Ozone anion

• Formula: O₃^-
• Molecular weight: 47.9987
• CAS Registry Number: 12596-80-4
• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Ion clustering data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O₃^- +  = (O₃^- • )

By formula: O₃^- + N₂ = (O₃^- • N₂)

O₃^- +  = (O₃^- • )

By formula: O₃^- + O₂ = (O₃^- • O₂)

(O₃^- • 4) +  = (O₃^- • 5)

By formula: (O₃^- • 4O₂) + O₂ = (O₃^- • 5O₂)

(O₃^- • 2) +  = (O₃^- • 3)

By formula: (O₃^- • 2N₂) + N₂ = (O₃^- • 3N₂)

(O₃^- • 2) +  = (O₃^- • 3)

By formula: (O₃^- • 2O₂) + O₂ = (O₃^- • 3O₂)

(O₃^- • 3) +  = (O₃^- • 4)

By formula: (O₃^- • 3N₂) + N₂ = (O₃^- • 4N₂)

(O₃^- • 3) +  = (O₃^- • 4)

By formula: (O₃^- • 3O₂) + O₂ = (O₃^- • 4O₂)

(O₃^- • 4) +  = (O₃^- • 5)

By formula: (O₃^- • 4N₂) + N₂ = (O₃^- • 5N₂)

(O₃^- • 5) +  = (O₃^- • 6)

By formula: (O₃^- • 5N₂) + N₂ = (O₃^- • 6N₂)

(O₃^- • 6) +  = (O₃^- • 7)

By formula: (O₃^- • 6N₂) + N₂ = (O₃^- • 7N₂)

(O₃^- • 7) +  = (O₃^- • 8)

By formula: (O₃^- • 7N₂) + N₂ = (O₃^- • 8N₂)

(O₃^- • 8) +  = (O₃^- • 9)

By formula: (O₃^- • 8N₂) + N₂ = (O₃^- • 9N₂)

(O₃^- • ) +  = (O₃^- • 2)

By formula: (O₃^- • N₂) + N₂ = (O₃^- • 2N₂)

(O₃^- • ) +  = (O₃^- • 2)

By formula: (O₃^- • O₂) + O₂ = (O₃^- • 2O₂)

(O₃^- • 2) +  = (O₃^- • 3)

By formula: (O₃^- • 2H₂O) + H₂O = (O₃^- • 3H₂O)

Free energy of reaction

(O₃^- • ) +  = (O₃^- • 2)

By formula: (O₃^- • H₂O) + H₂O = (O₃^- • 2H₂O)

Free energy of reaction

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(O₃^- • ) +  = (O₃^- • 2)

By formula: (O₃^- • H₂O) + H₂O = (O₃^- • 2H₂O)

Free energy of reaction

(O₃^- • 2) +  = (O₃^- • 3)

By formula: (O₃^- • 2H₂O) + H₂O = (O₃^- • 3H₂O)

Free energy of reaction

O₃^- +  = (O₃^- • )

By formula: O₃^- + N₂ = (O₃^- • N₂)

(O₃^- • ) +  = (O₃^- • 2)

By formula: (O₃^- • N₂) + N₂ = (O₃^- • 2N₂)

(O₃^- • 2) +  = (O₃^- • 3)

By formula: (O₃^- • 2N₂) + N₂ = (O₃^- • 3N₂)

(O₃^- • 3) +  = (O₃^- • 4)

By formula: (O₃^- • 3N₂) + N₂ = (O₃^- • 4N₂)

(O₃^- • 4) +  = (O₃^- • 5)

By formula: (O₃^- • 4N₂) + N₂ = (O₃^- • 5N₂)

(O₃^- • 5) +  = (O₃^- • 6)

By formula: (O₃^- • 5N₂) + N₂ = (O₃^- • 6N₂)

(O₃^- • 6) +  = (O₃^- • 7)

By formula: (O₃^- • 6N₂) + N₂ = (O₃^- • 7N₂)

(O₃^- • 7) +  = (O₃^- • 8)

By formula: (O₃^- • 7N₂) + N₂ = (O₃^- • 8N₂)

(O₃^- • 8) +  = (O₃^- • 9)

By formula: (O₃^- • 8N₂) + N₂ = (O₃^- • 9N₂)

O₃^- +  = (O₃^- • )

By formula: O₃^- + O₂ = (O₃^- • O₂)

(O₃^- • ) +  = (O₃^- • 2)

By formula: (O₃^- • O₂) + O₂ = (O₃^- • 2O₂)

(O₃^- • 2) +  = (O₃^- • 3)

By formula: (O₃^- • 2O₂) + O₂ = (O₃^- • 3O₂)

(O₃^- • 3) +  = (O₃^- • 4)

By formula: (O₃^- • 3O₂) + O₂ = (O₃^- • 4O₂)

(O₃^- • 4) +  = (O₃^- • 5)

By formula: (O₃^- • 4O₂) + O₂ = (O₃^- • 5O₂)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C

State:   ?

