Magnesium monofluoride

• Formula: FMg
• Molecular weight: 43.3034
• IUPAC Standard InChI: InChI=1S/FH.Mg/h1H;/q;+1/p-1 Copy

  
• IUPAC Standard InChIKey: WSXHQDSJUJYQDO-UHFFFAOYSA-M Copy
• CAS Registry Number: 14953-28-7
• Chemical structure:
  This structure is also available as a 2d Mol file
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• Information on this page:
  • Gas phase thermochemistry data
  • Gas phase ion energetics data
  • Constants of diatomic molecules
  • References
  • Notes
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to FMg⁺ (ion structure unspecified)

Ionization energy determinations

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through March, 1977

Notes

References

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hildenbrand, 1968
Hildenbrand, D.L., Mass-spectrometric studies of bonding in the group IIA fluorides, J. Chem. Phys., 1968, 48, 3657. [all data]

Barrow and Beale, 1967
Barrow, R.F.; Beale, J.R., Rotational analysis of electronic bands of gaseous MgF, Proc. Phys. Soc. (London), 1967, 91, 483. [all data]

Murad, Hildenbrand, et al., 1966
Murad, E.; Hildenbrand, D.L.; Main, R.P., Dissociation energies of group IIIA monofluorides-the possibility of potential maxima in their excited H states,, J. Chem. Phys., 1966, 45, 263. [all data]

Ehlert, Blue, et al., 1964
Ehlert, T.C.; Blue, G.D.; Green, J.W.; Margrave, J.L., Mass spectrometric studies at high temperatures. IV. Dissociation energies of the alkaline earth monofluorides, J. Chem. Phys., 1964, 41, 2250. [all data]

Novikov and Gurvich, 1971
Novikov, M.M.; Gurvich, L.V., The electronic spectra of MgF and MgF⁺, J. Appl. Spectrosc. Engl. Transl., 1971, 14, 820, In original 1113. [all data]

Jevons, 1929
Jevons, W., Observations in connection with the band systems of the fluorides of beryllium and magnesium, Proc. R. Soc. London A, 1929, 122, 211. [all data]

Knight, Easley, et al., 1971
Knight, L.B., Jr.; Easley, W.C.; Weltner, W., Jr., Hyperfine interaction and chemical bonding in MgF, CaF, SrF, and BaF molecules, J. Chem. Phys., 1971, 54, 322. [all data]

Maheshwari, Singh, et al., 1968
Maheshwari, R.C.; Singh, I.D.; Shukla, M.M., Franck-Condon factors and r centroids for the B-X and C-X systems of the MgF molecule, J. Phys. B:, 1968, 1, 993. [all data]

Rao and Lakshman, 1970
Rao, T.V.R.; Lakshman, S.V.J., r-Centroids and Franck-Condon factors for the bands of the C²Σ⁺-X²Σ⁺ system of MgF, J. Quant. Spectrosc. Radiat. Transfer, 1970, 10, 945. [all data]

Rao and Lakshman, 1970, 2
Rao, T.V.R.; Lakshman, S.V.J., The true potential energy curves, γ-centroids and Franck-Condon factors of the bands of the B²Σ⁺-X²Σ⁺ system of MgF, Physica (Amsterdam), 1970, 46, 609. [all data]

Walker and Richards, 1970
Walker, T.E.H.; Richards, W.G., The assignment of molecular orbital configurations on the basis of λ-type doubling, J. Phys., 1970, 3, 271. [all data]

Walker and Richards, 1968
Walker, T.E.H.; Richards, W.G., The nature of the first excited electronic state in MgF, J. Phys. B:, 1968, 1, 1061. [all data]

Singh, Shukla, et al., 1969
Singh, I.D.; Shukla, M.M.; Maheshwari, R.C., Vibrational transition probabilities and r-centroids for the A-X system of the magnesium fluoride molecule, J. Quant. Spectrosc. Radiat. Transfer, 1969, 9, 533. [all data]

Notes

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• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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