Chromium, bis(η6-benzene)-

• Formula: C₁₂H₁₂Cr
• Molecular weight: 208.2198
• IUPAC Standard InChI: InChI=1S/2C6H6.Cr/c2*1-2-4-6-5-3-1;/h2*1-6H; Copy

  
• IUPAC Standard InChIKey: HVURSIGIEONDKB-UHFFFAOYSA-N Copy
• CAS Registry Number: 1271-54-1
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Chromium, bis(benzene)-; Bis(benzene)chromium; Dibenzenechromium; bis(η⁶-Benzene) chromium; Bis(benzene)chromium(0)
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• Information on this page:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Phase change data
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Devyatykh, Larin, et al., 1969
Devyatykh, G.G.; Larin, N.V.; Gaivoronskii, P.E., Mass spectrum of bis(benzene)chromiurn and the appearance potentials of ions, Zh. Obshch. Khim., 1969, 39, 1823, In original 1786. [all data]

Muller and Goser, 1968
Muller, J.; Goser, P., Massenspektroskopische Untersuchungen an Ubergangsmetall-π-Komplexen mit funf-, sechs- und siebengliedrigen aromatischen Ringliganden, J. Organometal. Chem., 1968, 12, 163. [all data]

Pignataro and Lossing, 1967
Pignataro, S.; Lossing, F.P., Mass spectra and ionization potentials of C₆H₆CrC₆H₆ and C₆H₆Cr(CO)₃, J. Organometal. Chem., 1967, 10, 531. [all data]

Cabelli, Cowley, et al., 1982
Cabelli, D.E.; Cowley, A.H.; Lagowski, J.J., The bonding in some bis(arene)chromium compounds as indicated by U. V. photoelectron zpectroscopy, Inorg. Chim. Acta, 1982, 57, 195. [all data]

Guest, Hillier, et al., 1975
Guest, M.F.; Hillier, I.H.; Higginson, B.R.; Lloyd, D.R., The electronic structure of transition metal complexes containing organic ligands II. Low energy photoelectron spectra and ab initio SCF MO calculations of dibenzene chromium and benzene chromium tricarbonyl, Mol. Phys., 1975, 29, 113. [all data]

Evans, Green, et al., 1972
Evans, S.; Green, J.C.; Jackson, S.E., He(I) photoelectron spectra of some π-arene complexes, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 249. [all data]

Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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