NaCH3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CH3 s-stretch 2760 s N2 IR Burczyk and Downs, 1990
2 CH3 s-deform. 1092 w N2 IR Burczyk and Downs, 1990
3 CNa stretch 298 s N2 IR Burczyk and Downs, 1990
e 4 CH3 a-stretch 2805 s N2 IR Burczyk and Downs, 1990
5 CH3 a-deform. 1384 w N2 IR Burczyk and Downs, 1990
6 HCNa bend 362 s N2 IR Burczyk and Downs, 1990

Additional references: Jacox, 1994, page 229; Jacox, 2003, page 247; Li, Xin, et al., 1997; Grotjahn, Pesch, et al., 1997

Notes

wWeak
sStrong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Burczyk and Downs, 1990
Burczyk, K.; Downs, A.J., J. Chem. Soc., 1990, Dalton Trans. 2351. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Li, Xin, et al., 1997
Li, B.-Z.; Xin, J.; Ziurys, L.M., The pure rotational spectrum of NaCH3 (), Chem. Phys. Lett., 1997, 280, 5-6, 513, https://doi.org/10.1016/S0009-2614(97)01199-8 . [all data]

Grotjahn, Pesch, et al., 1997
Grotjahn, D.B.; Pesch, T.C.; Xin, J.; Ziurys, L.M., Structure of Solvent-Free, Monomeric CH, J. Am. Chem. Soc., 1997, 119, 50, 12368, https://doi.org/10.1021/ja972613q . [all data]

Notes

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