silver iodide
- Formula: AgI
- Molecular weight: 234.7727
- IUPAC Standard InChI: InChI=1S/Ag.HI/h;1H/q+1;/p-1
- IUPAC Standard InChIKey: MSFPLIAKTHOCQP-UHFFFAOYSA-M
- CAS Registry Number: 7783-96-2
- Chemical structure:
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Phase change data
Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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| Temperature (K) | A | B | C | Reference | Comment |
|---|---|---|---|---|---|
| 1093. to 1779. | 4.05773 | 6697.512 | -127.973 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Gas phase ion energetics data
Go To: Top, Phase change data, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.8 | EI | Pittermann and Weil, 1980 | |
| 8.9 | EI | Bernauer and Weil, 1974 | |
| ~8.4 | PI | Berkowitz, 1971 | |
| 13.75 | PE | Berkowitz, Batson, et al., 1980 | Vertical value |
| 10.21 | PE | Berkowitz, Batson, et al., 1980 | Vertical value |
| 8.80 | PE | Berkowitz, Batson, et al., 1980 | Vertical value |
| 9.27 | PE | Berkowitz, Batson, et al., 1980 | Vertical value |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| I+ | 11.1 | Ag | EI | Bernauer and Weil, 1974 |
Constants of diatomic molecules
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through November, 1974
| Symbol | Meaning |
|---|---|
| State | electronic state and / or symmetry symbol |
| Te | minimum electronic energy (cm-1) |
| ωe | vibrational constant – first term (cm-1) |
| ωexe | vibrational constant – second term (cm-1) |
| ωeye | vibrational constant – third term (cm-1) |
| Be | rotational constant in equilibrium position (cm-1) |
| αe | rotational constant – first term (cm-1) |
| γe | rotation-vibration interaction constant (cm-1) |
| De | centrifugal distortion constant (cm-1) |
| βe | rotational constant – first term, centrifugal force (cm-1) |
| re | internuclear distance (Å) |
| Trans. | observed transition(s) corresponding to electronic state |
| ν00 | position of 0-0 band (units noted in table) |
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| D | (45487) | (176) 1 H | (2.5) | D ← X R | ||||||||
| ↳Metropolis, 1939; Barrow and Mulcahy, 1948 | ||||||||||||
| C | 44721 | 155.5 2 H | 1.7 | C ← X R | 44695 H | |||||||
| ↳Metropolis, 1939; Barrow and Mulcahy, 1948 | ||||||||||||
| Continuous absorption above 42400 cm-1. | ||||||||||||
| ↳Metropolis, 1939 | ||||||||||||
| Continuous absorption 29800 - 33300 cm-1, maximum at 31500 cm-1. | ||||||||||||
| ↳Brice, 1931; Mulliken, 1937; Davidovits and Bellisio, 1969 | ||||||||||||
| State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
| B 0+ | 31194.06 | 127.14 Z | 4.255 3 | 0.040716 | 0.000572 3 | [2.19E-08] 4 | 2.6712 | B ↔ X R | 31153.42 Z | |||
| ↳missing citation; Mulliken, 1937; Sastry and Rao, 1945; Barrow and Mulcahy, 1948, 2; Barrow, Morgan, et al., 1959; Barrow, Clements, et al., 1967 | ||||||||||||
| Continuous absorption above 24000 cm-1. | ||||||||||||
| ↳Metropolis and Beutler, 1939 | ||||||||||||
| A | 23906 | 151.2 H | A ← X R | 23879 H | ||||||||
| ↳Metropolis and Beutler, 1939 | ||||||||||||
| X 1Σ+ | 0 | 206.52 Z | 0.445 | 0.04486806 | 0.00014139 | 5.7E-08 | 8.47E-09 5 | 2.544621 6 | ||||
| ↳Hoeft, Lovas, et al., 1971 | ||||||||||||
Notes
| 1 | Analysis Metropolis, 1939 uncertain. Barrow and Mulcahy, 1948 estimate νe ~46000 Barrow and Mulcahy, 1948, ωe ~165 Barrow and Mulcahy, 1948. |
| 2 | Average of Metropolis, 1939 and Barrow and Mulcahy, 1948. |