State:   A

State:   X

Additional references: Jacox, 1994, page 109; Jacox, 1998, page 203

Notes

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O₃-, J. Chem. Phys., 1979, 70, 2652. [all data]

Hiraoka, 1988
Hiraoka, K., Determination of the Stabilities of O₃^-(N₂)n, O₃^-(O₂)n, and O₄^-(N₂)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Hiller and Vestal, 1981
Hiller, J.F.; Vestal, M.L., Laser Photodissociation of O3- by Triple Quadrupole Mass Spectrometry, J. Chem. Phys., 1981, 74, 11, 6096, https://doi.org/10.1063/1.441053 . [all data]

Wang, Woo, et al., 1987
Wang, L.J.; Woo, S.B.; Helmy, E.M., Laser photodetachment of O_{3} ^{-}, Phys. Rev. A, 1987, 35, 2, 759, https://doi.org/10.1103/PhysRevA.35.759 . [all data]

Cosby, Moseley, et al., 1978
Cosby, P.C.; Moseley, J.T.; Peterson, J.R.; Ling, J.H., Photodissociation spectroscopy of O₃, J. Chem. Phys., 1978, 69, 2771. [all data]

Arnold, Xu, et al., 1994
Arnold, D.W.; Xu, C.S.; Kim, E.H.; Neumark, D.M., Study of low-lying electronic states of ozone by anion photoelectron spectroscopy of O-3(-), J. Chem. Phys., 1994, 101, 2, 912, https://doi.org/10.1063/1.467745 . [all data]

Andrews, 1973
Andrews, L., Resonance Raman spectrum of the matrix isolated ozonide ion in the species metal(+) ozonide(-), J. Am. Chem. Soc., 1973, 95, 14, 4487, https://doi.org/10.1021/ja00795a003 . [all data]

Andrews and Spiker, 1973
Andrews, L.; Spiker, R.C., Jr., Resonance Raman spectrum and vibrational analysis of the ozonide ion in the argon matrix-isolated M[sup +]O[sub 3][sup -] species, J. Chem. Phys., 1973, 59, 4, 1863, https://doi.org/10.1063/1.1680271 . [all data]

Spiker and Andrews, 1973
Spiker, R.C., Jr.; Andrews, L., Matrix reactions of alkali metal atoms with ozone: Infrared spectra of the alkali metal ozonide molecules, J. Chem. Phys., 1973, 59, 4, 1851, https://doi.org/10.1063/1.1680270 . [all data]

Bopp, Alexandrova, et al., 2009
Bopp, J.C.; Alexandrova, A.N.; Elliott, B.M.; Herden, T.; Johnson, M.A., Vibrational predissociation spectra of the , n=3--10, 12 clusters: Even--odd alternation in the core ion, Int. J. Mass Spectrom., 2009, 283, 1-3, 94, https://doi.org/10.1016/j.ijms.2009.02.003 . [all data]

Thompson and Jacox, 1989
Thompson, W.E.; Jacox, M.E., The vibrational spectra of molecular ions isolated in solid neon. II. O+4 and O-4, J. Chem. Phys., 1989, 91, 7, 3826, https://doi.org/10.1063/1.456868 . [all data]

Lugez, Thompson, et al., 1996
Lugez, C.L.; Thompson, W.E.; Jacox, M.E., Matrix isolation study of the interaction of excited neon atoms with O3: Infrared spectrum of O-3 and evidence for the stabilization of O2•••O+4, J. Chem. Phys., 1996, 105, 6, 2153, https://doi.org/10.1063/1.472533 . [all data]

Andrews, Ault, et al., 1975
Andrews, L.; Ault, B.S.; Grzybowski, J.M.; Allen, R.O., Proton and deuteron radiolysis of argon matrix samples of O2 and Cl2. Infrared spectra of charged species, J. Chem. Phys., 1975, 62, 6, 2461, https://doi.org/10.1063/1.430723 . [all data]

Wight, Ault, et al., 1976
Wight, C.A.; Ault, B.S.; Andrews, L., On microwave discharge sources of new chemical species for matrix-isolation spectroscopy and the identification of charged species, J. Chem. Phys., 1976, 65, 4, 1244, https://doi.org/10.1063/1.433233 . [all data]

Jacox and Milligan, 1972
Jacox, M.E.; Milligan, D.E., Vibrational and electronic spectra of the O3- anion isolated in an argon matrix, J. Mol. Spectrosc., 1972, 43, 1, 148, https://doi.org/10.1016/0022-2852(72)90167-1 . [all data]

Jacox and Milligan, 1972, 2
Jacox, M.E.; Milligan, D.E., Spectrum and structure of the O-3 and O-4 anions isolated in an argon matrix, Chem. Phys. Lett., 1972, 14, 4, 518, https://doi.org/10.1016/0009-2614(72)80253-7 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  T	Temperature
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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