Hexaphenylditin

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas855. ± 11.kJ/molReviewMartinho SimõesSelected data
Δfgas955. ± 18.kJ/molReviewMartinho Simões 
Δfgas863. ± 30.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid666.6 ± 9.6kJ/molReviewMartinho SimõesSelected data
Δfsolid767. ± 17.kJ/molReviewMartinho Simões 
Δfsolid675. ± 30.kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcsolid-20275.7 ± 8.4kJ/molCC-RBCarson, Laye, et al., 1970Please also see Pedley and Rylance, 1977.
Δcsolid-20376. ± 17.kJ/molCC-RBTel'noi and Rabinovich, 1966Please also see Cox and Pilcher, 1970.
Δcsolid-20284. ± 29.kJ/molCC-RBLautsch, Tröber, et al., 1963Please also see Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub188.3 ± 4.2kJ/molCC-RBKeiser and Kana'an, 1969MS
Δsub188.3 ± 4.2kJ/molME,TEKeiser and Kana'an, 1969, 2AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C18H15Sn+8.7 ± 0.2?EIChambers and Glockling, 1970 

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 156966

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Carson, Laye, et al., 1970
Carson, a.S.; Laye, P.G.; Spencer, J.A.; Steele, W.V., The enthalpy of combustion of organo-metallic compounds measured with a vacuum-jacketed aneroid calorimeter. The enthalpy of formation of di-tin hexaphenyl and some associated bond energies, J. Chem. Thermodyn., 1970, 2, 659. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1966
Tel'noi, V.I.; Rabinovich, I.B., Russ. J. Phys. Chem., 1966, 40, 842. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Keiser and Kana'an, 1969
Keiser, D.; Kana'an, A.S., J. Phys. Chem., 1969, 73, 4264. [all data]

Keiser and Kana'an, 1969, 2
Keiser, D.; Kana'an, A.S., Enthalpy and entropy of sublimation of tetraphenyltin and hexaphenylditin. Bond dissociation energy of Sn-C and Sn-Sn, J. Phys. Chem., 1969, 73, 12, 4264-4269, https://doi.org/10.1021/j100846a038 . [all data]

Chambers and Glockling, 1970
Chambers, D.B.; Glockling, F., Electron impact determination of heats of formation and bond energies in triphenyltin compounds, Inorg. Chim. Acta, 1970, 4, 150. [all data]


Notes

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