| 3 | From v=0,1,2 only; γe= -31.5E-5. The vibrational levels converge rapidly to a maximum in the potential curve at ~510 cm-1 above v=0; see Barrow and Mulcahy, 1948, 2. |
| 4 | D1 = 2.53E-8, D2 = 3.38E-8. |
| 5 | Calculated from 4Be3/ωe2. From the rotational analysis of B-X bands D0= 0.96, D1= 0.90, D2= 0.85, D3= 0.840E-8. |
| 6 | Microwave sp. 8 |
| 7 | Thermochemical value Brewer and Lofgren, 1950, Barrow, 1954. |
| 8 | For value of eqQ(127I) see Hoeft, Lovas, et al., 1971. |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Pittermann and Weil, 1980
Pittermann, U.; Weil, K.G.,
Massenspektrometrische Untersuchungen an Silberhalogeniden V: Verdampfung von Silberiodid,
Ber. Bunsen-Ges. Phys. Chem., 1980, 84, 542. [all data]
Bernauer and Weil, 1974
Bernauer, O.; Weil, K.G.,
Massenspektrometrische untersuchungen an silberhalogeniden. III: Silberbromid und silberjodid,
Ber. Bunsen-Ges. Phys. Chem., 1974, 12, 1339. [all data]
Berkowitz, 1971
Berkowitz, J.,
Photoionization mass spectrometry photoelectron spectroscopy of high temperature vapor,
Adv. High Temp. Chem., 1971, 3, 123. [all data]
Berkowitz, Batson, et al., 1980
Berkowitz, J.; Batson, C.H.; Goodman, G.L.,
Photoelectron spectroscopy of AgCl, AgBr, and AgI vapors,
J. Chem. Phys., 1980, 72, 5829. [all data]
Metropolis, 1939
Metropolis, N.,
A new ultraviolet band system of silver iodide,
Phys. Rev., 1939, 55, 636. [all data]
Barrow and Mulcahy, 1948
Barrow, R.F.; Mulcahy, M.F.R.,
Excited States of Silver Bromide and Iodide,
Nature (London), 1948, 162, 4113, 336-337. [all data]
Brice, 1931
Brice, B.A.,
Absorption band spectra of silver bromide and silver iodide vapors,
Phys. Rev., 1931, 38, 658. [all data]
Mulliken, 1937
Mulliken, R.S.,
Low electronic states of simple heteropolar diatomic molecules: III. Hydrogen and univalent metal halides,
Phys. Rev., 1937, 51, 310. [all data]
Davidovits and Bellisio, 1969
Davidovits, P.; Bellisio, J.A.,
Ultraviolet Absorption Cross Sections for the Thallium Halide and Silver Halide Vapors,
J. Chem. Phys., 1969, 50, 8, 3560-3567. [all data]
Sastry and Rao, 1945
Sastry, C.R.; Rao, K.R.,
Note on the emission bands of the silver iodide molecule,
Indian J. Phys., 1945, 19, 136. [all data]
Barrow and Mulcahy, 1948, 2
Barrow, R.F.; Mulcahy, M.F.R.,
The B-N band-system of silver iodide,
Proc. Phys. Soc. London, 1948, 61, 99. [all data]
Barrow, Morgan, et al., 1959
Barrow, R.F.; Morgan, E.; Wright, C.V.,
Internuclear distances in gaseous silver halides,
Proc. Chem. Soc. London, 1959, 303. [all data]
Barrow, Clements, et al., 1967
Barrow, R.F.; Clements, R.M.; Wright, C.V.,
Rotational analysis of bands of the B-X system of gaseous AgI,
Trans. Faraday Soc., 1967, 63, 2874. [all data]
Metropolis and Beutler, 1939
Metropolis, N.; Beutler, H.,
Additional band systems of silver halide vapors and a new thermodynamical calculation of their dissociation energies,
Phys. Rev., 1939, 55, 1113. [all data]
Hoeft, Lovas, et al., 1971
Hoeft, J.; Lovas, F.J.; Tiemann, F.; Torring, T.,
Die Mikrowellen-Rotationsspektren des AgCl, AgBr, and AgJ,
Z. Naturforsch. A, 1971, 26, 240. [all data]
Brewer and Lofgren, 1950
Brewer, L.; Lofgren, N.L.,
The thermodynamics of gaseous cuprous chloride, monomer and trimer,
J. Am. Chem. Soc., 1950, 72, 3038. [all data]
Barrow, 1954
Barrow, R.F.,
Maxima in the potential energy-distance functions of diatomic molecules,
J. Chem. Phys., 1954, 22, 573. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Constants of diatomic molecules, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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