Azide cation

• Formula: N₃⁺
• Molecular weight: 42.0196
• CAS Registry Number: 12185-03-4
• Information on this page:
  • Reaction thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Ion clustering data
• Options:
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(N₃⁺ • 10) +  = (N₃⁺ • 11)

By formula: (N₃⁺ • 10N₂) + N₂ = (N₃⁺ • 11N₂)

(N₃⁺ • 9) +  = (N₃⁺ • 10)

By formula: (N₃⁺ • 9N₂) + N₂ = (N₃⁺ • 10N₂)

(N₃⁺ • 3) +  = (N₃⁺ • 4)

By formula: (N₃⁺ • 3N₂) + N₂ = (N₃⁺ • 4N₂)

(N₃⁺ • 4) +  = (N₃⁺ • 5)

By formula: (N₃⁺ • 4N₂) + N₂ = (N₃⁺ • 5N₂)

(N₃⁺ • 5) +  = (N₃⁺ • 6)

By formula: (N₃⁺ • 5N₂) + N₂ = (N₃⁺ • 6N₂)

(N₃⁺ • 6) +  = (N₃⁺ • 7)

By formula: (N₃⁺ • 6N₂) + N₂ = (N₃⁺ • 7N₂)

(N₃⁺ • 7) +  = (N₃⁺ • 8)

By formula: (N₃⁺ • 7N₂) + N₂ = (N₃⁺ • 8N₂)

(N₃⁺ • 8) +  = (N₃⁺ • 9)

By formula: (N₃⁺ • 8N₂) + N₂ = (N₃⁺ • 9N₂)

(N₃⁺ • 2) +  = (N₃⁺ • 3)

By formula: (N₃⁺ • 2N₂) + N₂ = (N₃⁺ • 3N₂)

(N₃⁺ • ) +  = (N₃⁺ • 2)

By formula: (N₃⁺ • N₂) + N₂ = (N₃⁺ • 2N₂)

N₃⁺ +  = (N₃⁺ • )

By formula: N₃⁺ + N₂ = (N₃⁺ • N₂)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A

State:   b

State:   a

State:   X

Additional references: Jacox, 1994, page 72; Jacox, 1998, page 181

Notes

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S., Stabilities of the N3+(N2)n Cluster Ions with n = 1 - 11, Chem. Phys. Lett., 1989, 154, 2, 139, https://doi.org/10.1016/S0009-2614(89)87275-6 . [all data]

Friedmann, Soliva, et al., 1994
Friedmann, A.; Soliva, A.M.; Nizkorodov, S.A.; Bieske, E.J.; Maier, J.P., A 3.PI.u .rarw. X 3.SIGMA.g- Electronic Spectrum of N3+, J. Phys. Chem., 1994, 98, 36, 8896, https://doi.org/10.1021/j100087a013 . [all data]

Dyke, Jonathan, et al., 1982
Dyke, J.M.; Jonathan, N.B.H.; Lewis, A.E.; Morris, A., Vacuum ultraviolet photoelectron spectroscopy oftransient species. Part 15. The N₃(X2π) radical, Mol. Phys., 1982, 47, 1231. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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