10 gas Hochlaf, Hall, et al., 1998
Eland, 2003
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 758 ± 10 w gas PE Eland, 2003

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 725 ± 25 gas PE Eland, 2003

Notes

wWeak
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Eland, 2003
Eland, J.H.D., Complete double photoionisation spectra of small molecules from TOF-PEPECO measurements, Chem. Phys., 2003, 294, 2, 171, https://doi.org/10.1016/j.chemphys.2003.08.001 . [all data]

Hochlaf, Hall, et al., 1998
Hochlaf, M.; Hall, R.I.; Penent, F.; Eland, J.H.D.; Lablanquie, P., Investigation of the CS22+ dication using threshold photoelectrons coincidence spectroscopy, Chem. Phys., 1998, 234, 1-3, 249, https://doi.org/10.1016/S0301-0104(98)00177-3 . [all data]

Notes

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