(Z)-5-Decene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus160.KN/ABenkeser, Schroll, et al., 1955Uncertainty assigned by TRC = 2. K; TRC
Tfus162.KN/ACampbell and Young, 1943Uncertainty assigned by TRC = 1. K; TRC
Tfus161.KN/ACampbell and Eby, 1941Uncertainty assigned by TRC = 2. K; TRC
Tfus161.15KN/ACampbell and Eby, 1941, 2Uncertainty assigned by TRC = 1.5 K; TRC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
10.3412.AStephenson and Malanowski, 1987Based on data from 397. to 443. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Hydrogen + (Z)-5-Decene = Decane

By formula: H2 + C10H20 = C10H22

Quantity Value Units Method Reference Comment
Δr-28.56 ± 0.35kcal/molChydRogers and Siddiqui, 1975liquid phase; solvent: n-Hexane

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.773 ± 0.006PIRang, Martinson, et al., 1974LLK
8.766 ± 0.005PEMasclet, Grosjean, et al., 1973LLK
8.94 ± 0.01PEKrause, Taylor, et al., 1978Vertical value; LLK

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner Copyright (C) 1987 by the Coblentz Society
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin COLGATE-PALMOLIVE COMPANY (KELLENBACH)
Source reference COBLENTZ NO. 9782
Date 1967/01/26
Name(s) (5Z)-5-decene
5-Decene, cis-
State LIQUID (NEAT)
PURITY 96%
SOURCE - CHEMICAL SAMPLES CO.
Instrument BECKMAN IR-12 (GRATING)
Instrument parameters GRATING
Path length 0.01056 CM
Resolution 2
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY COBLENTZ SOCIETY (BATCH II) FROM HARD COPY

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Benkeser, Schroll, et al., 1955
Benkeser, R.A.; Schroll, G.; Sauve, D.M., J. Am. Chem. Soc., 1955, 77, 3378. [all data]

Campbell and Young, 1943
Campbell, K.N.; Young, E.E., Addition of hydrogen to multiple carbon-carbon bonds: IV the electrolytic reduction of alkyl and aryl acetylenes, J. Am. Chem. Soc., 1943, 65, 965. [all data]

Campbell and Eby, 1941
Campbell, K.N.; Eby, L.T., The preparation of higher cis and trans olefins, J. Am. Chem. Soc., 1941, 63, 216. [all data]

Campbell and Eby, 1941, 2
Campbell, K.N.; Eby, L.T., The Reduction of Multiple Carbon-Carbon Bonds III. Further Studies on the Preparation of Olefins from Acetylenes, J. Am. Chem. Soc., 1941, 63, 2683. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Rogers and Siddiqui, 1975
Rogers, D.W.; Siddiqui, N.A., Heats of hydrogenation of large molecules. I. Esters of unsaturated fatty acids, J. Phys. Chem., 1975, 79, 574-577. [all data]

Rang, Martinson, et al., 1974
Rang, S.; Martinson, E.; Muurisepp, M., Ionization potentials of unsaturated hydrocarbons. 1. n-Alkenes, Eesti NSV Teaduste Akadeemia Toimetised 23, Eesti. NSV Tead. Akad. Toim., 1974, 352. [all data]

Masclet, Grosjean, et al., 1973
Masclet, P.; Grosjean, D.; Mouvier, G., Alkene ionization potentials. Part I. Quantitative determination of alkyl group structural effects, J. Electron Spectrosc. Relat. Phenom., 1973, 2, 225. [all data]

Krause, Taylor, et al., 1978
Krause, D.A.; Taylor, J.W.; Fenske, R.F., An analysis of the effects of alkyl substituents on the ionization potentials of n-alkenes, J. Am. Chem. Soc., 1978, 100, 718. [all data]


Notes

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